Cluster Fusion: Face-Fused Nine-Atom Deltahedral Clusters in [Sn14Ni(CO)]4

The title anion was synthesized by heating dimethylformamide (DMF) solution of the known Ni‐centered and Ni(CO)‐capped tin clusters [Ni@Sn9Ni(CO)]3−. The new anion represents the first example of face‐fused nine‐atom molecular clusters. The two clusters are identical elongated tricapped trigonal pri...

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