Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water
Immobilization of polyethylene glycol-substituted 1-methylimidazolium bromide on the surface of magnetic Fe 3 O 4 nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer catalysis which was successfully used for regioselective ring openin...
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| Veröffentlicht in: | Russian journal of organic chemistry 2017-06, Vol.53 (6), p.846-852 |
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| container_end_page | 852 |
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| container_issue | 6 |
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| container_title | Russian journal of organic chemistry |
| container_volume | 53 |
| creator | Ayashi, N. Fallah-Mehrjardi, M. Kiasat, A. R. |
| description | Immobilization of polyethylene glycol-substituted 1-methylimidazolium bromide on the surface of magnetic Fe
3
O
4
nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer catalysis which was successfully used for regioselective ring opening of epoxides with azide and nitrite anions in aqueous medium. The new catalyst can readily be recovered by simple magnetic decantation and recycled several times without appreciable loss of catalytic activity. |
| doi_str_mv | 10.1134/S1070428017060069 |
| format | Article |
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3
O
4
nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer catalysis which was successfully used for regioselective ring opening of epoxides with azide and nitrite anions in aqueous medium. The new catalyst can readily be recovered by simple magnetic decantation and recycled several times without appreciable loss of catalytic activity.</description><identifier>ISSN: 1070-4280</identifier><identifier>EISSN: 1608-3393</identifier><identifier>DOI: 10.1134/S1070428017060069</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alcohols ; Catalysis ; Catalytic activity ; Chemical industry ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Decantation ; Iron oxides ; Organic Chemistry ; Phase transfer catalysts ; Polyethylene glycol ; Polyethylenes ; Regioselectivity ; Ring opening</subject><ispartof>Russian journal of organic chemistry, 2017-06, Vol.53 (6), p.846-852</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-6fbcfde3918da598b523ce18e2aaf59542701bb768fbabaec56b93462848d0703</citedby><cites>FETCH-LOGICAL-c316t-6fbcfde3918da598b523ce18e2aaf59542701bb768fbabaec56b93462848d0703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070428017060069$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070428017060069$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Ayashi, N.</creatorcontrib><creatorcontrib>Fallah-Mehrjardi, M.</creatorcontrib><creatorcontrib>Kiasat, A. R.</creatorcontrib><title>Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water</title><title>Russian journal of organic chemistry</title><addtitle>Russ J Org Chem</addtitle><description>Immobilization of polyethylene glycol-substituted 1-methylimidazolium bromide on the surface of magnetic Fe
3
O
4
nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer catalysis which was successfully used for regioselective ring opening of epoxides with azide and nitrite anions in aqueous medium. The new catalyst can readily be recovered by simple magnetic decantation and recycled several times without appreciable loss of catalytic activity.</description><subject>Alcohols</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemical industry</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Decantation</subject><subject>Iron oxides</subject><subject>Organic Chemistry</subject><subject>Phase transfer catalysts</subject><subject>Polyethylene glycol</subject><subject>Polyethylenes</subject><subject>Regioselectivity</subject><subject>Ring opening</subject><issn>1070-4280</issn><issn>1608-3393</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kc9OwzAMxisEEmPwANwicS4kTZu2RzTxT5rEYXCu3NRdM3VJSbKh8UZceRCeiWxDCAlxsi1_38-WHUXnjF4yxtOrGaM5TZOCspwKSkV5EI2YoEXMeckPQx7a8bZ_HJ04t6CUpizlo-h9ttG-Q6ccAd0Q2YEF6dGqN_DKaGJaAkSbNfZEgzZLmGv0SpKhA4ext6Bdi5ZI8NBvnN9BlA-wYeiV3DO8IRbnyjjsUXq1RuJ-hgb-50cMb6oxO28otPI2FL00nekdUZq8QtjoNDpqoXd49h3H0fPtzdPkPp4-3j1Mrqex5Ez4WLS1bBvkJSsayMqizhIukRWYALRZmaVJTlld56Joa6gBZSbqkqciKdKiCUfi4-hizx2seVmh89XCrKwOIytWJpwnjAkeVGyvktY4Z7GtBquWYDcVo9X2I9WfjwRPsve4oNVztL_I_5q-AHoZkvU</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Ayashi, N.</creator><creator>Fallah-Mehrjardi, M.</creator><creator>Kiasat, A. R.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170601</creationdate><title>Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water</title><author>Ayashi, N. ; Fallah-Mehrjardi, M. ; Kiasat, A. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-6fbcfde3918da598b523ce18e2aaf59542701bb768fbabaec56b93462848d0703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Alcohols</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chemical industry</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Decantation</topic><topic>Iron oxides</topic><topic>Organic Chemistry</topic><topic>Phase transfer catalysts</topic><topic>Polyethylene glycol</topic><topic>Polyethylenes</topic><topic>Regioselectivity</topic><topic>Ring opening</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ayashi, N.</creatorcontrib><creatorcontrib>Fallah-Mehrjardi, M.</creatorcontrib><creatorcontrib>Kiasat, A. R.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ayashi, N.</au><au>Fallah-Mehrjardi, M.</au><au>Kiasat, A. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water</atitle><jtitle>Russian journal of organic chemistry</jtitle><stitle>Russ J Org Chem</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>53</volume><issue>6</issue><spage>846</spage><epage>852</epage><pages>846-852</pages><issn>1070-4280</issn><eissn>1608-3393</eissn><abstract>Immobilization of polyethylene glycol-substituted 1-methylimidazolium bromide on the surface of magnetic Fe
3
O
4
nanoparticles through hexane-1,6-diyldicarbamate linker afforded a powerful and reusable heterogeneous phase-transfer catalysis which was successfully used for regioselective ring opening of epoxides with azide and nitrite anions in aqueous medium. The new catalyst can readily be recovered by simple magnetic decantation and recycled several times without appreciable loss of catalytic activity.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070428017060069</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Russian journal of organic chemistry, 2017-06, Vol.53 (6), p.846-852 |
| issn | 1070-4280 1608-3393 |
| language | eng |
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| subjects | Alcohols Catalysis Catalytic activity Chemical industry Chemical synthesis Chemistry Chemistry and Materials Science Decantation Iron oxides Organic Chemistry Phase transfer catalysts Polyethylene glycol Polyethylenes Regioselectivity Ring opening |
| title | Synthesis and characterization of a novel nanomagnetic phase-transfer catalyst and its application to regioselective synthesis of β-azido and β-nitro alcohols in water |
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