Application of extractive liquid scintillation spectrometry for rapid determination of uranium
A radiochemical technique for estimation of uranium concentration and 234 U/ 238 U isotopic ratios by direct extraction of uranium with Bis (2-ethylhexyl) phosphate (HDEHP) in toluene at an optimized pH of 2–2.5 with an efficiency of 95–99 % was standardized. The extractant also acted as a scintilla...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2016-09, Vol.309 (3), p.1049-1057 |
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| container_end_page | 1057 |
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| container_issue | 3 |
| container_start_page | 1049 |
| container_title | Journal of radioanalytical and nuclear chemistry |
| container_volume | 309 |
| creator | Reddy, Priyanka J. Pulhani, Vandana Dhole, S. D. Bhade, S. P. D. Anilkumar, S. Kolekar, R. V. Singh, Rajvir |
| description | A radiochemical technique for estimation of uranium concentration and
234
U/
238
U isotopic ratios by direct extraction of uranium with Bis (2-ethylhexyl) phosphate (HDEHP) in toluene at an optimized pH of 2–2.5 with an efficiency of 95–99 % was standardized. The extractant also acted as a scintillator for measurement of alpha radiations by liquid scintillation spectrometer (LSS). The method was validated by estimating the ratios of
234
U/
238
U in certified reference materials like, IAEA RGU-1, Depleted uranium, Ammonium di-uranate samples and ore samples from different locations in India. Conventional radiochemical separation and alpha spectrometry of electroplated source was used to compare and ascertain the isotopic ratios of uranium. |
| doi_str_mv | 10.1007/s10967-016-4698-4 |
| format | Article |
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234
U/
238
U isotopic ratios by direct extraction of uranium with Bis (2-ethylhexyl) phosphate (HDEHP) in toluene at an optimized pH of 2–2.5 with an efficiency of 95–99 % was standardized. The extractant also acted as a scintillator for measurement of alpha radiations by liquid scintillation spectrometer (LSS). The method was validated by estimating the ratios of
234
U/
238
U in certified reference materials like, IAEA RGU-1, Depleted uranium, Ammonium di-uranate samples and ore samples from different locations in India. Conventional radiochemical separation and alpha spectrometry of electroplated source was used to compare and ascertain the isotopic ratios of uranium.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-016-4698-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Alpha rays ; Chemistry ; Chemistry and Materials Science ; Diagnostic Radiology ; Hadrons ; Heavy Ions ; Inorganic Chemistry ; Isotopes ; Measurement ; Nuclear Chemistry ; Nuclear Physics ; Phosphates ; Physical Chemistry ; Radiation ; Radiochemical separation ; Reference materials ; Scientific imaging ; Scintillation ; Spectrometry ; Spectroscopy ; Spectrum analysis ; Toluene ; Uranium</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2016-09, Vol.309 (3), p.1049-1057</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c355t-b9c5771ae1526d9ebaf5b55cc4de37b438c0b8ad8d9a4668c2850f9319fd82853</citedby><cites>FETCH-LOGICAL-c355t-b9c5771ae1526d9ebaf5b55cc4de37b438c0b8ad8d9a4668c2850f9319fd82853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-016-4698-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-016-4698-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Reddy, Priyanka J.</creatorcontrib><creatorcontrib>Pulhani, Vandana</creatorcontrib><creatorcontrib>Dhole, S. D.</creatorcontrib><creatorcontrib>Bhade, S. P. D.</creatorcontrib><creatorcontrib>Anilkumar, S.</creatorcontrib><creatorcontrib>Kolekar, R. V.</creatorcontrib><creatorcontrib>Singh, Rajvir</creatorcontrib><title>Application of extractive liquid scintillation spectrometry for rapid determination of uranium</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>A radiochemical technique for estimation of uranium concentration and
234
U/
238
U isotopic ratios by direct extraction of uranium with Bis (2-ethylhexyl) phosphate (HDEHP) in toluene at an optimized pH of 2–2.5 with an efficiency of 95–99 % was standardized. The extractant also acted as a scintillator for measurement of alpha radiations by liquid scintillation spectrometer (LSS). The method was validated by estimating the ratios of
234
U/
238
U in certified reference materials like, IAEA RGU-1, Depleted uranium, Ammonium di-uranate samples and ore samples from different locations in India. Conventional radiochemical separation and alpha spectrometry of electroplated source was used to compare and ascertain the isotopic ratios of uranium.</description><subject>Alpha rays</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diagnostic Radiology</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Isotopes</subject><subject>Measurement</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Phosphates</subject><subject>Physical Chemistry</subject><subject>Radiation</subject><subject>Radiochemical separation</subject><subject>Reference materials</subject><subject>Scientific imaging</subject><subject>Scintillation</subject><subject>Spectrometry</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Toluene</subject><subject>Uranium</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhoMoOI4-gLuC645Jk7TJchi8wYAb3RrSXIYMbdNJUnHe3gwVcSNZnHD4_pOcD4BbBFcIwuY-IsjrpoSoLknNWUnOwAJRxsqqYfAcLGCF65I2GF2Cqxj3EELOGF6Aj_U4dk7J5PxQeFuYrxSkSu7TFJ07TE4XUbkhua6bkTgalYLvTQrHwvpQBDlmSJtkQu-G3zlTkIOb-mtwYWUXzc1PXYL3x4e3zXO5fX162ay3pcKUprLlijYNkgbRqtbctNLSllKliDa4aQlmCrZMaqa5JHXNVMUotBwjbjXLd7wEd_PcMfjDZGISez-FIT8pEGMwr0oxzNRqpnayM8IN1p-WzUeb3ik_GOtyf00aSEhWdQqgOaCCjzEYK8bgehmOAkFx8i5m7yJ7FyfvguRMNWdiZoedCX--8m_oG39eh1g</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Reddy, Priyanka J.</creator><creator>Pulhani, Vandana</creator><creator>Dhole, S. D.</creator><creator>Bhade, S. P. D.</creator><creator>Anilkumar, S.</creator><creator>Kolekar, R. V.</creator><creator>Singh, Rajvir</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160901</creationdate><title>Application of extractive liquid scintillation spectrometry for rapid determination of uranium</title><author>Reddy, Priyanka J. ; Pulhani, Vandana ; Dhole, S. D. ; Bhade, S. P. D. ; Anilkumar, S. ; Kolekar, R. V. ; Singh, Rajvir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c355t-b9c5771ae1526d9ebaf5b55cc4de37b438c0b8ad8d9a4668c2850f9319fd82853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Alpha rays</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diagnostic Radiology</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Isotopes</topic><topic>Measurement</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Phosphates</topic><topic>Physical Chemistry</topic><topic>Radiation</topic><topic>Radiochemical separation</topic><topic>Reference materials</topic><topic>Scientific imaging</topic><topic>Scintillation</topic><topic>Spectrometry</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Toluene</topic><topic>Uranium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reddy, Priyanka J.</creatorcontrib><creatorcontrib>Pulhani, Vandana</creatorcontrib><creatorcontrib>Dhole, S. D.</creatorcontrib><creatorcontrib>Bhade, S. P. D.</creatorcontrib><creatorcontrib>Anilkumar, S.</creatorcontrib><creatorcontrib>Kolekar, R. V.</creatorcontrib><creatorcontrib>Singh, Rajvir</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reddy, Priyanka J.</au><au>Pulhani, Vandana</au><au>Dhole, S. D.</au><au>Bhade, S. P. D.</au><au>Anilkumar, S.</au><au>Kolekar, R. V.</au><au>Singh, Rajvir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of extractive liquid scintillation spectrometry for rapid determination of uranium</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2016-09-01</date><risdate>2016</risdate><volume>309</volume><issue>3</issue><spage>1049</spage><epage>1057</epage><pages>1049-1057</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>A radiochemical technique for estimation of uranium concentration and
234
U/
238
U isotopic ratios by direct extraction of uranium with Bis (2-ethylhexyl) phosphate (HDEHP) in toluene at an optimized pH of 2–2.5 with an efficiency of 95–99 % was standardized. The extractant also acted as a scintillator for measurement of alpha radiations by liquid scintillation spectrometer (LSS). The method was validated by estimating the ratios of
234
U/
238
U in certified reference materials like, IAEA RGU-1, Depleted uranium, Ammonium di-uranate samples and ore samples from different locations in India. Conventional radiochemical separation and alpha spectrometry of electroplated source was used to compare and ascertain the isotopic ratios of uranium.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10967-016-4698-4</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of radioanalytical and nuclear chemistry, 2016-09, Vol.309 (3), p.1049-1057 |
| issn | 0236-5731 1588-2780 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Alpha rays Chemistry Chemistry and Materials Science Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Isotopes Measurement Nuclear Chemistry Nuclear Physics Phosphates Physical Chemistry Radiation Radiochemical separation Reference materials Scientific imaging Scintillation Spectrometry Spectroscopy Spectrum analysis Toluene Uranium |
| title | Application of extractive liquid scintillation spectrometry for rapid determination of uranium |
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