A Boryl-Substituted Diphosphene: Synthesis, Structure, and Reaction with n-Butyllithium To Form a Stabilized Adduct by p[pi]-p[pi] Interaction

A boryl-substituted diphosphene was synthesized through the nucleophilic borylation of PCl3 with a borylzinc reagent, followed by a reduction with Mg. A combined analysis of the resulting diboryldiphosphene by single-crystal X-ray diffraction, DFT calculations, and UV/Vis spectroscopy revealed a σ-e...

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Veröffentlicht in:	Angewandte Chemie 2016-10, Vol.128 (41), p.13019
Hauptverfasser:	Asami, Shun-suke, Okamoto, Masafumi, Suzuki, Katsunori, Yamashita, Makoto
Format:	Artikel
Sprache:	ger
Schlagworte:	Butyllithium Chemical synthesis Chemistry Crystals Diffraction Mathematical analysis Single crystals Spectroscopy X-ray diffraction
Online-Zugang:	Volltext
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