Structure of a trinuclear μ3-vinylidene cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6

Structure of a trinuclear μ3-vinylidene cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6

The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ 3 -C=CHPh)(PPh 3 )(CO) 6 is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å 3 , space group C 2/ c , Z = 8, d calc =...

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Veröffentlicht in:Journal of structural chemistry 2017-05, Vol.58 (3), p.600-602
Hauptverfasser: Chudin, O. S., Verpekin, V. V., Vasiliev, A. D., Rubaylo, A. I.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Bridging
Brief Communications
Chemistry
Chemistry and Materials Science
Clusters
Crystallography
Diffraction
Inorganic Chemistry
Iron
Manganese
Molecular
Optical and Plasma Physics
Physical Chemistry
Platinum
Solid State Physics
Vanadium
Vinylidene
X-ray diffraction
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Zusammenfassung:The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ 3 -C=CHPh)(PPh 3 )(CO) 6 is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å 3 , space group C 2/ c , Z = 8, d calc = 1.741 g/cm 3 . The cluster molecule contains a bridging phenylvinylidene ligand coordinated to a metallic core in the form of a Mn–Fe–Pt chain (the Mn–Fe and Fe–Pt bond lengths are 2.6768(14) Å and 2.6280(11) Å respectively and the Mn⋯Pt distance is 3.6425(19) Å).
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476617030234