Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries
In order to improve electrochemical performance of inert SiO 2 anode for lithium ion batteries, submicro-sized porous SiO 2 /C and SiO 2 /C/graphene spheres with the same SiO 2 content (43 wt.%) have been synthesized through a simple suspension nebulization and spray pyrolysis method followed by car...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2017-08, Vol.21 (8), p.2425-2432 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Xiang, Zhiming Chen, Yuxi Li, Jin Xia, Xiaohong He, Yuede Liu, Hongbo |
| description | In order to improve electrochemical performance of inert SiO
2
anode for lithium ion batteries, submicro-sized porous SiO
2
/C and SiO
2
/C/graphene spheres with the same SiO
2
content (43 wt.%) have been synthesized through a simple suspension nebulization and spray pyrolysis method followed by carbonization, where the components of the spheres are mixed uniformly. The addition of graphene results in mesoporous structure of the SiO
2
/C/graphene spheres. The electrochemical performances of the porous SiO
2
/C and SiO
2
/C/graphene spheres have been evaluated, which indicate that the SiO
2
/C/graphene spheres exhibits much higher cyclic capacity and stability than SiO
2
/C with reversible capacity retention of 97% over 100 cycles. The graphene additives display very strong effects in reducing charge transfer resistance and improving structural stability of the porous spheres simultaneously. The mesoporous SiO
2
/C/graphene spheres are promising anode candidate for high energy-density lithium ion batteries.
Graphical abstract
ᅟ |
| doi_str_mv | 10.1007/s10008-017-3566-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1921207565</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1921207565</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-9f155222e4d754a452f86a0fa2bb58ca115a2761388d933f4259ae5ee4a2856b3</originalsourceid><addsrcrecordid>eNp1ULtOAzEQtBBIhMAH0FmiNvHbvhJFvKRIkQjUli9nJ46S82HfFfD1OFwKGpqdKWZmdweAW4LvCcZqlsvEGmGiEBNSInUGJoQzhrCS-vyXU6S51pfgKucdLkJJ8AS8rYb6ENYpohy-XQO7mOKQ4Sos6WwObduc6GyTbLd1rYO5QHIZ-pjgPvTbMBxgiC2sbd-7FFy-Bhfe7rO7OeEUfDw9vs9f0GL5_Dp_WKA1E6xHlSdCUEodb5TglgvqtbTYW1rXQq8tIcLSciTTuqkY85yKyjrhHLdUC1mzKbgbc7sUPweXe7OLQ2rLSkMqSihWQoqiIqOq_Jhzct50KRxs-jIEm2N1ZqzOlEbMsTqjioeOnly07calP8n_mn4ARglvcA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1921207565</pqid></control><display><type>article</type><title>Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries</title><source>SpringerLink Journals - AutoHoldings</source><creator>Xiang, Zhiming ; Chen, Yuxi ; Li, Jin ; Xia, Xiaohong ; He, Yuede ; Liu, Hongbo</creator><creatorcontrib>Xiang, Zhiming ; Chen, Yuxi ; Li, Jin ; Xia, Xiaohong ; He, Yuede ; Liu, Hongbo</creatorcontrib><description>In order to improve electrochemical performance of inert SiO
2
anode for lithium ion batteries, submicro-sized porous SiO
2
/C and SiO
2
/C/graphene spheres with the same SiO
2
content (43 wt.%) have been synthesized through a simple suspension nebulization and spray pyrolysis method followed by carbonization, where the components of the spheres are mixed uniformly. The addition of graphene results in mesoporous structure of the SiO
2
/C/graphene spheres. The electrochemical performances of the porous SiO
2
/C and SiO
2
/C/graphene spheres have been evaluated, which indicate that the SiO
2
/C/graphene spheres exhibits much higher cyclic capacity and stability than SiO
2
/C with reversible capacity retention of 97% over 100 cycles. The graphene additives display very strong effects in reducing charge transfer resistance and improving structural stability of the porous spheres simultaneously. The mesoporous SiO
2
/C/graphene spheres are promising anode candidate for high energy-density lithium ion batteries.
Graphical abstract
ᅟ</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-017-3566-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Additives ; Analytical Chemistry ; Anodes ; Carbonization ; Characterization and Evaluation of Materials ; Charge transfer ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemical analysis ; Electrochemistry ; Energy Storage ; Graphene ; Ions ; Lithium ; Lithium-ion batteries ; Original Paper ; Physical Chemistry ; Rechargeable batteries ; Silicon dioxide ; Spray pyrolysis ; Structural stability</subject><ispartof>Journal of solid state electrochemistry, 2017-08, Vol.21 (8), p.2425-2432</ispartof><rights>Springer-Verlag Berlin Heidelberg 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-9f155222e4d754a452f86a0fa2bb58ca115a2761388d933f4259ae5ee4a2856b3</citedby><cites>FETCH-LOGICAL-c353t-9f155222e4d754a452f86a0fa2bb58ca115a2761388d933f4259ae5ee4a2856b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-017-3566-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-017-3566-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Xiang, Zhiming</creatorcontrib><creatorcontrib>Chen, Yuxi</creatorcontrib><creatorcontrib>Li, Jin</creatorcontrib><creatorcontrib>Xia, Xiaohong</creatorcontrib><creatorcontrib>He, Yuede</creatorcontrib><creatorcontrib>Liu, Hongbo</creatorcontrib><title>Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>In order to improve electrochemical performance of inert SiO
2
anode for lithium ion batteries, submicro-sized porous SiO
2
/C and SiO
2
/C/graphene spheres with the same SiO
2
content (43 wt.%) have been synthesized through a simple suspension nebulization and spray pyrolysis method followed by carbonization, where the components of the spheres are mixed uniformly. The addition of graphene results in mesoporous structure of the SiO
2
/C/graphene spheres. The electrochemical performances of the porous SiO
2
/C and SiO
2
/C/graphene spheres have been evaluated, which indicate that the SiO
2
/C/graphene spheres exhibits much higher cyclic capacity and stability than SiO
2
/C with reversible capacity retention of 97% over 100 cycles. The graphene additives display very strong effects in reducing charge transfer resistance and improving structural stability of the porous spheres simultaneously. The mesoporous SiO
2
/C/graphene spheres are promising anode candidate for high energy-density lithium ion batteries.
Graphical abstract
ᅟ</description><subject>Additives</subject><subject>Analytical Chemistry</subject><subject>Anodes</subject><subject>Carbonization</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charge transfer</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Graphene</subject><subject>Ions</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Silicon dioxide</subject><subject>Spray pyrolysis</subject><subject>Structural stability</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1ULtOAzEQtBBIhMAH0FmiNvHbvhJFvKRIkQjUli9nJ46S82HfFfD1OFwKGpqdKWZmdweAW4LvCcZqlsvEGmGiEBNSInUGJoQzhrCS-vyXU6S51pfgKucdLkJJ8AS8rYb6ENYpohy-XQO7mOKQ4Sos6WwObduc6GyTbLd1rYO5QHIZ-pjgPvTbMBxgiC2sbd-7FFy-Bhfe7rO7OeEUfDw9vs9f0GL5_Dp_WKA1E6xHlSdCUEodb5TglgvqtbTYW1rXQq8tIcLSciTTuqkY85yKyjrhHLdUC1mzKbgbc7sUPweXe7OLQ2rLSkMqSihWQoqiIqOq_Jhzct50KRxs-jIEm2N1ZqzOlEbMsTqjioeOnly07calP8n_mn4ARglvcA</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Xiang, Zhiming</creator><creator>Chen, Yuxi</creator><creator>Li, Jin</creator><creator>Xia, Xiaohong</creator><creator>He, Yuede</creator><creator>Liu, Hongbo</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170801</creationdate><title>Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries</title><author>Xiang, Zhiming ; Chen, Yuxi ; Li, Jin ; Xia, Xiaohong ; He, Yuede ; Liu, Hongbo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-9f155222e4d754a452f86a0fa2bb58ca115a2761388d933f4259ae5ee4a2856b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Additives</topic><topic>Analytical Chemistry</topic><topic>Anodes</topic><topic>Carbonization</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charge transfer</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Graphene</topic><topic>Ions</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Silicon dioxide</topic><topic>Spray pyrolysis</topic><topic>Structural stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiang, Zhiming</creatorcontrib><creatorcontrib>Chen, Yuxi</creatorcontrib><creatorcontrib>Li, Jin</creatorcontrib><creatorcontrib>Xia, Xiaohong</creatorcontrib><creatorcontrib>He, Yuede</creatorcontrib><creatorcontrib>Liu, Hongbo</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiang, Zhiming</au><au>Chen, Yuxi</au><au>Li, Jin</au><au>Xia, Xiaohong</au><au>He, Yuede</au><au>Liu, Hongbo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2017-08-01</date><risdate>2017</risdate><volume>21</volume><issue>8</issue><spage>2425</spage><epage>2432</epage><pages>2425-2432</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>In order to improve electrochemical performance of inert SiO
2
anode for lithium ion batteries, submicro-sized porous SiO
2
/C and SiO
2
/C/graphene spheres with the same SiO
2
content (43 wt.%) have been synthesized through a simple suspension nebulization and spray pyrolysis method followed by carbonization, where the components of the spheres are mixed uniformly. The addition of graphene results in mesoporous structure of the SiO
2
/C/graphene spheres. The electrochemical performances of the porous SiO
2
/C and SiO
2
/C/graphene spheres have been evaluated, which indicate that the SiO
2
/C/graphene spheres exhibits much higher cyclic capacity and stability than SiO
2
/C with reversible capacity retention of 97% over 100 cycles. The graphene additives display very strong effects in reducing charge transfer resistance and improving structural stability of the porous spheres simultaneously. The mesoporous SiO
2
/C/graphene spheres are promising anode candidate for high energy-density lithium ion batteries.
Graphical abstract
ᅟ</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-017-3566-7</doi><tpages>8</tpages></addata></record> |
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| language | eng |
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| subjects | Additives Analytical Chemistry Anodes Carbonization Characterization and Evaluation of Materials Charge transfer Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemical analysis Electrochemistry Energy Storage Graphene Ions Lithium Lithium-ion batteries Original Paper Physical Chemistry Rechargeable batteries Silicon dioxide Spray pyrolysis Structural stability |
| title | Submicro-sized porous SiO2/C and SiO2/C/graphene spheres for lithium ion batteries |
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