The Effect of trans Ligands in the NO‐Linkage Reverse Isomerization for Ruthenium–Nitrosyl–Tetraammine Complexes: A DFT Study

The rearrangement of the NO ligand in ruthenium–nitrosyl–tetraammine complexes trans‐[Ru(NO)(NH3)4X]2+ (X = F–, Cl–, OH–, SH–) has been studied for metastable oxygen‐coordinated NO complexes by means of DFT. On the basis of obtained data, this rearrangement is concluded to be caused by ligand‐to‐met...

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