Isothermal kinetics approach to investigating the oxidation process of red phosphorus in air
The isothermal oxidation process of red phosphorus (RP) was investigated by thermogravimetric analysis in the temperature range of 320–480 °C. The model-free, model-fitting and reduced-time plot methods were used to research the oxidation kinetics of RP. According to the d α /d t − α and model-fre...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2017-06, Vol.128 (3), p.1801-1810 |
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| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 128 |
| creator | Liu, Jie Song, Dongming Guan, Hua |
| description | The isothermal oxidation process of red phosphorus (RP) was investigated by thermogravimetric analysis in the temperature range of 320–480 °C. The model-free, model-fitting and reduced-time plot methods were used to research the oxidation kinetics of RP. According to the d
α
/d
t
−
α
and model-free curves in different temperatures, the oxidation temperatures are divided into two ranges: lower temperatures (320–380 °C) and higher temperatures (390–410 °C). The apparent activation energy and oxidation controlling mechanisms in different temperature ranges are obtained. Besides, the trend of the oxidation rate with mass loss or temperature ranges is discussed. |
| doi_str_mv | 10.1007/s10973-016-6073-7 |
| format | Article |
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α
/d
t
−
α
and model-free curves in different temperatures, the oxidation temperatures are divided into two ranges: lower temperatures (320–380 °C) and higher temperatures (390–410 °C). The apparent activation energy and oxidation controlling mechanisms in different temperature ranges are obtained. Besides, the trend of the oxidation rate with mass loss or temperature ranges is discussed.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-016-6073-7</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Activation energy ; Analysis ; Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Electromagnetic radiation ; Inorganic Chemistry ; Investigations ; Kinetics ; Measurement Science and Instrumentation ; Oxidation rate ; Oxidation-reduction reactions ; Phosphorus ; Physical Chemistry ; Polymer Sciences ; Reaction kinetics ; Thermogravimetric analysis</subject><ispartof>Journal of thermal analysis and calorimetry, 2017-06, Vol.128 (3), p.1801-1810</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2017</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-3948168798f418127c6b8dee6b64eb7b98bd85f9b8288a37a2d68d7bc707e4233</citedby><cites>FETCH-LOGICAL-c426t-3948168798f418127c6b8dee6b64eb7b98bd85f9b8288a37a2d68d7bc707e4233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-016-6073-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-016-6073-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Song, Dongming</creatorcontrib><creatorcontrib>Guan, Hua</creatorcontrib><title>Isothermal kinetics approach to investigating the oxidation process of red phosphorus in air</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The isothermal oxidation process of red phosphorus (RP) was investigated by thermogravimetric analysis in the temperature range of 320–480 °C. The model-free, model-fitting and reduced-time plot methods were used to research the oxidation kinetics of RP. According to the d
α
/d
t
−
α
and model-free curves in different temperatures, the oxidation temperatures are divided into two ranges: lower temperatures (320–380 °C) and higher temperatures (390–410 °C). The apparent activation energy and oxidation controlling mechanisms in different temperature ranges are obtained. Besides, the trend of the oxidation rate with mass loss or temperature ranges is discussed.</description><subject>Activation energy</subject><subject>Analysis</subject><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electromagnetic radiation</subject><subject>Inorganic Chemistry</subject><subject>Investigations</subject><subject>Kinetics</subject><subject>Measurement Science and Instrumentation</subject><subject>Oxidation rate</subject><subject>Oxidation-reduction reactions</subject><subject>Phosphorus</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Reaction kinetics</subject><subject>Thermogravimetric analysis</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kUtLAzEUhQdRsFZ_gLuAKxdTk8xMHstSfBQKgo-dEDKZzDS1ndQklfrvvWVc6EJCyEn4zs2Bk2WXBE8IxvwmEix5kWPCcoZB8KNsRCohciopOwZdgGakwqfZWYwrjLGUmIyyt3n0aWnDRq_Ru-ttciYivd0Gr80SJY9c_2ljcp1Oru8QoMjvXQM33yOgjI0R-RYF26Dt0kfYYRfBhbQL59lJq9fRXvyc4-z17vZl9pAvHu_ns-kiNyVlKS9kKQgTXIq2JIJQblgtGmtZzUpb81qKuhFVK2tBhdAF17RhouG14ZjbkhbFOLsa5kKgjx3EVSu_Cz18qYiQouQFIwSoyUB1em2V61ufgjawGrtxxve2dfA-rSosK8oYA8P1HwMwye5Tp3cxqvnz01-WDKwJPsZgW7UNbqPDlyJYHRpSQ0MKGlKHhhQHDx08Edi-s-FX7H9N3w_gkus</recordid><startdate>20170601</startdate><enddate>20170601</enddate><creator>Liu, Jie</creator><creator>Song, Dongming</creator><creator>Guan, Hua</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20170601</creationdate><title>Isothermal kinetics approach to investigating the oxidation process of red phosphorus in air</title><author>Liu, Jie ; Song, Dongming ; Guan, Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-3948168798f418127c6b8dee6b64eb7b98bd85f9b8288a37a2d68d7bc707e4233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Activation energy</topic><topic>Analysis</topic><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electromagnetic radiation</topic><topic>Inorganic Chemistry</topic><topic>Investigations</topic><topic>Kinetics</topic><topic>Measurement Science and Instrumentation</topic><topic>Oxidation rate</topic><topic>Oxidation-reduction reactions</topic><topic>Phosphorus</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Reaction kinetics</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Jie</creatorcontrib><creatorcontrib>Song, Dongming</creatorcontrib><creatorcontrib>Guan, Hua</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Jie</au><au>Song, Dongming</au><au>Guan, Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isothermal kinetics approach to investigating the oxidation process of red phosphorus in air</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2017-06-01</date><risdate>2017</risdate><volume>128</volume><issue>3</issue><spage>1801</spage><epage>1810</epage><pages>1801-1810</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>The isothermal oxidation process of red phosphorus (RP) was investigated by thermogravimetric analysis in the temperature range of 320–480 °C. The model-free, model-fitting and reduced-time plot methods were used to research the oxidation kinetics of RP. According to the d
α
/d
t
−
α
and model-free curves in different temperatures, the oxidation temperatures are divided into two ranges: lower temperatures (320–380 °C) and higher temperatures (390–410 °C). The apparent activation energy and oxidation controlling mechanisms in different temperature ranges are obtained. Besides, the trend of the oxidation rate with mass loss or temperature ranges is discussed.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-016-6073-7</doi><tpages>10</tpages></addata></record> |
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| subjects | Activation energy Analysis Analytical Chemistry Chemistry Chemistry and Materials Science Electromagnetic radiation Inorganic Chemistry Investigations Kinetics Measurement Science and Instrumentation Oxidation rate Oxidation-reduction reactions Phosphorus Physical Chemistry Polymer Sciences Reaction kinetics Thermogravimetric analysis |
| title | Isothermal kinetics approach to investigating the oxidation process of red phosphorus in air |
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