Expedient Synthesis of a Metallostibine Os2(CO)8(µ‐SbPh): An Unusual and Strong Two‐Electron‐Donor Ligand

A metallostibine, Os2(CO)8(µ‐SbPh) (2), was generated readily and in high yield and purity from the Os3(CO)11(µ‐SbPh)(Cl)2 (1) cluster through elimination of the terminal Os(CO)3(Cl)2 Lewis acid fragment with activated γ‐alumina. Compound 2 is air sensitive in solution but relatively stable as a sol...

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Veröffentlicht in:	European journal of inorganic chemistry 2017-05, Vol.2017 (19), p.2541-2546
Hauptverfasser:	Li, Ying‐Zhou, Ganguly, Rakesh, Leong, Weng Kee
Format:	Artikel
Sprache:	eng
Schlagworte:	Antimony Donating ligands Electrons Inorganic chemistry Lewis acid Metallostibines Osmium Structure elucidation
Online-Zugang:	Volltext
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