Controlling the Atomic Structure of Au30 Nanoclusters by a Ligand-Based Strategy

We report the X‐ray structure of a gold nanocluster with 30 gold atoms protected by 18 1‐adamantanethiolate ligands (formulated as Au30(S‐Adm)18). This nanocluster exhibits a threefold rotationally symmetrical, hexagonal‐close‐packed (HCP) Au18 kernel protected by six dimeric Au2(SR)3 staple motifs....

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-06, Vol.55 (23), p.6694-6697
Hauptverfasser:	Higaki, Tatsuya, Liu, Chong, Zeng, Chenjie, Jin, Renxi, Chen, Yuxiang, Rosi, Nathaniel L., Jin, Rongchao
Format:	Artikel
Sprache:	eng
Schlagworte:	Alloys Atomic structure Benzene Close packed lattices Clusters Face centered cubic lattice Gold Ligands Nanoclusters Nanostructure nanostructures Solubility Solvents Strategy thiols
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