Hierarchical Mn1.5Co1.5O4 microspheres constructed from one-dimensional nanorods as high-performance anode material for lithium-ion battery
Mn 1.5 Co 1.5 O 4 hierarchical microspheres have been successfully synthesized via a solvothermal method and an annealing procedure. Mn 1.5 Co 1.5 O 4 exhibits advanced cycling performance, and it retains a reversible capacity of 633 mA h g −1 at a current density of 400 mA g −1 with a coulombic eff...
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| Veröffentlicht in: | Ionics 2017-05, Vol.23 (5), p.1067-1074 |
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| container_title | Ionics |
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| creator | Hu, Dong-Xue Wang, Lei Gu, Da-Ming Wang, Zhen-Bo |
| description | Mn
1.5
Co
1.5
O
4
hierarchical microspheres have been successfully synthesized via a solvothermal method and an annealing procedure. Mn
1.5
Co
1.5
O
4
exhibits advanced cycling performance, and it retains a reversible capacity of 633 mA h g
−1
at a current density of 400 mA g
−1
with a coulombic efficiency of 99.0% after 220 cycles. Its remarkable performance is attributed to the hierarchical structure assembled with nanorods, which increases the contact area between each nanorod and electrolyte. More significantly, the open space between neighboring nanorods and the pores on the surface of nanorods can improve Li
+
ion diffusion rate. Furthermore, the nanorods have rapid one-dimensional Li
+
diffusion channels, which not only possess a large specific surface area for high activity but accommodate the volume change during lithiation–delithiation processes. Therefore, Mn
1.5
Co
1.5
O
4
hierarchical microspheres can act as a promising alternative anode material for lithium-ion battery. |
| doi_str_mv | 10.1007/s11581-016-1928-2 |
| format | Article |
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1.5
Co
1.5
O
4
hierarchical microspheres have been successfully synthesized via a solvothermal method and an annealing procedure. Mn
1.5
Co
1.5
O
4
exhibits advanced cycling performance, and it retains a reversible capacity of 633 mA h g
−1
at a current density of 400 mA g
−1
with a coulombic efficiency of 99.0% after 220 cycles. Its remarkable performance is attributed to the hierarchical structure assembled with nanorods, which increases the contact area between each nanorod and electrolyte. More significantly, the open space between neighboring nanorods and the pores on the surface of nanorods can improve Li
+
ion diffusion rate. Furthermore, the nanorods have rapid one-dimensional Li
+
diffusion channels, which not only possess a large specific surface area for high activity but accommodate the volume change during lithiation–delithiation processes. Therefore, Mn
1.5
Co
1.5
O
4
hierarchical microspheres can act as a promising alternative anode material for lithium-ion battery.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-016-1928-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Anodes ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Diffusion rate ; Electrochemistry ; Electrode materials ; Energy Storage ; Lithium ions ; Lithium-ion batteries ; Microspheres ; Nanorods ; Optical and Electronic Materials ; Original Paper ; Renewable and Green Energy ; Specific surface ; Surface area</subject><ispartof>Ionics, 2017-05, Vol.23 (5), p.1067-1074</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-c6d5643963b2a6a052990e2513bd8f393ce0709e1e7acd783342cd985abc6b2b3</citedby><cites>FETCH-LOGICAL-c316t-c6d5643963b2a6a052990e2513bd8f393ce0709e1e7acd783342cd985abc6b2b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-016-1928-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-016-1928-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Hu, Dong-Xue</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><creatorcontrib>Gu, Da-Ming</creatorcontrib><creatorcontrib>Wang, Zhen-Bo</creatorcontrib><title>Hierarchical Mn1.5Co1.5O4 microspheres constructed from one-dimensional nanorods as high-performance anode material for lithium-ion battery</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Mn
1.5
Co
1.5
O
4
hierarchical microspheres have been successfully synthesized via a solvothermal method and an annealing procedure. Mn
1.5
Co
1.5
O
4
exhibits advanced cycling performance, and it retains a reversible capacity of 633 mA h g
−1
at a current density of 400 mA g
−1
with a coulombic efficiency of 99.0% after 220 cycles. Its remarkable performance is attributed to the hierarchical structure assembled with nanorods, which increases the contact area between each nanorod and electrolyte. More significantly, the open space between neighboring nanorods and the pores on the surface of nanorods can improve Li
+
ion diffusion rate. Furthermore, the nanorods have rapid one-dimensional Li
+
diffusion channels, which not only possess a large specific surface area for high activity but accommodate the volume change during lithiation–delithiation processes. Therefore, Mn
1.5
Co
1.5
O
4
hierarchical microspheres can act as a promising alternative anode material for lithium-ion battery.</description><subject>Anodes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Diffusion rate</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Energy Storage</subject><subject>Lithium ions</subject><subject>Lithium-ion batteries</subject><subject>Microspheres</subject><subject>Nanorods</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Renewable and Green Energy</subject><subject>Specific surface</subject><subject>Surface area</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kLFu2zAQhomgBeKmfYBuBDrTOZISKY6B0SYBXHhpZ4KiThYNi3RIefAz9KVLwx2ydLkD7v7vgPsI-cphzQH0Y-G87TgDrhg3omPijqx4pwQDreADWYFpNNPQ6HvyqZQDgFJc6BX58xIwu-yn4N2R_ox83W5SLbuGzsHnVE4TZizUp1iWfPYLDnTMaaYpIhvCjLGEFCsaXUw5DYW6Qqewn9gJ85jy7KJHWncD0tktmEPN1jk9hmUK55lVmvZuqZvLZ_JxdMeCX_71B_L7x_dfmxe23T2_bp62zEuuFubV0KpGGiV74ZSDVhgDKFou-6EbpZEeQYNBjtr5QXdSNsIPpmtd71UvevlAvt3unnJ6O2NZ7CGdc32iWN4ZUCAb3dYUv6WuFkrG0Z5ymF2-WA726tzenNvq3F6dW1EZcWNKzcY95neX_wv9BcLOhfo</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Hu, Dong-Xue</creator><creator>Wang, Lei</creator><creator>Gu, Da-Ming</creator><creator>Wang, Zhen-Bo</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170501</creationdate><title>Hierarchical Mn1.5Co1.5O4 microspheres constructed from one-dimensional nanorods as high-performance anode material for lithium-ion battery</title><author>Hu, Dong-Xue ; Wang, Lei ; Gu, Da-Ming ; Wang, Zhen-Bo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-c6d5643963b2a6a052990e2513bd8f393ce0709e1e7acd783342cd985abc6b2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Anodes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Diffusion rate</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Energy Storage</topic><topic>Lithium ions</topic><topic>Lithium-ion batteries</topic><topic>Microspheres</topic><topic>Nanorods</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Renewable and Green Energy</topic><topic>Specific surface</topic><topic>Surface area</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Dong-Xue</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><creatorcontrib>Gu, Da-Ming</creatorcontrib><creatorcontrib>Wang, Zhen-Bo</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Dong-Xue</au><au>Wang, Lei</au><au>Gu, Da-Ming</au><au>Wang, Zhen-Bo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hierarchical Mn1.5Co1.5O4 microspheres constructed from one-dimensional nanorods as high-performance anode material for lithium-ion battery</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2017-05-01</date><risdate>2017</risdate><volume>23</volume><issue>5</issue><spage>1067</spage><epage>1074</epage><pages>1067-1074</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Mn
1.5
Co
1.5
O
4
hierarchical microspheres have been successfully synthesized via a solvothermal method and an annealing procedure. Mn
1.5
Co
1.5
O
4
exhibits advanced cycling performance, and it retains a reversible capacity of 633 mA h g
−1
at a current density of 400 mA g
−1
with a coulombic efficiency of 99.0% after 220 cycles. Its remarkable performance is attributed to the hierarchical structure assembled with nanorods, which increases the contact area between each nanorod and electrolyte. More significantly, the open space between neighboring nanorods and the pores on the surface of nanorods can improve Li
+
ion diffusion rate. Furthermore, the nanorods have rapid one-dimensional Li
+
diffusion channels, which not only possess a large specific surface area for high activity but accommodate the volume change during lithiation–delithiation processes. Therefore, Mn
1.5
Co
1.5
O
4
hierarchical microspheres can act as a promising alternative anode material for lithium-ion battery.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-016-1928-2</doi><tpages>8</tpages></addata></record> |
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| ispartof | Ionics, 2017-05, Vol.23 (5), p.1067-1074 |
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| language | eng |
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| subjects | Anodes Chemistry Chemistry and Materials Science Condensed Matter Physics Diffusion rate Electrochemistry Electrode materials Energy Storage Lithium ions Lithium-ion batteries Microspheres Nanorods Optical and Electronic Materials Original Paper Renewable and Green Energy Specific surface Surface area |
| title | Hierarchical Mn1.5Co1.5O4 microspheres constructed from one-dimensional nanorods as high-performance anode material for lithium-ion battery |
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