Frontispiece: Bimetallic Cooperativity in Proton Reduction with an Amido‐Bridged Cobalt Catalyst

The bimetallic catalyst [CoII2(L1)(bpy)2]ClO4 (1) was investigated both experimentally and theoretically to probe the cooperative activity among the cobalt centers toward proton reduction to dihydrogen. Mechanistically, a [CoICoI] core acts by protonation of one CoI center that triggers a sequential...

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Veröffentlicht in:	Chemistry : a European journal 2017-07, Vol.23 (39), p.n/a
Hauptverfasser:	Kpogo, Kenneth K., Mazumder, Shivnath, Wang, Denan, Schlegel, H. Bernhard, Fiedler, Adam T., Verani, Cláudio N.
Format:	Artikel
Sprache:	eng
Schlagworte:	bimetallic complexes bimetallic cooperativity Bimetals Catalysts Chemistry Cobalt CoII–H− species Cooperativity Hydrogen proton reduction Protonation Proximity Reduction Topology
Online-Zugang:	Volltext
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