Cover Picture: Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal-Organic Framework Matrices (Chem. Eur. J. 19/2016)
Inorganic molecular oxides—also called polyoxometalates (POMs)—possess a high thermal and chemical stability, a major advantage for the further processing of these species. This feature has been exploited for the incorporation of single‐molecule magnet POMs in supports with very different characteri...
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| Veröffentlicht in: | Chemistry : a European journal 2016-05, Vol.22 (19), p.6409-6409 |
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| container_title | Chemistry : a European journal |
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| creator | Salomon, William Lan, Yanhua Rivière, Eric Yang, Shu Roch-Marchal, Catherine Dolbecq, Anne Simonnet-Jégat, Corine Steunou, Nathalie Leclerc-Laronze, Nathalie Ruhlmann, Laurent Mallah, Talal Wernsdorfer, Wolfgang Mialane, Pierre |
| description | Inorganic molecular oxides—also called polyoxometalates (POMs)—possess a high thermal and chemical stability, a major advantage for the further processing of these species. This feature has been exploited for the incorporation of single‐molecule magnet POMs in supports with very different characteristics (amorphous vs. crystalline; diamagnetic vs. paramagnetic). It is shown that with a judicious choice of the matrix, the single‐molecule magnet properties of the embedded and well‐isolated molecules are very close to those of a crystal. More information can be found in the Full Paper by T. Mallah, W. Wernsdorfer, P. Mialane et al. on page 6564 ff. |
| doi_str_mv | 10.1002/chem.201601356 |
| format | Article |
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| subjects | Aluminum biopolymers Chemistry Corrosion resistance Crystal structure Diamagnetism Magnetic properties Matrices (mathematics) metal-organic frameworks Metals Oxides polyoxometalates Polyoxometallates Stability Temporal variations Visual stimuli |
| title | Cover Picture: Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal-Organic Framework Matrices (Chem. Eur. J. 19/2016) |
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