ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification

Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites co...

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Veröffentlicht in:Journal of the American Ceramic Society 2016-02, Vol.99 (2), p.667-673
Hauptverfasser: Cheng, Eric Jianfeng, Katsui, Hirokazu, Goto, Takashi
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container_title Journal of the American Ceramic Society
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creator Cheng, Eric Jianfeng
Katsui, Hirokazu
Goto, Takashi
description Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites containing 50 mol% of ZrB2 (irrespective of the ZrC/ZrN ratio) showed rod‐like eutectic structures, where ZrCxN1−x single‐crystalline rods were dispersed in the ZrB2 single‐crystalline matrices. Multiple orientation relationships between the ZrCxN1−x rods and the ZrB2 matrices were observed, and one was determined as ZrB2 { 01 1 ¯ 0 } //ZrxN1−x {111} and ZrB2 < 2 1 ¯ 1 ¯ 0 > //ZrCxN1−x < 10 1 ¯ > . The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.
doi_str_mv 10.1111/jace.13984
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The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.13984</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Columbus: Blackwell Publishing Ltd</publisher><subject>Alloys ; Ceramics ; Composite materials ; Crystal structure ; Diamond pyramid hardness ; Dispersion ; Electric arc melting ; Eutectic composites ; Eutectic composition ; Matrices (mathematics) ; Mechanical properties ; Microstructure ; Orientation relationships ; Particulate composites ; Rods ; Single crystals ; Solidification</subject><ispartof>Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.667-673</ispartof><rights>2015 The American Ceramic Society</rights><rights>2016 American Ceramic Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.13984$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.13984$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><contributor>Dickey, E.</contributor><creatorcontrib>Cheng, Eric Jianfeng</creatorcontrib><creatorcontrib>Katsui, Hirokazu</creatorcontrib><creatorcontrib>Goto, Takashi</creatorcontrib><title>ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification</title><title>Journal of the American Ceramic Society</title><addtitle>J. Am. Ceram. Soc</addtitle><description>Ceramic eutectics are naturally occurring in‐situ composites and can offer superior mechanical properties. Here, ZrB2–ZrCxN1−x quasi‐binary ceramic eutectic composites were produced by arc‐melting a mixture of ZrB2, ZrC, and ZrN powders in an N2 atmosphere. The arc‐melted ZrB2–ZrCxN1−x composites containing 50 mol% of ZrB2 (irrespective of the ZrC/ZrN ratio) showed rod‐like eutectic structures, where ZrCxN1−x single‐crystalline rods were dispersed in the ZrB2 single‐crystalline matrices. Multiple orientation relationships between the ZrCxN1−x rods and the ZrB2 matrices were observed, and one was determined as ZrB2 { 01 1 ¯ 0 } //ZrxN1−x {111} and ZrB2 &lt; 2 1 ¯ 1 ¯ 0 &gt; //ZrCxN1−x &lt; 10 1 ¯ &gt; . 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The rod‐like eutectic composites had higher hardness than the hypo‐ and hypereutectic composites and the 50ZrB2–40ZrC–10ZrN (mol%) eutectic composite showed the highest Vickers hardness (Hv) of 19 GPa.</abstract><cop>Columbus</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/jace.13984</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
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source Wiley Online Library Journals Frontfile Complete
subjects Alloys
Ceramics
Composite materials
Crystal structure
Diamond pyramid hardness
Dispersion
Electric arc melting
Eutectic composites
Eutectic composition
Matrices (mathematics)
Mechanical properties
Microstructure
Orientation relationships
Particulate composites
Rods
Single crystals
Solidification
title ZrB2-ZrCxN1−x Eutectic Composites Produced by Melt Solidification
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