On the gassing behavior of lithium-ion batteries with NCM523 cathodes
Gas evolution has a profound effect on the functioning of state-of-the-art lithium-ion batteries. On one hand, it is the natural concomitant of solid electrolyte interphase (SEI) formation on the anode (reduction of electrolyte components). On the other hand, because of the demand for high terminal...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2016-11, Vol.20 (11), p.2961-2967 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Berkes, Balázs B. Schiele, Alexander Sommer, Heino Brezesinski, Torsten Janek, Jürgen |
| description | Gas evolution has a profound effect on the functioning of state-of-the-art lithium-ion batteries. On one hand, it is the natural concomitant of solid electrolyte interphase (SEI) formation on the anode (reduction of electrolyte components). On the other hand, because of the demand for high terminal voltages, it is also the consequence of electrolyte and/or cathode material oxidation. Overall, gassing happens on the expense of Coulombic efficiency and additionally raises safety issues. Herein, the gassing behavior of one of the most important commercialized cathode materials, namely Ni-rich Li
1 +
x
Ni
0.5
Co
0.2
Mn
0.3
O
2
(NCM523 with 0.01 |
| doi_str_mv | 10.1007/s10008-016-3362-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880854076</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880854076</sourcerecordid><originalsourceid>FETCH-LOGICAL-c357t-129c1cb0ddd95baf3e2fbc788ddc0f9304a564def4af4b11814ede5304ff57043</originalsourceid><addsrcrecordid>eNp1kD9PwzAQxS0EEqXwAdgsMRvOsZ04I6oKRSp0gdly_KdJ1SbFdkF8e1zCwMJyd3p67073Q-iawi0FqO5iriAJ0JIwVhakPkETyhkjUJXy9GcuiORSnqOLGDcAtCopTNB81ePUOrzWMXb9Gjeu1R_dEPDg8bZLbXfYkW7ocaNTcqFzEX9mFb_MnkXBsNGpHayLl-jM6210V799it4e5q-zBVmuHp9m90timKgSoUVtqGnAWluLRnvmCt-YSkprDfiaAdei5NZ5rj1vKJWUO-tE1r0XFXA2RTfj3n0Y3g8uJrUZDqHPJxWVEqTg-d3soqPLhCHG4Lzah26nw5eioI601EhLZVrqSEvVOVOMmZi9_dqFP5v_DX0DxdZsDg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880854076</pqid></control><display><type>article</type><title>On the gassing behavior of lithium-ion batteries with NCM523 cathodes</title><source>SpringerLink Journals</source><creator>Berkes, Balázs B. ; Schiele, Alexander ; Sommer, Heino ; Brezesinski, Torsten ; Janek, Jürgen</creator><creatorcontrib>Berkes, Balázs B. ; Schiele, Alexander ; Sommer, Heino ; Brezesinski, Torsten ; Janek, Jürgen</creatorcontrib><description>Gas evolution has a profound effect on the functioning of state-of-the-art lithium-ion batteries. On one hand, it is the natural concomitant of solid electrolyte interphase (SEI) formation on the anode (reduction of electrolyte components). On the other hand, because of the demand for high terminal voltages, it is also the consequence of electrolyte and/or cathode material oxidation. Overall, gassing happens on the expense of Coulombic efficiency and additionally raises safety issues. Herein, the gassing behavior of one of the most important commercialized cathode materials, namely Ni-rich Li
1 +
x
Ni
0.5
Co
0.2
Mn
0.3
O
2
(NCM523 with 0.01 <
x
< 0.05), is reported for the first time. We analyze the generation pattern of the most typical gases H
2
, C
2
H
4
, CO
2
, and CO during 30 cycles by means of differential electrochemical mass spectrometry combined with Fourier transform infrared spectroscopy. In a long-term test of an NCM523/graphite cell, we monitor its potential-resolved gas evolution and evaluate the total amount of gas from cycle to cycle. An explanation on the characteristic features of pressure versus time curves during cycling is given by combining the spectrometric and total gas pressure data. With additional information from graphite/lithium cells, the identity of gases formed during SEI formation is revealed.</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-016-3362-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Cathodes ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Commercialization ; Condensed Matter Physics ; Electrochemistry ; Electrode materials ; Electrolytes ; Electrolytic cells ; Energy Storage ; Fourier transforms ; Gas evolution ; Gas pressure ; Gases ; Graphite ; Infrared analysis ; Lithium ; Lithium-ion batteries ; Mass spectrometry ; Original Paper ; Oxidation ; Pattern analysis ; Physical Chemistry ; Solid electrolytes</subject><ispartof>Journal of solid state electrochemistry, 2016-11, Vol.20 (11), p.2961-2967</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c357t-129c1cb0ddd95baf3e2fbc788ddc0f9304a564def4af4b11814ede5304ff57043</citedby><cites>FETCH-LOGICAL-c357t-129c1cb0ddd95baf3e2fbc788ddc0f9304a564def4af4b11814ede5304ff57043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-016-3362-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-016-3362-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Berkes, Balázs B.</creatorcontrib><creatorcontrib>Schiele, Alexander</creatorcontrib><creatorcontrib>Sommer, Heino</creatorcontrib><creatorcontrib>Brezesinski, Torsten</creatorcontrib><creatorcontrib>Janek, Jürgen</creatorcontrib><title>On the gassing behavior of lithium-ion batteries with NCM523 cathodes</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>Gas evolution has a profound effect on the functioning of state-of-the-art lithium-ion batteries. On one hand, it is the natural concomitant of solid electrolyte interphase (SEI) formation on the anode (reduction of electrolyte components). On the other hand, because of the demand for high terminal voltages, it is also the consequence of electrolyte and/or cathode material oxidation. Overall, gassing happens on the expense of Coulombic efficiency and additionally raises safety issues. Herein, the gassing behavior of one of the most important commercialized cathode materials, namely Ni-rich Li
1 +
x
Ni
0.5
Co
0.2
Mn
0.3
O
2
(NCM523 with 0.01 <
x
< 0.05), is reported for the first time. We analyze the generation pattern of the most typical gases H
2
, C
2
H
4
, CO
2
, and CO during 30 cycles by means of differential electrochemical mass spectrometry combined with Fourier transform infrared spectroscopy. In a long-term test of an NCM523/graphite cell, we monitor its potential-resolved gas evolution and evaluate the total amount of gas from cycle to cycle. An explanation on the characteristic features of pressure versus time curves during cycling is given by combining the spectrometric and total gas pressure data. With additional information from graphite/lithium cells, the identity of gases formed during SEI formation is revealed.</description><subject>Analytical Chemistry</subject><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Commercialization</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrolytes</subject><subject>Electrolytic cells</subject><subject>Energy Storage</subject><subject>Fourier transforms</subject><subject>Gas evolution</subject><subject>Gas pressure</subject><subject>Gases</subject><subject>Graphite</subject><subject>Infrared analysis</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Mass spectrometry</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Pattern analysis</subject><subject>Physical Chemistry</subject><subject>Solid electrolytes</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kD9PwzAQxS0EEqXwAdgsMRvOsZ04I6oKRSp0gdly_KdJ1SbFdkF8e1zCwMJyd3p67073Q-iawi0FqO5iriAJ0JIwVhakPkETyhkjUJXy9GcuiORSnqOLGDcAtCopTNB81ePUOrzWMXb9Gjeu1R_dEPDg8bZLbXfYkW7ocaNTcqFzEX9mFb_MnkXBsNGpHayLl-jM6210V799it4e5q-zBVmuHp9m90timKgSoUVtqGnAWluLRnvmCt-YSkprDfiaAdei5NZ5rj1vKJWUO-tE1r0XFXA2RTfj3n0Y3g8uJrUZDqHPJxWVEqTg-d3soqPLhCHG4Lzah26nw5eioI601EhLZVrqSEvVOVOMmZi9_dqFP5v_DX0DxdZsDg</recordid><startdate>20161101</startdate><enddate>20161101</enddate><creator>Berkes, Balázs B.</creator><creator>Schiele, Alexander</creator><creator>Sommer, Heino</creator><creator>Brezesinski, Torsten</creator><creator>Janek, Jürgen</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20161101</creationdate><title>On the gassing behavior of lithium-ion batteries with NCM523 cathodes</title><author>Berkes, Balázs B. ; Schiele, Alexander ; Sommer, Heino ; Brezesinski, Torsten ; Janek, Jürgen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c357t-129c1cb0ddd95baf3e2fbc788ddc0f9304a564def4af4b11814ede5304ff57043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Analytical Chemistry</topic><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Commercialization</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrolytes</topic><topic>Electrolytic cells</topic><topic>Energy Storage</topic><topic>Fourier transforms</topic><topic>Gas evolution</topic><topic>Gas pressure</topic><topic>Gases</topic><topic>Graphite</topic><topic>Infrared analysis</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Mass spectrometry</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Pattern analysis</topic><topic>Physical Chemistry</topic><topic>Solid electrolytes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berkes, Balázs B.</creatorcontrib><creatorcontrib>Schiele, Alexander</creatorcontrib><creatorcontrib>Sommer, Heino</creatorcontrib><creatorcontrib>Brezesinski, Torsten</creatorcontrib><creatorcontrib>Janek, Jürgen</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berkes, Balázs B.</au><au>Schiele, Alexander</au><au>Sommer, Heino</au><au>Brezesinski, Torsten</au><au>Janek, Jürgen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the gassing behavior of lithium-ion batteries with NCM523 cathodes</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2016-11-01</date><risdate>2016</risdate><volume>20</volume><issue>11</issue><spage>2961</spage><epage>2967</epage><pages>2961-2967</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>Gas evolution has a profound effect on the functioning of state-of-the-art lithium-ion batteries. On one hand, it is the natural concomitant of solid electrolyte interphase (SEI) formation on the anode (reduction of electrolyte components). On the other hand, because of the demand for high terminal voltages, it is also the consequence of electrolyte and/or cathode material oxidation. Overall, gassing happens on the expense of Coulombic efficiency and additionally raises safety issues. Herein, the gassing behavior of one of the most important commercialized cathode materials, namely Ni-rich Li
1 +
x
Ni
0.5
Co
0.2
Mn
0.3
O
2
(NCM523 with 0.01 <
x
< 0.05), is reported for the first time. We analyze the generation pattern of the most typical gases H
2
, C
2
H
4
, CO
2
, and CO during 30 cycles by means of differential electrochemical mass spectrometry combined with Fourier transform infrared spectroscopy. In a long-term test of an NCM523/graphite cell, we monitor its potential-resolved gas evolution and evaluate the total amount of gas from cycle to cycle. An explanation on the characteristic features of pressure versus time curves during cycling is given by combining the spectrometric and total gas pressure data. With additional information from graphite/lithium cells, the identity of gases formed during SEI formation is revealed.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-016-3362-9</doi><tpages>7</tpages></addata></record> |
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| subjects | Analytical Chemistry Cathodes Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Commercialization Condensed Matter Physics Electrochemistry Electrode materials Electrolytes Electrolytic cells Energy Storage Fourier transforms Gas evolution Gas pressure Gases Graphite Infrared analysis Lithium Lithium-ion batteries Mass spectrometry Original Paper Oxidation Pattern analysis Physical Chemistry Solid electrolytes |
| title | On the gassing behavior of lithium-ion batteries with NCM523 cathodes |
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