Mechanism of ionic transport in cesium-conducting solid electrolytes based on cesium orthophosphate
The earlier obtained data on the transport properties of cesium-conducting solid electrolytes based on cesium orthophosphate in the Cs 3–2x M x II PO 4 (M II = Mg, Ca, Sr, Ba), Cs 3–3x PO 4 (M x III = Sc, Y, La, Sm, Nd) and Cs 3–x P 1–x Z x VI O 4 (Z = S, Cr, Mo, W) systems are analyzed. It is shown...
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| Veröffentlicht in: | Russian journal of electrochemistry 2016-08, Vol.52 (8), p.796-800 |
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| container_title | Russian journal of electrochemistry |
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| creator | Burmakin, E. I. Shekhtman, G. Sh |
| description | The earlier obtained data on the transport properties of cesium-conducting solid electrolytes based on cesium orthophosphate in the Cs
3–2x
M
x
II
PO
4
(M
II
= Mg, Ca, Sr, Ba), Cs
3–3x
PO
4
(M
x
III
= Sc, Y, La, Sm, Nd) and Cs
3–x
P
1–x
Z
x
VI
O
4
(Z = S, Cr, Mo, W) systems are analyzed. It is shown that, in addition to the conventional jump mechanism, the “paddle wheel” mechanism can play an important role in the ionic transport. This mechanism is associated with the orientation disordering of [PO
4
] tetrahedrons at the elevated temperatures, which leads to their rotation promoting “pushing” cesium ions into the accessible neighboring positions. |
| doi_str_mv | 10.1134/S1023193516080048 |
| format | Article |
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3–2x
M
x
II
PO
4
(M
II
= Mg, Ca, Sr, Ba), Cs
3–3x
PO
4
(M
x
III
= Sc, Y, La, Sm, Nd) and Cs
3–x
P
1–x
Z
x
VI
O
4
(Z = S, Cr, Mo, W) systems are analyzed. It is shown that, in addition to the conventional jump mechanism, the “paddle wheel” mechanism can play an important role in the ionic transport. This mechanism is associated with the orientation disordering of [PO
4
] tetrahedrons at the elevated temperatures, which leads to their rotation promoting “pushing” cesium ions into the accessible neighboring positions.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193516080048</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Cesium ions ; Chemistry ; Chemistry and Materials Science ; Electrochemistry ; High temperature ; Molten salt electrolytes ; Physical Chemistry ; Short Communications ; Solid electrolytes ; Tetrahedra ; Transport properties</subject><ispartof>Russian journal of electrochemistry, 2016-08, Vol.52 (8), p.796-800</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-4dd24bf40fd50b7418c9431804e886d0d90f1e64757c93f422062ad7a32ec0b93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193516080048$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193516080048$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Burmakin, E. I.</creatorcontrib><creatorcontrib>Shekhtman, G. Sh</creatorcontrib><title>Mechanism of ionic transport in cesium-conducting solid electrolytes based on cesium orthophosphate</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>The earlier obtained data on the transport properties of cesium-conducting solid electrolytes based on cesium orthophosphate in the Cs
3–2x
M
x
II
PO
4
(M
II
= Mg, Ca, Sr, Ba), Cs
3–3x
PO
4
(M
x
III
= Sc, Y, La, Sm, Nd) and Cs
3–x
P
1–x
Z
x
VI
O
4
(Z = S, Cr, Mo, W) systems are analyzed. It is shown that, in addition to the conventional jump mechanism, the “paddle wheel” mechanism can play an important role in the ionic transport. This mechanism is associated with the orientation disordering of [PO
4
] tetrahedrons at the elevated temperatures, which leads to their rotation promoting “pushing” cesium ions into the accessible neighboring positions.</description><subject>Cesium ions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>High temperature</subject><subject>Molten salt electrolytes</subject><subject>Physical Chemistry</subject><subject>Short Communications</subject><subject>Solid electrolytes</subject><subject>Tetrahedra</subject><subject>Transport properties</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxDAUhYMoOI7-AHcB19Wbx7TpUgZfoLhQ1yXNY5qhk9QkXcy_t2UUBHF1D5zvnAsHoUsC14QwfvNGgDJSsxUpQQBwcYQWsywY4_R40pNdzP4pOktpCwCiIvUCqRejOuld2uFgsQveKZyj9GkIMWPnsTLJjbtCBa9HlZ3f4BR6p7Hpjcox9PtsEm5lMhqHHxpP2S4MXUhDJ7M5RydW9slcfN8l-ri_e18_Fs-vD0_r2-dC0VLkgmtNeWs5WL2CtuJEqJozIoAbIUoNugZLTMmrVaVqZjmlUFKpK8moUdDWbImuDr1DDJ-jSbnZhjH66WVDhAAhGGEzRQ6UiiGlaGwzRLeTcd8QaOYtmz9bThl6yKSJ9RsTfzX_G_oCoYF2mQ</recordid><startdate>20160801</startdate><enddate>20160801</enddate><creator>Burmakin, E. I.</creator><creator>Shekhtman, G. Sh</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160801</creationdate><title>Mechanism of ionic transport in cesium-conducting solid electrolytes based on cesium orthophosphate</title><author>Burmakin, E. I. ; Shekhtman, G. Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-4dd24bf40fd50b7418c9431804e886d0d90f1e64757c93f422062ad7a32ec0b93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Cesium ions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemistry</topic><topic>High temperature</topic><topic>Molten salt electrolytes</topic><topic>Physical Chemistry</topic><topic>Short Communications</topic><topic>Solid electrolytes</topic><topic>Tetrahedra</topic><topic>Transport properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burmakin, E. I.</creatorcontrib><creatorcontrib>Shekhtman, G. Sh</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burmakin, E. I.</au><au>Shekhtman, G. Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanism of ionic transport in cesium-conducting solid electrolytes based on cesium orthophosphate</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2016-08-01</date><risdate>2016</risdate><volume>52</volume><issue>8</issue><spage>796</spage><epage>800</epage><pages>796-800</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>The earlier obtained data on the transport properties of cesium-conducting solid electrolytes based on cesium orthophosphate in the Cs
3–2x
M
x
II
PO
4
(M
II
= Mg, Ca, Sr, Ba), Cs
3–3x
PO
4
(M
x
III
= Sc, Y, La, Sm, Nd) and Cs
3–x
P
1–x
Z
x
VI
O
4
(Z = S, Cr, Mo, W) systems are analyzed. It is shown that, in addition to the conventional jump mechanism, the “paddle wheel” mechanism can play an important role in the ionic transport. This mechanism is associated with the orientation disordering of [PO
4
] tetrahedrons at the elevated temperatures, which leads to their rotation promoting “pushing” cesium ions into the accessible neighboring positions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193516080048</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1023-1935 |
| ispartof | Russian journal of electrochemistry, 2016-08, Vol.52 (8), p.796-800 |
| issn | 1023-1935 1608-3342 |
| language | eng |
| recordid | cdi_proquest_journals_1880883139 |
| source | SpringerNature Journals |
| subjects | Cesium ions Chemistry Chemistry and Materials Science Electrochemistry High temperature Molten salt electrolytes Physical Chemistry Short Communications Solid electrolytes Tetrahedra Transport properties |
| title | Mechanism of ionic transport in cesium-conducting solid electrolytes based on cesium orthophosphate |
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