Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye
One new polymerizable fluorescent disperse dye (PEANI) based on 1,8-naphthalimide was synthesized via reaction of 2-(2-hydroxyethyl)-6-(1-pyrrolidinyl)-1H-benzo [de]isoquinoline-1,3(2H)-dione (PAENI) with acryloyl chloride firstly. Dye’s structure and fluorescent properties were carefully investigat...
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| Veröffentlicht in: | Fibers and polymers 2017-06, Vol.18 (6), p.1017-1024 |
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| creator | Bao, Zhimin Lu, Chuchu Qin, Chuanxiang Tang, Sonsong Dai, Lixing Chen, Guoqiang Mei, Feng |
| description | One new polymerizable fluorescent disperse dye (PEANI) based on 1,8-naphthalimide was synthesized via reaction of 2-(2-hydroxyethyl)-6-(1-pyrrolidinyl)-1H-benzo [de]isoquinoline-1,3(2H)-dione (PAENI) with acryloyl chloride firstly. Dye’s structure and fluorescent properties were carefully investigated using nuclear magnetic resonance (
1
H-NMR), UV-Vis and fluorescent spectra. Then the yellow copolymer (F-PAN) of PEANI and acrylonitrile was obtained through radical polymerization. Fluorescent nanofiber membrane could be prepared by electrospinning of the F-PAN solution in N,N-dimethylformamide solvent and strong green fluorescent emission located around 510 nm could be found (λ
ex
=450 nm). The electrospun F-PAN membrane showed obvious fluorescent effect even the mass ratio of PEANI to acrylonitrile was only 0.1 %, which has broken through the traditional limitation of using the cationic dye involved in the dyeing procedure to obtain fluorescent acrylic fabrics. |
| doi_str_mv | 10.1007/s12221-017-7053-7 |
| format | Article |
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1
H-NMR), UV-Vis and fluorescent spectra. Then the yellow copolymer (F-PAN) of PEANI and acrylonitrile was obtained through radical polymerization. Fluorescent nanofiber membrane could be prepared by electrospinning of the F-PAN solution in N,N-dimethylformamide solvent and strong green fluorescent emission located around 510 nm could be found (λ
ex
=450 nm). The electrospun F-PAN membrane showed obvious fluorescent effect even the mass ratio of PEANI to acrylonitrile was only 0.1 %, which has broken through the traditional limitation of using the cationic dye involved in the dyeing procedure to obtain fluorescent acrylic fabrics.</description><identifier>ISSN: 1229-9197</identifier><identifier>EISSN: 1875-0052</identifier><identifier>DOI: 10.1007/s12221-017-7053-7</identifier><language>eng</language><publisher>Seoul: The Korean Fiber Society</publisher><subject>Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chlorides ; Dispersion ; Dyeing ; Dyes ; Electrospinning ; Emission ; Fabrics ; Fluorescence ; Magnetic properties ; NMR ; Nuclear magnetic resonance ; Polyacrylonitrile ; Polymer Sciences ; Polymerization ; Textile composites</subject><ispartof>Fibers and polymers, 2017-06, Vol.18 (6), p.1017-1024</ispartof><rights>The Korean Fiber Society and Springer Science+Business Media B.V. 2017</rights><rights>Fibers and Polymers is a copyright of Springer, 2017.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-b58047fe30c5abcb26bd6807aa8f10978a26a9e64899a94ada212afd0fcbca253</citedby><cites>FETCH-LOGICAL-c353t-b58047fe30c5abcb26bd6807aa8f10978a26a9e64899a94ada212afd0fcbca253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12221-017-7053-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12221-017-7053-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Bao, Zhimin</creatorcontrib><creatorcontrib>Lu, Chuchu</creatorcontrib><creatorcontrib>Qin, Chuanxiang</creatorcontrib><creatorcontrib>Tang, Sonsong</creatorcontrib><creatorcontrib>Dai, Lixing</creatorcontrib><creatorcontrib>Chen, Guoqiang</creatorcontrib><creatorcontrib>Mei, Feng</creatorcontrib><title>Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye</title><title>Fibers and polymers</title><addtitle>Fibers Polym</addtitle><description>One new polymerizable fluorescent disperse dye (PEANI) based on 1,8-naphthalimide was synthesized via reaction of 2-(2-hydroxyethyl)-6-(1-pyrrolidinyl)-1H-benzo [de]isoquinoline-1,3(2H)-dione (PAENI) with acryloyl chloride firstly. Dye’s structure and fluorescent properties were carefully investigated using nuclear magnetic resonance (
1
H-NMR), UV-Vis and fluorescent spectra. Then the yellow copolymer (F-PAN) of PEANI and acrylonitrile was obtained through radical polymerization. Fluorescent nanofiber membrane could be prepared by electrospinning of the F-PAN solution in N,N-dimethylformamide solvent and strong green fluorescent emission located around 510 nm could be found (λ
ex
=450 nm). The electrospun F-PAN membrane showed obvious fluorescent effect even the mass ratio of PEANI to acrylonitrile was only 0.1 %, which has broken through the traditional limitation of using the cationic dye involved in the dyeing procedure to obtain fluorescent acrylic fabrics.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Dispersion</subject><subject>Dyeing</subject><subject>Dyes</subject><subject>Electrospinning</subject><subject>Emission</subject><subject>Fabrics</subject><subject>Fluorescence</subject><subject>Magnetic properties</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polyacrylonitrile</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Textile composites</subject><issn>1229-9197</issn><issn>1875-0052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kLlOxDAURSMEEsPyAXSRaDHYzuK4RCM2aSQooLaek2fGo8QOdqYIHX9OolBAQeVXnHMtnSS5YPSaUSpuIuOcM0KZIIIWGREHyYpVoiCUFvxwujmXRDIpjpOTGHeUloyLbJV8vQTsIcBgvUu9SU279wFjjW5Ie9-OUIex9c4OwbaYOnDeWI0h7bDTARymGiI26STPdIfBfoKeSHZVEQf9dthCazvb4J_lxsYeQ8S0GfEsOTLQRjz_eU-Tt_u71_Uj2Tw_PK1vN6TOimwguqhoLgxmtC5A15qXuikrKgAqw6gUFfASJJZ5JSXIHBrgjINpqKl1DbzITpPLZbcP_mOPcVA7vw9u-lIxyXIqWVbNFFuoOvgYAxrVB9tBGBWjai6tltJqKq3m0kpMDl-cOLHuHcOv5X-lb7CYhLM</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Bao, Zhimin</creator><creator>Lu, Chuchu</creator><creator>Qin, Chuanxiang</creator><creator>Tang, Sonsong</creator><creator>Dai, Lixing</creator><creator>Chen, Guoqiang</creator><creator>Mei, Feng</creator><general>The Korean Fiber Society</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20170601</creationdate><title>Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye</title><author>Bao, Zhimin ; Lu, Chuchu ; Qin, Chuanxiang ; Tang, Sonsong ; Dai, Lixing ; Chen, Guoqiang ; Mei, Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-b58047fe30c5abcb26bd6807aa8f10978a26a9e64899a94ada212afd0fcbca253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Dispersion</topic><topic>Dyeing</topic><topic>Dyes</topic><topic>Electrospinning</topic><topic>Emission</topic><topic>Fabrics</topic><topic>Fluorescence</topic><topic>Magnetic properties</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polyacrylonitrile</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Textile composites</topic><toplevel>online_resources</toplevel><creatorcontrib>Bao, Zhimin</creatorcontrib><creatorcontrib>Lu, Chuchu</creatorcontrib><creatorcontrib>Qin, Chuanxiang</creatorcontrib><creatorcontrib>Tang, Sonsong</creatorcontrib><creatorcontrib>Dai, Lixing</creatorcontrib><creatorcontrib>Chen, Guoqiang</creatorcontrib><creatorcontrib>Mei, Feng</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Fibers and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bao, Zhimin</au><au>Lu, Chuchu</au><au>Qin, Chuanxiang</au><au>Tang, Sonsong</au><au>Dai, Lixing</au><au>Chen, Guoqiang</au><au>Mei, Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye</atitle><jtitle>Fibers and polymers</jtitle><stitle>Fibers Polym</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>18</volume><issue>6</issue><spage>1017</spage><epage>1024</epage><pages>1017-1024</pages><issn>1229-9197</issn><eissn>1875-0052</eissn><abstract>One new polymerizable fluorescent disperse dye (PEANI) based on 1,8-naphthalimide was synthesized via reaction of 2-(2-hydroxyethyl)-6-(1-pyrrolidinyl)-1H-benzo [de]isoquinoline-1,3(2H)-dione (PAENI) with acryloyl chloride firstly. Dye’s structure and fluorescent properties were carefully investigated using nuclear magnetic resonance (
1
H-NMR), UV-Vis and fluorescent spectra. Then the yellow copolymer (F-PAN) of PEANI and acrylonitrile was obtained through radical polymerization. Fluorescent nanofiber membrane could be prepared by electrospinning of the F-PAN solution in N,N-dimethylformamide solvent and strong green fluorescent emission located around 510 nm could be found (λ
ex
=450 nm). The electrospun F-PAN membrane showed obvious fluorescent effect even the mass ratio of PEANI to acrylonitrile was only 0.1 %, which has broken through the traditional limitation of using the cationic dye involved in the dyeing procedure to obtain fluorescent acrylic fabrics.</abstract><cop>Seoul</cop><pub>The Korean Fiber Society</pub><doi>10.1007/s12221-017-7053-7</doi><tpages>8</tpages></addata></record> |
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| subjects | Chemical synthesis Chemistry Chemistry and Materials Science Chlorides Dispersion Dyeing Dyes Electrospinning Emission Fabrics Fluorescence Magnetic properties NMR Nuclear magnetic resonance Polyacrylonitrile Polymer Sciences Polymerization Textile composites |
| title | Preparation of fluorescent polyacrylonitrile nanofiber membrane based on polymerizable 1,8-naphthalimide fluorescent disperse dye |
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