A Boryl-Substituted Diphosphene: Synthesis, Structure, and Reaction with n-Butyllithium To Form a Stabilized Adduct by p[pi]-p[pi] Interaction

A boryl-substituted diphosphene was synthesized through the nucleophilic borylation of PCl3 with a borylzinc reagent, followed by a reduction with Mg. A combined analysis of the resulting diboryldiphosphene by single-crystal X-ray diffraction, DFT calculations, and UV/Vis spectroscopy revealed a σ-e...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2016-10, Vol.55 (41), p.12827
Hauptverfasser:	Asami, Shun-suke, Okamoto, Masafumi, Suzuki, Katsunori, Yamashita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Butyllithium Chemical synthesis Crystals Diffraction Mathematical analysis Single crystals Spectroscopy Ultraviolet spectroscopy X-ray diffraction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!