New polar fluorinated diluents for diamide extractants
The extraction properties of TODGA solutions in novel polar fluorinated diluents were investigated. The extraction of nitric acid, Am and lanthanides was studied. It was found that aromatic fluorinated diluents provide the highest loading capacity of organic phase comparing with aliphatic diluents....
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Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2016-11, Vol.310 (2), p.785-792 |
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container_title | Journal of radioanalytical and nuclear chemistry |
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creator | Alyapyshev, Mikhail Babain, Vasiliy Eliseev, Ivan Kenf, Ekaterina Tkachenko, Lyudmila |
description | The extraction properties of TODGA solutions in novel polar fluorinated diluents were investigated. The extraction of nitric acid, Am and lanthanides was studied. It was found that aromatic fluorinated diluents provide the highest loading capacity of organic phase comparing with aliphatic diluents. A new solvent on the base of TODGA in meta-nitrobenzotrifluoride is the most promising for technological purposes. |
doi_str_mv | 10.1007/s10967-016-4907-1 |
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The extraction of nitric acid, Am and lanthanides was studied. It was found that aromatic fluorinated diluents provide the highest loading capacity of organic phase comparing with aliphatic diluents. 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The extraction of nitric acid, Am and lanthanides was studied. It was found that aromatic fluorinated diluents provide the highest loading capacity of organic phase comparing with aliphatic diluents. A new solvent on the base of TODGA in meta-nitrobenzotrifluoride is the most promising for technological purposes.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diagnostic Radiology</subject><subject>Fluorination</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Lanthanides</subject><subject>Nitric acid</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8Fz9GZpE0nR1n8gkUveg7ZNJEu3XZNWtR_b5Z68OJpmOF534GHsUuEawSobxKCVjUHVLzUUHM8YgusiLioCY7ZAoRUvKolnrKzlLYAoInkgqln_1nsh87GInTTENvejr4pmrabfD-mIgwxL3bXNr7wX2O0brT5fs5Ogu2Sv_idS_Z2f_e6euTrl4en1e2aO0li5JtKa4QQnAMg8OBqDbIMDQL5klRwZY0CUWwyowVpZ7UnUNSQqJogg1yyq7l3H4ePyafRbIcp9vmlQSIgJUtRZgpnysUhpeiD2cd2Z-O3QTAHPWbWY7Iec9BjMGfEnEmZ7d99_NP8b-gHCmpm3w</recordid><startdate>20161101</startdate><enddate>20161101</enddate><creator>Alyapyshev, Mikhail</creator><creator>Babain, Vasiliy</creator><creator>Eliseev, Ivan</creator><creator>Kenf, Ekaterina</creator><creator>Tkachenko, Lyudmila</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20161101</creationdate><title>New polar fluorinated diluents for diamide extractants</title><author>Alyapyshev, Mikhail ; Babain, Vasiliy ; Eliseev, Ivan ; Kenf, Ekaterina ; Tkachenko, Lyudmila</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-b59910ffcc0080e0c79034fd108e486fc4712112b0ff9289ca9e8068d825df3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diagnostic Radiology</topic><topic>Fluorination</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Lanthanides</topic><topic>Nitric acid</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alyapyshev, Mikhail</creatorcontrib><creatorcontrib>Babain, Vasiliy</creatorcontrib><creatorcontrib>Eliseev, Ivan</creatorcontrib><creatorcontrib>Kenf, Ekaterina</creatorcontrib><creatorcontrib>Tkachenko, Lyudmila</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alyapyshev, Mikhail</au><au>Babain, Vasiliy</au><au>Eliseev, Ivan</au><au>Kenf, Ekaterina</au><au>Tkachenko, Lyudmila</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New polar fluorinated diluents for diamide extractants</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2016-11-01</date><risdate>2016</risdate><volume>310</volume><issue>2</issue><spage>785</spage><epage>792</epage><pages>785-792</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>The extraction properties of TODGA solutions in novel polar fluorinated diluents were investigated. 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subjects | Chemistry Chemistry and Materials Science Diagnostic Radiology Fluorination Hadrons Heavy Ions Inorganic Chemistry Lanthanides Nitric acid Nuclear Chemistry Nuclear Physics Physical Chemistry |
title | New polar fluorinated diluents for diamide extractants |
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