Selective Trifluoromethylthiolation and Trifluoromethylsulfinylation of Indoles with Sodium Trifluoromethanesulfinate Promoted by Phosphorus Reagents

Direct trifluoromethylthiolation and trifluoromethylsulfinylation reactions by using sodium trifluoromethanesulfinate were promoted by different phosphorus reagents to selectively occur under mild and transition‐metal‐free conditions. In the presence of phosphorus trichloride, sodium trifluoromethan...

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Veröffentlicht in:	European journal of organic chemistry 2017-06, Vol.2017 (24), p.3505-3511
Hauptverfasser:	Sun, Dong‐Wei, Jiang, Xu, Jiang, Min, Lin, Yun, Liu, Jin‐Tao
Format:	Artikel
Sprache:	eng
Schlagworte:	Derivatives Fluorinated compounds Fluorine Indoles Nitrogen heterocycles Phosphorus Reagents Sodium Sulfinates Synthetic methods
Online-Zugang:	Volltext
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