Synthesis and Structural and Initial Cancer Cell Line Characterization of Organotin Polyesters from Dipicolinic Acid

The interfacial polymerization is employed to produce high polymer poly(ester ethers) from the reaction of the salt of dipicolinic acid and various organotin dihalides. They are rapidly synthesized with yield increasing as the length of the organotin alkyl chain increases. Infrared spectroscopy show...

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Veröffentlicht in:	Journal of inorganic and organometallic polymers and materials 2016-11, Vol.26 (6), p.1338-1350
Hauptverfasser:	Carraher, Charles E., Slawek, Paul P., Roner, Michael R., Moric-Johnson, Alisa, Miller, Lindsey C., Einkauf, Jeffrey D., Russell, Floyd
Format:	Artikel
Sprache:	eng
Schlagworte:	Cancer Chemistry Chemistry and Materials Science Ethers High polymers Inorganic Chemistry Organic Chemistry Polyester resins Polymer Sciences Tin
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creator	Carraher, Charles E. Slawek, Paul P. Roner, Michael R. Moric-Johnson, Alisa Miller, Lindsey C. Einkauf, Jeffrey D. Russell, Floyd
description	The interfacial polymerization is employed to produce high polymer poly(ester ethers) from the reaction of the salt of dipicolinic acid and various organotin dihalides. They are rapidly synthesized with yield increasing as the length of the organotin alkyl chain increases. Infrared spectroscopy shows the formation of new bands derived from the Sn–O and Sn–O(CO) linkages. IR also shows that the products exist as a combination of molecular geometries about the tin atom. MALDI MS shows formation of ion fragment clusters to five and six units in length. The products show good inhibition of a variety of cancer cell lines including two pancreatic cancer cell lines.
doi_str_mv	10.1007/s10904-016-0424-5
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subjects	Cancer Chemistry Chemistry and Materials Science Ethers High polymers Inorganic Chemistry Organic Chemistry Polyester resins Polymer Sciences Tin
title	Synthesis and Structural and Initial Cancer Cell Line Characterization of Organotin Polyesters from Dipicolinic Acid
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