Structure and piezoelectric properties of microporous polyvinylidene fluoride films

A method to produce microporous polyvinylidene fluoride films characterized by a high content of a piezoactive crystalline phase and a developed relief surface is elaborated. The porous films are obtained in the process based on melt extrusion with subsequent isometric annealing and uniaxial extensi...

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Veröffentlicht in:Physics of the solid state 2017-05, Vol.59 (5), p.1041-1046
Hauptverfasser: Dmitriev, I. Yu, Kuryndin, I. S., Lavrentyev, V. K., Elyashevich, G. K.
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container_end_page 1046
container_issue 5
container_start_page 1041
container_title Physics of the solid state
container_volume 59
creator Dmitriev, I. Yu
Kuryndin, I. S.
Lavrentyev, V. K.
Elyashevich, G. K.
description A method to produce microporous polyvinylidene fluoride films characterized by a high content of a piezoactive crystalline phase and a developed relief surface is elaborated. The porous films are obtained in the process based on melt extrusion with subsequent isometric annealing and uniaxial extension. It is found that the samples have an oriented lamellar structure containing both α- and β-modifications of the crystallites. The effect of temperature and degree of uniaxial extention of the annealed films on the characteristics of the porous samples, that is, the content of the piezoactive crystalline β-phase, overall porosity, breakdown voltage and the piezoelectric modulus is studied.
doi_str_mv 10.1134/S1063783417050092
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ispartof Physics of the solid state, 2017-05, Vol.59 (5), p.1041-1046
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1090-6460
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source Springer Journals
subjects Analysis
Annealing
Beta phase
Chemical industry
Crystal structure
Crystallinity
Crystallites
Extrusion
Fluorides
Fluorine compounds
Lamellar structure
Physics
Physics and Astronomy
Piezoelectricity
Polymers
Polyvinylidene fluoride
Polyvinylidene fluorides
Porosity
Solid State Physics
Temperature effects
title Structure and piezoelectric properties of microporous polyvinylidene fluoride films
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