(Amido)‐ and (Chlorido)titanium and ‐zirconium Complexes Coordinated by ansa‐Bis(amidinate) Ligands with a Rigid o‐Phenylene Linker

Bis(amido)–TiIV and –ZrIV complexes stabilized by the bis(amidinate) ligands {C6H4‐1,2‐[NC(tBu)N(2,6‐R2C6H3)]2}M(NMe2)2 [M = ZrIV, R = Me (3), R = iPr (4); M = TiIV, R = Me (5), R = iPr (6)] and {C6H4‐1,2‐[NC(tBu)N(2,6‐Me2C6H3)]2}Zr(NMe2)3H (3·HNMe2) were prepared in fairly good yields by treating a...

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Veröffentlicht in:	European journal of inorganic chemistry 2017-05, Vol.2017 (20), p.2736-2744
Hauptverfasser:	Tolpygin, Aleksei O., Luconi, Lapo, Shavyrin, Andrei S., Tuci, Giulia, Cherkasov, Anton V., Rossin, Andrea, Fukin, Georgy K., Giambastiani, Giuliano, Trifonov, Alexander A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aniline Coordination modes Decomposition reactions Dichlorides Inorganic chemistry Ligands Mathematical models N ligands Nitrogen atoms Solid state Steric hindrance Titanium Toluene Zirconium Zirconium compounds
Online-Zugang:	Volltext
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