Reactions of 2,2′-Pyridyl with the cadmium(II) compounds: Synthesis, crystal structure, and luminescence properties of [Cd(Pic)2(H2O)2] · H2O
The reactions of 2,2'-pyridyl, (2-Py)C(O)C(O)(2-Py), with the Cd(II) compounds under various conditions are studied. The medium and nature of the anions exert a decisive effect on the compositions and structures of the formed cadmium complexes. The reaction of cadmium diacetate with 2,2'-p...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2016-09, Vol.42 (9), p.614-619 |
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| creator | Kokunov, Yu. V. Kovalev, V. V. Gorbunova, Yu. E. Kozyukhin, S. A. |
| description | The reactions of 2,2'-pyridyl, (2-Py)C(O)C(O)(2-Py), with the Cd(II) compounds under various conditions are studied. The medium and nature of the anions exert a decisive effect on the compositions and structures of the formed cadmium complexes. The reaction of cadmium diacetate with 2,2'-pyridyl in an aqueous-alcohol medium in air affords coordination compound [Cd(Рic)
2
(H
2
O)
2
] · H
2
O (
I
) (Pic
−
is picolinate ion, CO
2
C
5
H
4
N), and its crystal structure is determined. The crystals are monoclinic: space group
P
2
1
/
c
,
a
= 7.499(1),
b
= 15.676(1),
с
= 12.719(1) Å, β = 94.79(1)°,
V
= 1490.0(2) Å3,
Z
= 4, ρ
calcd
= 1.502 g/cm
3
. The molecular packing of compound I is a supramolecular 3D framework consisting of discrete complexes [Cd(Pic)
2
(H
2
O)
2
] linked by hydrogen bonds O–H…O. The coordination sphere of Cd
2+
contains two O atoms and two N atoms of the ligand and two water molecules. The coordination polyhedron of Cd
2+
is a distorted octahedron. |
| doi_str_mv | 10.1134/S1070328416090025 |
| format | Article |
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2
(H
2
O)
2
] · H
2
O (
I
) (Pic
−
is picolinate ion, CO
2
C
5
H
4
N), and its crystal structure is determined. The crystals are monoclinic: space group
P
2
1
/
c
,
a
= 7.499(1),
b
= 15.676(1),
с
= 12.719(1) Å, β = 94.79(1)°,
V
= 1490.0(2) Å3,
Z
= 4, ρ
calcd
= 1.502 g/cm
3
. The molecular packing of compound I is a supramolecular 3D framework consisting of discrete complexes [Cd(Pic)
2
(H
2
O)
2
] linked by hydrogen bonds O–H…O. The coordination sphere of Cd
2+
contains two O atoms and two N atoms of the ligand and two water molecules. The coordination polyhedron of Cd
2+
is a distorted octahedron.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328416090025</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Cadmium ; Cadmium acetate ; Cadmium compounds ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Composition effects ; Coordination compounds ; Crystal structure ; Hydrogen bonds ; Inorganic Chemistry ; Luminescence ; Optical properties ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2016-09, Vol.42 (9), p.614-619</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2315-66231eaa654db8bbd052ed5dca7a8bd02468452bf17dbe55a28ee1680bad1fc33</citedby><cites>FETCH-LOGICAL-c2315-66231eaa654db8bbd052ed5dca7a8bd02468452bf17dbe55a28ee1680bad1fc33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328416090025$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328416090025$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kokunov, Yu. V.</creatorcontrib><creatorcontrib>Kovalev, V. V.</creatorcontrib><creatorcontrib>Gorbunova, Yu. E.</creatorcontrib><creatorcontrib>Kozyukhin, S. A.</creatorcontrib><title>Reactions of 2,2′-Pyridyl with the cadmium(II) compounds: Synthesis, crystal structure, and luminescence properties of [Cd(Pic)2(H2O)2] · H2O</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The reactions of 2,2'-pyridyl, (2-Py)C(O)C(O)(2-Py), with the Cd(II) compounds under various conditions are studied. The medium and nature of the anions exert a decisive effect on the compositions and structures of the formed cadmium complexes. The reaction of cadmium diacetate with 2,2'-pyridyl in an aqueous-alcohol medium in air affords coordination compound [Cd(Рic)
2
(H
2
O)
2
] · H
2
O (
I
) (Pic
−
is picolinate ion, CO
2
C
5
H
4
N), and its crystal structure is determined. The crystals are monoclinic: space group
P
2
1
/
c
,
a
= 7.499(1),
b
= 15.676(1),
с
= 12.719(1) Å, β = 94.79(1)°,
V
= 1490.0(2) Å3,
Z
= 4, ρ
calcd
= 1.502 g/cm
3
. The molecular packing of compound I is a supramolecular 3D framework consisting of discrete complexes [Cd(Pic)
2
(H
2
O)
2
] linked by hydrogen bonds O–H…O. The coordination sphere of Cd
2+
contains two O atoms and two N atoms of the ligand and two water molecules. The coordination polyhedron of Cd
2+
is a distorted octahedron.</description><subject>Cadmium</subject><subject>Cadmium acetate</subject><subject>Cadmium compounds</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition effects</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Luminescence</subject><subject>Optical properties</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKAzEUHUTBWv0AdwE3LXQ0yUxmUndS1BYKLVZXIkMmuWNT5lGTGWR2foLf4sa9n-KXmFoXgrg653Ie93I975jgU0KC8GxBcIwDykMS4SHGlO14HUe5HwSE7zruZH-j73sH1q4wJhizYcd7vQEha12VFlUZogP6-fLmz1ujVZujZ10vUb0EJIUqdFP0JpM-klWxrppS2XO0aEunWm0HSJrW1iJHtjaNrBsDAyRKhfKm0CVYCaUEtDbVGkyt4XvX_Uj15lr2aW9MZ336gD7ekWOH3l4mcgtHP9j17q4ub0djfzq7nowupr6kAWF-FDkAISIWqpSnqcKMgmJKilhwN9Ew4iGjaUZilQJjgnIAEnGcCkUyGQRd72Tb6656asDWyapqTOlWJoRzzGMSUe5cZOuSprLWQJasjS6EaROCk83jkz-Pdxm6zVjnLR_B_Gr-N_QF3m-Fwg</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Kokunov, Yu. V.</creator><creator>Kovalev, V. V.</creator><creator>Gorbunova, Yu. E.</creator><creator>Kozyukhin, S. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160901</creationdate><title>Reactions of 2,2′-Pyridyl with the cadmium(II) compounds: Synthesis, crystal structure, and luminescence properties of [Cd(Pic)2(H2O)2] · H2O</title><author>Kokunov, Yu. V. ; Kovalev, V. V. ; Gorbunova, Yu. E. ; Kozyukhin, S. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2315-66231eaa654db8bbd052ed5dca7a8bd02468452bf17dbe55a28ee1680bad1fc33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Cadmium</topic><topic>Cadmium acetate</topic><topic>Cadmium compounds</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition effects</topic><topic>Coordination compounds</topic><topic>Crystal structure</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Luminescence</topic><topic>Optical properties</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kokunov, Yu. V.</creatorcontrib><creatorcontrib>Kovalev, V. V.</creatorcontrib><creatorcontrib>Gorbunova, Yu. E.</creatorcontrib><creatorcontrib>Kozyukhin, S. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kokunov, Yu. V.</au><au>Kovalev, V. V.</au><au>Gorbunova, Yu. E.</au><au>Kozyukhin, S. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactions of 2,2′-Pyridyl with the cadmium(II) compounds: Synthesis, crystal structure, and luminescence properties of [Cd(Pic)2(H2O)2] · H2O</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2016-09-01</date><risdate>2016</risdate><volume>42</volume><issue>9</issue><spage>614</spage><epage>619</epage><pages>614-619</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The reactions of 2,2'-pyridyl, (2-Py)C(O)C(O)(2-Py), with the Cd(II) compounds under various conditions are studied. The medium and nature of the anions exert a decisive effect on the compositions and structures of the formed cadmium complexes. The reaction of cadmium diacetate with 2,2'-pyridyl in an aqueous-alcohol medium in air affords coordination compound [Cd(Рic)
2
(H
2
O)
2
] · H
2
O (
I
) (Pic
−
is picolinate ion, CO
2
C
5
H
4
N), and its crystal structure is determined. The crystals are monoclinic: space group
P
2
1
/
c
,
a
= 7.499(1),
b
= 15.676(1),
с
= 12.719(1) Å, β = 94.79(1)°,
V
= 1490.0(2) Å3,
Z
= 4, ρ
calcd
= 1.502 g/cm
3
. The molecular packing of compound I is a supramolecular 3D framework consisting of discrete complexes [Cd(Pic)
2
(H
2
O)
2
] linked by hydrogen bonds O–H…O. The coordination sphere of Cd
2+
contains two O atoms and two N atoms of the ligand and two water molecules. The coordination polyhedron of Cd
2+
is a distorted octahedron.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328416090025</doi><tpages>6</tpages></addata></record> |
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| subjects | Cadmium Cadmium acetate Cadmium compounds Chemical bonds Chemistry Chemistry and Materials Science Composition effects Coordination compounds Crystal structure Hydrogen bonds Inorganic Chemistry Luminescence Optical properties Physical Chemistry |
| title | Reactions of 2,2′-Pyridyl with the cadmium(II) compounds: Synthesis, crystal structure, and luminescence properties of [Cd(Pic)2(H2O)2] · H2O |
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