An Optical Investigation of Silver Nanoclusters Composite Soda-lime Glass Formed by Electric Field Assisted Diffusion

Silver nanoclusters(NCs) embedded in soda-lime glass was synthesized by the electric fieldassisted diffusion(EFAD) and successive annealing. The samples were characterized by UV-Vis absorption spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy(XPS), and lifetime measureme...

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Veröffentlicht in:Journal of Wuhan University of Technology. Materials science edition 2017-04, Vol.32 (2), p.338-344
Hauptverfasser: Zhao, Junhong, Lin, Jian, Zhang, Wenjun, Zhang, Shuo, Zhao, Guannan, Cai, Wen
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container_issue 2
container_start_page 338
container_title Journal of Wuhan University of Technology. Materials science edition
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creator Zhao, Junhong
Lin, Jian
Zhang, Wenjun
Zhang, Shuo
Zhao, Guannan
Cai, Wen
description Silver nanoclusters(NCs) embedded in soda-lime glass was synthesized by the electric fieldassisted diffusion(EFAD) and successive annealing. The samples were characterized by UV-Vis absorption spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy(XPS), and lifetime measurements. The experimental results show that the growth of silver clusters is favored by the annealing temperature and dwell time. The as-diffused and annealed glass samples show photoluminescence around 550 nm under UV excitation, which can be associated with the presence of L-center and Ag3~+ cluster. And the increasing of the annealing temperature and dwell time results in an appearance of the SPR peak and the decreasing of the luminescence intensities because the Ag3~+ clusters grow up into the Ag nanoparticles.
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subjects Annealing
Cementitious Materials
Chemistry and Materials Science
Clusters
Diffusion annealing
Dwell time
Electric fields
Materials Science
Nanoclusters
Nanoparticles
Photoelectrons
Photoluminescence
Silver
Soda-lime glass
Spectrum analysis
X ray photoelectron spectroscopy
title An Optical Investigation of Silver Nanoclusters Composite Soda-lime Glass Formed by Electric Field Assisted Diffusion
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