[Pt(SCN)4]2–‐Based Coordination Polymers and Supramolecular Squares: Intermolecular Pt···H–C Interactions Probed by Luminescence Spectroscopy at Variable Pressure

The structures of four types of supramolecular systems containing [Pt(SCN)4]2– molecular units have been characterized. [Mn(bipy)2Pt(SCN)4]2·2MeOH (1) and [Zn(bipy)2Pt(SCN)4]2·2MeOH (2) show cis‐thiocyanato ligands bridging the PtII and MnII or ZnII ions, leading to a molecular square motif. [Zn(bip...

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Veröffentlicht in:	European journal of inorganic chemistry 2017-06, Vol.2017 (22), p.2865-2875
Hauptverfasser:	Suffren, Yan, Kobayashi, Masayuki, Ovens, Jeffrey S., Rodrigue‐Witchel, Alexandre, Genre, Caroline, Sakai, Ken, Reber, Christian, Leznoff, Daniel B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Agostic interactions Bridging Chains (polymeric) Compressing Coordination polymers Electronic structure High‐pressure chemistry Inorganic chemistry Lead Ligands Luminescence Maxima Molecular structure Platinum Polymers Spectra Spectroscopy Spectrum analysis Structure elucidation
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