Pyrolyzed bacterial cellulose/graphene oxide sandwich interlayer for lithium–sulfur batteries
Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose（PBC）/graphene oxide（GO） composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bact...
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| Veröffentlicht in: | Rare metals 2017-05, Vol.36 (5), p.418-424 |
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| container_title | Rare metals |
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| creator | Shen, Yu-Di Xiao, Zhi-Chang Miao, Li-Xiao Kong, De-Bin Zheng, Xiao-Yu Chang, Yan-Hong Zhi, Lin-Jie |
| description | Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose（PBC）/graphene oxide（GO） composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bacterial cellulose（BC） network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries. |
| doi_str_mv | 10.1007/s12598-017-0906-9 |
| format | Article |
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The unique and delicate structure where three-dimensional interconnected bacterial cellulose（BC） network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries.</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-017-0906-9</identifier><language>eng</language><publisher>Beijing: Nonferrous Metals Society of China</publisher><subject>Bacteria ; Biomaterials ; Cellulose ; Chemical industry ; Chemistry and Materials Science ; Energy ; Graphene ; Interlayers ; Lithium sulfur batteries ; Materials Engineering ; Materials Science ; Metallic Materials ; Nanoscale Science and Technology ; Physical Chemistry ; 中国人民银行 ; 夹层 ; 氧化石墨 ; 电子传递途径 ; 电池 ; 硫 ; 细菌纤维素 ; 裂解</subject><ispartof>Rare metals, 2017-05, Vol.36 (5), p.418-424</ispartof><rights>The Nonferrous Metals Society of China and Springer-Verlag Berlin Heidelberg 2017</rights><rights>Rare Metals is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c343t-e863302193133f585e7ea4df93c2a9a02056711439d87f72a45694c009fbdc4f3</citedby><cites>FETCH-LOGICAL-c343t-e863302193133f585e7ea4df93c2a9a02056711439d87f72a45694c009fbdc4f3</cites><orcidid>0000-0003-2042-2780</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/85314X/85314X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12598-017-0906-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12598-017-0906-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Shen, Yu-Di</creatorcontrib><creatorcontrib>Xiao, Zhi-Chang</creatorcontrib><creatorcontrib>Miao, Li-Xiao</creatorcontrib><creatorcontrib>Kong, De-Bin</creatorcontrib><creatorcontrib>Zheng, Xiao-Yu</creatorcontrib><creatorcontrib>Chang, Yan-Hong</creatorcontrib><creatorcontrib>Zhi, Lin-Jie</creatorcontrib><title>Pyrolyzed bacterial cellulose/graphene oxide sandwich interlayer for lithium–sulfur batteries</title><title>Rare metals</title><addtitle>Rare Met</addtitle><addtitle>Rare Metals</addtitle><description>Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose（PBC）/graphene oxide（GO） composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bacterial cellulose（BC） network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries.</description><subject>Bacteria</subject><subject>Biomaterials</subject><subject>Cellulose</subject><subject>Chemical industry</subject><subject>Chemistry and Materials Science</subject><subject>Energy</subject><subject>Graphene</subject><subject>Interlayers</subject><subject>Lithium sulfur batteries</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanoscale Science and Technology</subject><subject>Physical Chemistry</subject><subject>中国人民银行</subject><subject>夹层</subject><subject>氧化石墨</subject><subject>电子传递途径</subject><subject>电池</subject><subject>硫</subject><subject>细菌纤维素</subject><subject>裂解</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kL1OwzAUhSMEEqXwAGwRzKbXf3E8ooo_qRIMMFtuYjep3KS1E0GYeAfekCfBVRBiYrp3-M53pJMk5xiuMICYBUy4zBFggUBChuRBMsF5JpDAOT-MPwBGwAk-Tk5CWAMwlmUwSdTT4Fs3vJsyXeqiM77WLi2Mc71rg5mtvN5WpjFp-1aXJg26KV_rokrrJqJOD8antvWpq7uq7jdfH5-hd7b30dXtXSacJkdWu2DOfu40ebm9eZ7fo8Xj3cP8eoEKymiHTJ5RCgRLiim1POdGGM1KK2lBtNRAgGcCY0ZlmQsriGY8k6wAkHZZFszSaXI5ere-3fUmdGrd9r6JlQpLIDmhjONI4ZEqfBuCN1Ztfb3RflAY1H5HNe6o4o5qv6OSMUPGTIhsszL-j_mf0MVPUdU2q13M_TZlgjDCOCf0GyAHgt8</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Shen, Yu-Di</creator><creator>Xiao, Zhi-Chang</creator><creator>Miao, Li-Xiao</creator><creator>Kong, De-Bin</creator><creator>Zheng, Xiao-Yu</creator><creator>Chang, Yan-Hong</creator><creator>Zhi, Lin-Jie</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-2042-2780</orcidid></search><sort><creationdate>20170501</creationdate><title>Pyrolyzed bacterial cellulose/graphene oxide sandwich interlayer for lithium–sulfur batteries</title><author>Shen, Yu-Di ; 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The unique and delicate structure where three-dimensional interconnected bacterial cellulose（BC） network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate capability.As a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. 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| subjects | Bacteria Biomaterials Cellulose Chemical industry Chemistry and Materials Science Energy Graphene Interlayers Lithium sulfur batteries Materials Engineering Materials Science Metallic Materials Nanoscale Science and Technology Physical Chemistry 中国人民银行 夹层 氧化石墨 电子传递途径 电池 硫 细菌纤维素 裂解 |
| title | Pyrolyzed bacterial cellulose/graphene oxide sandwich interlayer for lithium–sulfur batteries |
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