Determination of aliphatic acids in natural waters using distillation and solid-phase extraction
A procedure is developed and conditions are optimized for the pretreatment of natural water using distillation with no prefiltration of acidified water in combination with preconcentration by solid-phase extraction (SPE) on a Strata-X polymeric adsorbent followed by derivatization for the determinat...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2016-10, Vol.71 (10), p.1028-1032 |
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| container_end_page | 1032 |
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| container_issue | 10 |
| container_start_page | 1028 |
| container_title | Journal of analytical chemistry (New York, N.Y.) |
| container_volume | 71 |
| creator | Khasanov, V. V. Makarycheva, A. I. Slizhov, Yu. G. |
| description | A procedure is developed and conditions are optimized for the pretreatment of natural water using distillation with no prefiltration of acidified water in combination with preconcentration by solid-phase extraction (SPE) on a Strata-X polymeric adsorbent followed by derivatization for the determination of trace concentrations of C3–C18 aliphatic carboxylic acids by gas chromatography with mass spectrometric detection. It is shown that, at the distillation stage, 90% of free carboxylic acids of the homologous series are transferred to the distillate, which greatly facilitates the procedure of the analysis of natural water containing impurity particles and humic substances and ensures the achievement of the limit of detection for the analytes about 0.05 μg/L. It is found that, at the SPE stage, the adsorbents based on copolymers of styrene, divinylbenzene, and
N
-vinylpyrrolidone in plastic cartridges may serve as sources of additional pollution with benzoic, palmitic, and stearic acids in the eluates under investigation. |
| doi_str_mv | 10.1134/S1061934816100051 |
| format | Article |
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N
-vinylpyrrolidone in plastic cartridges may serve as sources of additional pollution with benzoic, palmitic, and stearic acids in the eluates under investigation.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934816100051</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acidification ; Adsorbents ; Aliphatic acids ; Aliphatic compounds ; Analytical Chemistry ; Carboxylic acids ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Copolymers ; Distillation ; Distilled water ; Divinylbenzene ; Gas chromatography ; Humic substances ; Pollution sources ; Solid phases ; Spectrometry ; Water</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2016-10, Vol.71 (10), p.1028-1032</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c455t-790b33b6902a66e769338f87bfc9fd0e6989ed588a2aef6c0e0d0e5fecf5656c3</citedby><cites>FETCH-LOGICAL-c455t-790b33b6902a66e769338f87bfc9fd0e6989ed588a2aef6c0e0d0e5fecf5656c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934816100051$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934816100051$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Khasanov, V. V.</creatorcontrib><creatorcontrib>Makarycheva, A. I.</creatorcontrib><creatorcontrib>Slizhov, Yu. G.</creatorcontrib><title>Determination of aliphatic acids in natural waters using distillation and solid-phase extraction</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>A procedure is developed and conditions are optimized for the pretreatment of natural water using distillation with no prefiltration of acidified water in combination with preconcentration by solid-phase extraction (SPE) on a Strata-X polymeric adsorbent followed by derivatization for the determination of trace concentrations of C3–C18 aliphatic carboxylic acids by gas chromatography with mass spectrometric detection. It is shown that, at the distillation stage, 90% of free carboxylic acids of the homologous series are transferred to the distillate, which greatly facilitates the procedure of the analysis of natural water containing impurity particles and humic substances and ensures the achievement of the limit of detection for the analytes about 0.05 μg/L. It is found that, at the SPE stage, the adsorbents based on copolymers of styrene, divinylbenzene, and
N
-vinylpyrrolidone in plastic cartridges may serve as sources of additional pollution with benzoic, palmitic, and stearic acids in the eluates under investigation.</description><subject>Acidification</subject><subject>Adsorbents</subject><subject>Aliphatic acids</subject><subject>Aliphatic compounds</subject><subject>Analytical Chemistry</subject><subject>Carboxylic acids</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Distillation</subject><subject>Distilled water</subject><subject>Divinylbenzene</subject><subject>Gas chromatography</subject><subject>Humic substances</subject><subject>Pollution sources</subject><subject>Solid phases</subject><subject>Spectrometry</subject><subject>Water</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kctOxCAUhhujidcHcEfiykVHGFoKS-N1kklMvKyRoYeK6dAR2qhv75mMiU4cwwI4__cBOWTZMaMjxnhx9sCoYIoXkglGKS3ZVrbHBJU5Z0pt4xrjfJnvZvspvSKiEN3Lni-hhzj3wfS-C6RzxLR-8YI7S4z1dSI-EAyHaFrybpBNZEg-NKT2qfdtu_JMqEnqWl_n6CYg8NFHY5fRYbbjTJvg6Hs-yJ6urx4vbvPp3c3k4nya26Is-7xSdMb5TCg6NkJAJRTn0slq5qxyNQWhpIK6lNKMDThhKVCslg6sK0UpLD_ITlbnLmL3NkDq9Ws3xIBXaiYllULIqvqhGtOC9sF1y3fOfbL6vFCCF4JxhlS-gWogAHahC-A8ltf40QYeRw1zbzcKp2sCMj22rDFDSnrycL_OshVrY5dSBKcX0c9N_NSM6uXf6z9_j8545SRkQwPxVzP-lb4AVQ2uvA</recordid><startdate>20161001</startdate><enddate>20161001</enddate><creator>Khasanov, V. V.</creator><creator>Makarycheva, A. I.</creator><creator>Slizhov, Yu. G.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20161001</creationdate><title>Determination of aliphatic acids in natural waters using distillation and solid-phase extraction</title><author>Khasanov, V. V. ; Makarycheva, A. I. ; Slizhov, Yu. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c455t-790b33b6902a66e769338f87bfc9fd0e6989ed588a2aef6c0e0d0e5fecf5656c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acidification</topic><topic>Adsorbents</topic><topic>Aliphatic acids</topic><topic>Aliphatic compounds</topic><topic>Analytical Chemistry</topic><topic>Carboxylic acids</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Distillation</topic><topic>Distilled water</topic><topic>Divinylbenzene</topic><topic>Gas chromatography</topic><topic>Humic substances</topic><topic>Pollution sources</topic><topic>Solid phases</topic><topic>Spectrometry</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khasanov, V. V.</creatorcontrib><creatorcontrib>Makarycheva, A. I.</creatorcontrib><creatorcontrib>Slizhov, Yu. G.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khasanov, V. V.</au><au>Makarycheva, A. I.</au><au>Slizhov, Yu. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of aliphatic acids in natural waters using distillation and solid-phase extraction</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2016-10-01</date><risdate>2016</risdate><volume>71</volume><issue>10</issue><spage>1028</spage><epage>1032</epage><pages>1028-1032</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>A procedure is developed and conditions are optimized for the pretreatment of natural water using distillation with no prefiltration of acidified water in combination with preconcentration by solid-phase extraction (SPE) on a Strata-X polymeric adsorbent followed by derivatization for the determination of trace concentrations of C3–C18 aliphatic carboxylic acids by gas chromatography with mass spectrometric detection. It is shown that, at the distillation stage, 90% of free carboxylic acids of the homologous series are transferred to the distillate, which greatly facilitates the procedure of the analysis of natural water containing impurity particles and humic substances and ensures the achievement of the limit of detection for the analytes about 0.05 μg/L. It is found that, at the SPE stage, the adsorbents based on copolymers of styrene, divinylbenzene, and
N
-vinylpyrrolidone in plastic cartridges may serve as sources of additional pollution with benzoic, palmitic, and stearic acids in the eluates under investigation.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934816100051</doi><tpages>5</tpages></addata></record> |
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| issn | 1061-9348 1608-3199 |
| language | eng |
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| subjects | Acidification Adsorbents Aliphatic acids Aliphatic compounds Analytical Chemistry Carboxylic acids Chemical properties Chemistry Chemistry and Materials Science Copolymers Distillation Distilled water Divinylbenzene Gas chromatography Humic substances Pollution sources Solid phases Spectrometry Water |
| title | Determination of aliphatic acids in natural waters using distillation and solid-phase extraction |
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