Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase
The graft polymerization of glycidyl methacrylate from irradiated polyethylene/polypropylene (PE/PP) in the presence of the chain transfer agent 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was studied at 40 °C using pre-irradiation grafting technique. Free radical active sites on pol...
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| Veröffentlicht in: | Colloid and polymer science 2017-06, Vol.295 (6), p.1007-1016 |
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| creator | Madrid, Jordan F. Abad, Lucille V. Yamanobe, Takeshi Seko, Noriaki |
| description | The graft polymerization of glycidyl methacrylate from irradiated polyethylene/polypropylene (PE/PP) in the presence of the chain transfer agent 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was studied at 40 °C using pre-irradiation grafting technique. Free radical active sites on polyethylene/polypropylene were formed by electron beam irradiation in nitrogen atmosphere and dry ice temperature. Compared to the conventional grafting method, addition of the chain transfer agent resulted in lower amount of grafted poly(glycidyl methacrylate) (PGMA) on the PE/PP trunk polymer. The calculated degree of grafting increased with increment in absorbed dose and reaction time but decreased with increasing glycidyl methacrylate concentration, at fixed monomer to CPPA ratio, and amount of CPPA. An apparent first-order dependence of conversion on monomer concentration was observed. The free poly(glycidyl methacrylate) that was formed in the polymerization mixture during grafting in the presence of CPPA had
M
n
which increased with reaction time and polydispersity index (PDI) values less than 2. NMR analysis of the PGMA homopolymer indicates the presence of dithiobenzoate group from CPPA at one end of the polymer chain. The pristine and grafted trunk polymers were characterized with FTIR, TGA, and SEM-EDX. |
| doi_str_mv | 10.1007/s00396-017-4088-7 |
| format | Article |
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M
n
which increased with reaction time and polydispersity index (PDI) values less than 2. NMR analysis of the PGMA homopolymer indicates the presence of dithiobenzoate group from CPPA at one end of the polymer chain. The pristine and grafted trunk polymers were characterized with FTIR, TGA, and SEM-EDX.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-017-4088-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chain transfer ; Chains (polymeric) ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Desiccants ; Dry ice ; Electron beams ; Electron irradiation ; Emulsion polymerization ; Food Science ; Free radicals ; Grafting ; Ice formation ; Monomers ; Nanotechnology and Microengineering ; NMR ; Nuclear magnetic resonance ; Original Contribution ; Physical Chemistry ; Polydispersity ; Polyethylene ; Polyethylenes ; Polymer Sciences ; Polymerization ; Polymers ; Polypropylene ; Reaction time ; Soft and Granular Matter</subject><ispartof>Colloid and polymer science, 2017-06, Vol.295 (6), p.1007-1016</ispartof><rights>Springer-Verlag Berlin Heidelberg 2017</rights><rights>Colloid and Polymer Science is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-3ae5dc51facda4fac796c458c2884e58bcf75e8d03d1789691560cae4d0bcb1b3</citedby><cites>FETCH-LOGICAL-c426t-3ae5dc51facda4fac796c458c2884e58bcf75e8d03d1789691560cae4d0bcb1b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-017-4088-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-017-4088-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Madrid, Jordan F.</creatorcontrib><creatorcontrib>Abad, Lucille V.</creatorcontrib><creatorcontrib>Yamanobe, Takeshi</creatorcontrib><creatorcontrib>Seko, Noriaki</creatorcontrib><title>Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>The graft polymerization of glycidyl methacrylate from irradiated polyethylene/polypropylene (PE/PP) in the presence of the chain transfer agent 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was studied at 40 °C using pre-irradiation grafting technique. Free radical active sites on polyethylene/polypropylene were formed by electron beam irradiation in nitrogen atmosphere and dry ice temperature. Compared to the conventional grafting method, addition of the chain transfer agent resulted in lower amount of grafted poly(glycidyl methacrylate) (PGMA) on the PE/PP trunk polymer. The calculated degree of grafting increased with increment in absorbed dose and reaction time but decreased with increasing glycidyl methacrylate concentration, at fixed monomer to CPPA ratio, and amount of CPPA. An apparent first-order dependence of conversion on monomer concentration was observed. The free poly(glycidyl methacrylate) that was formed in the polymerization mixture during grafting in the presence of CPPA had
M
n
which increased with reaction time and polydispersity index (PDI) values less than 2. NMR analysis of the PGMA homopolymer indicates the presence of dithiobenzoate group from CPPA at one end of the polymer chain. The pristine and grafted trunk polymers were characterized with FTIR, TGA, and SEM-EDX.</description><subject>Chain transfer</subject><subject>Chains (polymeric)</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Desiccants</subject><subject>Dry ice</subject><subject>Electron beams</subject><subject>Electron irradiation</subject><subject>Emulsion polymerization</subject><subject>Food Science</subject><subject>Free radicals</subject><subject>Grafting</subject><subject>Ice formation</subject><subject>Monomers</subject><subject>Nanotechnology and Microengineering</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polydispersity</subject><subject>Polyethylene</subject><subject>Polyethylenes</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polypropylene</subject><subject>Reaction time</subject><subject>Soft and Granular Matter</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kE1LxDAQhoMouK7-AG8Bz9GkTdP0KMv6AYIXBW8hTSdtl36ZpIeKP94s9eDFywwz87zvwIvQNaO3jNL8zlOaFoJQlhNOpST5CdownmaEZak4RRua0jReko9zdOH9gVLKCyE26HtvLZjg8WixaXQ74OD04C04rGsYAh7jpgEMXaRcHErQPWmHajZQ4dppG_A0dksPrv3SoY1EdKq7xbTV0uEeQqONWzodAEdz6OfOH6Gp0R4u0ZnVnYer375F7w_7t90TeXl9fN7dvxDDExFIqiGrTMasNpXmseaFMDyTJpGSQyZLY_MMZEXTiuWyEAXLBDUaeEVLU7Iy3aKb1Xdy4-cMPqjDOLshvlRMFlHARZFHiq2UcaP3DqyaXNtrtyhG1TFktYasYsjqGLI6apJV4yM71OD-OP8r-gHp0IKR</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Madrid, Jordan F.</creator><creator>Abad, Lucille V.</creator><creator>Yamanobe, Takeshi</creator><creator>Seko, Noriaki</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20170601</creationdate><title>Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase</title><author>Madrid, Jordan F. ; Abad, Lucille V. ; Yamanobe, Takeshi ; Seko, Noriaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-3ae5dc51facda4fac796c458c2884e58bcf75e8d03d1789691560cae4d0bcb1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chain transfer</topic><topic>Chains (polymeric)</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Desiccants</topic><topic>Dry ice</topic><topic>Electron beams</topic><topic>Electron irradiation</topic><topic>Emulsion polymerization</topic><topic>Food Science</topic><topic>Free radicals</topic><topic>Grafting</topic><topic>Ice formation</topic><topic>Monomers</topic><topic>Nanotechnology and Microengineering</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Polydispersity</topic><topic>Polyethylene</topic><topic>Polyethylenes</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polypropylene</topic><topic>Reaction time</topic><topic>Soft and Granular Matter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Madrid, Jordan F.</creatorcontrib><creatorcontrib>Abad, Lucille V.</creatorcontrib><creatorcontrib>Yamanobe, Takeshi</creatorcontrib><creatorcontrib>Seko, Noriaki</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Madrid, Jordan F.</au><au>Abad, Lucille V.</au><au>Yamanobe, Takeshi</au><au>Seko, Noriaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>295</volume><issue>6</issue><spage>1007</spage><epage>1016</epage><pages>1007-1016</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><abstract>The graft polymerization of glycidyl methacrylate from irradiated polyethylene/polypropylene (PE/PP) in the presence of the chain transfer agent 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was studied at 40 °C using pre-irradiation grafting technique. Free radical active sites on polyethylene/polypropylene were formed by electron beam irradiation in nitrogen atmosphere and dry ice temperature. Compared to the conventional grafting method, addition of the chain transfer agent resulted in lower amount of grafted poly(glycidyl methacrylate) (PGMA) on the PE/PP trunk polymer. The calculated degree of grafting increased with increment in absorbed dose and reaction time but decreased with increasing glycidyl methacrylate concentration, at fixed monomer to CPPA ratio, and amount of CPPA. An apparent first-order dependence of conversion on monomer concentration was observed. The free poly(glycidyl methacrylate) that was formed in the polymerization mixture during grafting in the presence of CPPA had
M
n
which increased with reaction time and polydispersity index (PDI) values less than 2. NMR analysis of the PGMA homopolymer indicates the presence of dithiobenzoate group from CPPA at one end of the polymer chain. The pristine and grafted trunk polymers were characterized with FTIR, TGA, and SEM-EDX.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-017-4088-7</doi><tpages>10</tpages></addata></record> |
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| subjects | Chain transfer Chains (polymeric) Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Desiccants Dry ice Electron beams Electron irradiation Emulsion polymerization Food Science Free radicals Grafting Ice formation Monomers Nanotechnology and Microengineering NMR Nuclear magnetic resonance Original Contribution Physical Chemistry Polydispersity Polyethylene Polyethylenes Polymer Sciences Polymerization Polymers Polypropylene Reaction time Soft and Granular Matter |
| title | Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase |
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