ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification
Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites co...
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Veröffentlicht in: | Journal of the American Ceramic Society 2016-02, Vol.99 (2), p.667-673 |
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creator | Cheng, Eric Jianfeng Katsui, Hirokazu Goto, Takashi |
description | Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites containing 50 mol% of ZrB2 (irrespective of the ZrC/ZrN ratio) showed rod‐like eutectic structures, where ZrCxN1−x single‐crystalline rods were dispersed in the ZrB2 single‐crystalline matrices. Multiple orientation relationships between the ZrCxN1−x rods and the ZrB2 matrices were observed, and one was determined as ZrB2 {
01
1
¯
0
} //ZrxN1−x {111} and ZrB2 <
2
1
¯
1
¯
0
> //ZrCxN1−x <
10
1
¯
> . The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa. |
doi_str_mv | 10.1111/jace.13984 |
format | Article |
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01
1
¯
0
} //ZrxN1−x {111} and ZrB2 <
2
1
¯
1
¯
0
> //ZrCxN1−x <
10
1
¯
> . The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.13984</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Columbus: Blackwell Publishing Ltd</publisher><subject>Alloys ; Ceramics ; Composite materials ; Crystal structure ; Diamond pyramid hardness ; Dispersion ; Electric arc melting ; Eutectic composites ; Eutectic composition ; Matrices (mathematics) ; Mechanical properties ; Microstructure ; Orientation relationships ; Particulate composites ; Rods ; Single crystals ; Solidification</subject><ispartof>Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.667-673</ispartof><rights>2015 The American Ceramic Society</rights><rights>2016 American Ceramic Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.13984$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.13984$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><contributor>Dickey, E.</contributor><creatorcontrib>Cheng, Eric Jianfeng</creatorcontrib><creatorcontrib>Katsui, Hirokazu</creatorcontrib><creatorcontrib>Goto, Takashi</creatorcontrib><title>ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification</title><title>Journal of the American Ceramic Society</title><addtitle>J. Am. Ceram. Soc</addtitle><description>Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites containing 50 mol% of ZrB2 (irrespective of the ZrC/ZrN ratio) showed rod‐like eutectic structures, where ZrCxN1−x single‐crystalline rods were dispersed in the ZrB2 single‐crystalline matrices. Multiple orientation relationships between the ZrCxN1−x rods and the ZrB2 matrices were observed, and one was determined as ZrB2 {
01
1
¯
0
} //ZrxN1−x {111} and ZrB2 <
2
1
¯
1
¯
0
> //ZrCxN1−x <
10
1
¯
> . The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.</description><subject>Alloys</subject><subject>Ceramics</subject><subject>Composite materials</subject><subject>Crystal structure</subject><subject>Diamond pyramid hardness</subject><subject>Dispersion</subject><subject>Electric arc melting</subject><subject>Eutectic composites</subject><subject>Eutectic composition</subject><subject>Matrices (mathematics)</subject><subject>Mechanical properties</subject><subject>Microstructure</subject><subject>Orientation relationships</subject><subject>Particulate composites</subject><subject>Rods</subject><subject>Single crystals</subject><subject>Solidification</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kE1OwzAQhS0EEqWw4QSRWKd47MSOlyVqC6iUSvxU6sZKHEdySZtiJ6K9AWuOyElwW8SS2cw86XszmofQJeAe-LpeZEr3gIokOkIdiGMIiQB2jDoYYxLyhOBTdObcwkvwUAelc3tDwrlNNxP4_vzaBIO20aoxKkjr5bp2ptEumNq6aJUugnwbPOiqCZ7qyhSmNCprTL06RydlVjl98du76GU4eE5vw_Hj6C7tj0NDBY1C0ASYKvKi5CTnhVacA6aYiwTyjBCmcrwTMSm1KpNEcM5KRrGIvGZRAbSLrg5717Z-b7Vr5KJu7cqflCBwxLn_if1LcRZTxqJEeAoO1Iep9FaurVlmdisBy12Ocpej3Oco7_vpYD95T3jwGNfozZ8ns2-SccpjOZuM5DCZTUevcyqn9AdrpXXF</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Cheng, Eric Jianfeng</creator><creator>Katsui, Hirokazu</creator><creator>Goto, Takashi</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201602</creationdate><title>ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification</title><author>Cheng, Eric Jianfeng ; Katsui, Hirokazu ; Goto, Takashi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3934-1e216cdbdf72b7dec7710307981ba226cb0079852fecf889776f63094fec64d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Alloys</topic><topic>Ceramics</topic><topic>Composite materials</topic><topic>Crystal structure</topic><topic>Diamond pyramid hardness</topic><topic>Dispersion</topic><topic>Electric arc melting</topic><topic>Eutectic composites</topic><topic>Eutectic composition</topic><topic>Matrices (mathematics)</topic><topic>Mechanical properties</topic><topic>Microstructure</topic><topic>Orientation relationships</topic><topic>Particulate composites</topic><topic>Rods</topic><topic>Single crystals</topic><topic>Solidification</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Eric Jianfeng</creatorcontrib><creatorcontrib>Katsui, Hirokazu</creatorcontrib><creatorcontrib>Goto, Takashi</creatorcontrib><collection>Istex</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Eric Jianfeng</au><au>Katsui, Hirokazu</au><au>Goto, Takashi</au><au>Dickey, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification</atitle><jtitle>Journal of the American Ceramic Society</jtitle><addtitle>J. Am. Ceram. Soc</addtitle><date>2016-02</date><risdate>2016</risdate><volume>99</volume><issue>2</issue><spage>667</spage><epage>673</epage><pages>667-673</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites containing 50 mol% of ZrB2 (irrespective of the ZrC/ZrN ratio) showed rod‐like eutectic structures, where ZrCxN1−x single‐crystalline rods were dispersed in the ZrB2 single‐crystalline matrices. Multiple orientation relationships between the ZrCxN1−x rods and the ZrB2 matrices were observed, and one was determined as ZrB2 {
01
1
¯
0
} //ZrxN1−x {111} and ZrB2 <
2
1
¯
1
¯
0
> //ZrCxN1−x <
10
1
¯
> . The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.</abstract><cop>Columbus</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/jace.13984</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Alloys Ceramics Composite materials Crystal structure Diamond pyramid hardness Dispersion Electric arc melting Eutectic composites Eutectic composition Matrices (mathematics) Mechanical properties Microstructure Orientation relationships Particulate composites Rods Single crystals Solidification |
title | ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification |
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