Effects of composition on the properties of dual physically cross-linked hydrogel composed of polyvinyl alcohol and poly (acrylamide-co-acrylic acid)
In previous work, we have developed a dual physically cross-linked hydrogel composed of poly (acrylamide-co-acrylic acid) (PAM-co-PAA) and polyvinyl alcohol (PVA), named as PVA/CP DN gel, by facile copolymerization and freezing/thawing. The PVA/CP DN gel is featuring both excellent mechanical proper...
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| Veröffentlicht in: | Journal of polymer research 2017-08, Vol.24 (8), p.1, Article 127 |
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| creator | Gong, Zhengyu Niu, Fangfang Zhang, Guoping Li, Jinhui Li, Gang Huang, Wangping Deng, Hai Sun, Rong Wong, Chingping |
| description | In previous work, we have developed a dual physically cross-linked hydrogel composed of poly (acrylamide-co-acrylic acid) (PAM-co-PAA) and polyvinyl alcohol (PVA), named as PVA/CP DN gel, by facile copolymerization and freezing/thawing. The PVA/CP DN gel is featuring both excellent mechanical properties and self-healing ability. Additionally, we have preliminarily found that the comonomer ratio for PVA/CP DN gel have great influence on the self-healing efficiency. In this research article, we will further discuss the mechanical and self-healing properties of the PVA/CP DN gel by varying the comonomer ratio of PAM-co-PAA. The results proved that the structure of DN will be loosen when the number of PAA segments exceed that of PAM. More PAA segments in copolymer make the PVA/CP DN gel have better elongation at break but weak in tensile strength and young’s modulus because of less PVA crystalline domains formed in the gel. The energy dissipation value for the double-network hydrogel decrease with the addition of PAA segments, whereas self-healing efficiency of PVA/CP DN gel increased. Anyway, this work provides more information to further understand the effects of composition on the properties of dual physically cross-linked PVA/CP DN hydrogel. |
| doi_str_mv | 10.1007/s10965-017-1284-6 |
| format | Article |
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The PVA/CP DN gel is featuring both excellent mechanical properties and self-healing ability. Additionally, we have preliminarily found that the comonomer ratio for PVA/CP DN gel have great influence on the self-healing efficiency. In this research article, we will further discuss the mechanical and self-healing properties of the PVA/CP DN gel by varying the comonomer ratio of PAM-co-PAA. The results proved that the structure of DN will be loosen when the number of PAA segments exceed that of PAM. More PAA segments in copolymer make the PVA/CP DN gel have better elongation at break but weak in tensile strength and young’s modulus because of less PVA crystalline domains formed in the gel. The energy dissipation value for the double-network hydrogel decrease with the addition of PAA segments, whereas self-healing efficiency of PVA/CP DN gel increased. Anyway, this work provides more information to further understand the effects of composition on the properties of dual physically cross-linked PVA/CP DN hydrogel.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-017-1284-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Acrylamide ; Acrylic acid ; Acrylics ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Composition effects ; Copolymerization ; Crosslinking ; Crystal structure ; Elongation ; Energy dissipation ; Freezing ; Healing ; Hydrogels ; Industrial Chemistry/Chemical Engineering ; Information dissemination ; Mechanical properties ; Modulus of elasticity ; Original Paper ; Polymer Sciences ; Polyvinyl alcohol ; Segments ; Tensile strength</subject><ispartof>Journal of polymer research, 2017-08, Vol.24 (8), p.1, Article 127</ispartof><rights>Springer Science+Business Media B.V. 2017</rights><rights>Journal of Polymer Research is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-9b5941ce1c4114220577584bd019c8f7e3170b1777bb636fad129f0f10a7160f3</citedby><cites>FETCH-LOGICAL-c316t-9b5941ce1c4114220577584bd019c8f7e3170b1777bb636fad129f0f10a7160f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-017-1284-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-017-1284-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Gong, Zhengyu</creatorcontrib><creatorcontrib>Niu, Fangfang</creatorcontrib><creatorcontrib>Zhang, Guoping</creatorcontrib><creatorcontrib>Li, Jinhui</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Huang, Wangping</creatorcontrib><creatorcontrib>Deng, Hai</creatorcontrib><creatorcontrib>Sun, Rong</creatorcontrib><creatorcontrib>Wong, Chingping</creatorcontrib><title>Effects of composition on the properties of dual physically cross-linked hydrogel composed of polyvinyl alcohol and poly (acrylamide-co-acrylic acid)</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>In previous work, we have developed a dual physically cross-linked hydrogel composed of poly (acrylamide-co-acrylic acid) (PAM-co-PAA) and polyvinyl alcohol (PVA), named as PVA/CP DN gel, by facile copolymerization and freezing/thawing. The PVA/CP DN gel is featuring both excellent mechanical properties and self-healing ability. Additionally, we have preliminarily found that the comonomer ratio for PVA/CP DN gel have great influence on the self-healing efficiency. In this research article, we will further discuss the mechanical and self-healing properties of the PVA/CP DN gel by varying the comonomer ratio of PAM-co-PAA. The results proved that the structure of DN will be loosen when the number of PAA segments exceed that of PAM. More PAA segments in copolymer make the PVA/CP DN gel have better elongation at break but weak in tensile strength and young’s modulus because of less PVA crystalline domains formed in the gel. The energy dissipation value for the double-network hydrogel decrease with the addition of PAA segments, whereas self-healing efficiency of PVA/CP DN gel increased. Anyway, this work provides more information to further understand the effects of composition on the properties of dual physically cross-linked PVA/CP DN hydrogel.</description><subject>Acrylamide</subject><subject>Acrylic acid</subject><subject>Acrylics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition effects</subject><subject>Copolymerization</subject><subject>Crosslinking</subject><subject>Crystal structure</subject><subject>Elongation</subject><subject>Energy dissipation</subject><subject>Freezing</subject><subject>Healing</subject><subject>Hydrogels</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Information dissemination</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Polyvinyl alcohol</subject><subject>Segments</subject><subject>Tensile strength</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1UMtKBDEQHETB5wd4C3jRQzSdmSSTo4gvELzoOWQyiRvNTsZkVpgP8X_N7nrwIjRUd1NVTVdVnQK5BELEVQYiOcMEBAbaNpjvVAfABMWtrNlu6QmlWApO9qvDnN8JYUzw9qD6vnXOmimj6JCJyzFmP_k4oFLTwqIxxdGmydsNoV_pgMbFnL3RIczIpJgzDn74sD1azH2Kbzb82pRNUYwxzF9-mAPSwcRFLDj0my061ybNQS99b7GJeDN5g7Tx_cVxted0yPbkF4-q17vbl5sH_PR8_3hz_YRNDXzCsmOyAWPBNAANpYQJwdqm6wlI0zphaxCkAyFE1_GaO90DlY44IFoAJ64-qs62vuXPz5XNk3qPqzSUkwokpZQzDrKwYMva_JusU2PyS51mBUSt01fb9FVJX63TV7xo6FaTC3d4s-mP87-iH8YQiaw</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Gong, Zhengyu</creator><creator>Niu, Fangfang</creator><creator>Zhang, Guoping</creator><creator>Li, Jinhui</creator><creator>Li, Gang</creator><creator>Huang, Wangping</creator><creator>Deng, Hai</creator><creator>Sun, Rong</creator><creator>Wong, Chingping</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20170801</creationdate><title>Effects of composition on the properties of dual physically cross-linked hydrogel composed of polyvinyl alcohol and poly (acrylamide-co-acrylic acid)</title><author>Gong, Zhengyu ; Niu, Fangfang ; Zhang, Guoping ; Li, Jinhui ; Li, Gang ; Huang, Wangping ; Deng, Hai ; Sun, Rong ; Wong, Chingping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-9b5941ce1c4114220577584bd019c8f7e3170b1777bb636fad129f0f10a7160f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acrylamide</topic><topic>Acrylic acid</topic><topic>Acrylics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition effects</topic><topic>Copolymerization</topic><topic>Crosslinking</topic><topic>Crystal structure</topic><topic>Elongation</topic><topic>Energy dissipation</topic><topic>Freezing</topic><topic>Healing</topic><topic>Hydrogels</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Information dissemination</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><topic>Polyvinyl alcohol</topic><topic>Segments</topic><topic>Tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gong, Zhengyu</creatorcontrib><creatorcontrib>Niu, Fangfang</creatorcontrib><creatorcontrib>Zhang, Guoping</creatorcontrib><creatorcontrib>Li, Jinhui</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Huang, Wangping</creatorcontrib><creatorcontrib>Deng, Hai</creatorcontrib><creatorcontrib>Sun, Rong</creatorcontrib><creatorcontrib>Wong, Chingping</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gong, Zhengyu</au><au>Niu, Fangfang</au><au>Zhang, Guoping</au><au>Li, Jinhui</au><au>Li, Gang</au><au>Huang, Wangping</au><au>Deng, Hai</au><au>Sun, Rong</au><au>Wong, Chingping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of composition on the properties of dual physically cross-linked hydrogel composed of polyvinyl alcohol and poly (acrylamide-co-acrylic acid)</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>24</volume><issue>8</issue><spage>1</spage><pages>1-</pages><artnum>127</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>In previous work, we have developed a dual physically cross-linked hydrogel composed of poly (acrylamide-co-acrylic acid) (PAM-co-PAA) and polyvinyl alcohol (PVA), named as PVA/CP DN gel, by facile copolymerization and freezing/thawing. The PVA/CP DN gel is featuring both excellent mechanical properties and self-healing ability. Additionally, we have preliminarily found that the comonomer ratio for PVA/CP DN gel have great influence on the self-healing efficiency. In this research article, we will further discuss the mechanical and self-healing properties of the PVA/CP DN gel by varying the comonomer ratio of PAM-co-PAA. The results proved that the structure of DN will be loosen when the number of PAA segments exceed that of PAM. More PAA segments in copolymer make the PVA/CP DN gel have better elongation at break but weak in tensile strength and young’s modulus because of less PVA crystalline domains formed in the gel. The energy dissipation value for the double-network hydrogel decrease with the addition of PAA segments, whereas self-healing efficiency of PVA/CP DN gel increased. Anyway, this work provides more information to further understand the effects of composition on the properties of dual physically cross-linked PVA/CP DN hydrogel.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-017-1284-6</doi></addata></record> |
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| subjects | Acrylamide Acrylic acid Acrylics Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Composition effects Copolymerization Crosslinking Crystal structure Elongation Energy dissipation Freezing Healing Hydrogels Industrial Chemistry/Chemical Engineering Information dissemination Mechanical properties Modulus of elasticity Original Paper Polymer Sciences Polyvinyl alcohol Segments Tensile strength |
| title | Effects of composition on the properties of dual physically cross-linked hydrogel composed of polyvinyl alcohol and poly (acrylamide-co-acrylic acid) |
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