Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K
The paper presents new experimental data on the chemical equilibrium in the system n -propanol + acetic acid + n -propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equil...
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| Veröffentlicht in: | Theoretical foundations of chemical engineering 2016, Vol.50 (5), p.739-745 |
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| container_title | Theoretical foundations of chemical engineering |
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| creator | Samarov, A. A. Toikka, M. A. Naumkin, P. V. Toikka, A. M. |
| description | The paper presents new experimental data on the chemical equilibrium in the system
n
-propanol + acetic acid +
n
-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed. |
| doi_str_mv | 10.1134/S0040579516050377 |
| format | Article |
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n
-propanol + acetic acid +
n
-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.</description><identifier>ISSN: 0040-5795</identifier><identifier>EISSN: 1608-3431</identifier><identifier>DOI: 10.1134/S0040579516050377</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acetic acid ; Chemical composition ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Liquid phases ; Liquid-liquid equilibrium ; Phase equilibria</subject><ispartof>Theoretical foundations of chemical engineering, 2016, Vol.50 (5), p.739-745</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2687-b135aabd6ff99d071deffc58dc4418735a96d8b0878a8729b4a59b8681e3641a3</citedby><cites>FETCH-LOGICAL-c2687-b135aabd6ff99d071deffc58dc4418735a96d8b0878a8729b4a59b8681e3641a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0040579516050377$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0040579516050377$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Samarov, A. A.</creatorcontrib><creatorcontrib>Toikka, M. A.</creatorcontrib><creatorcontrib>Naumkin, P. V.</creatorcontrib><creatorcontrib>Toikka, A. M.</creatorcontrib><title>Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K</title><title>Theoretical foundations of chemical engineering</title><addtitle>Theor Found Chem Eng</addtitle><description>The paper presents new experimental data on the chemical equilibrium in the system
n
-propanol + acetic acid +
n
-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.</description><subject>Acetic acid</subject><subject>Chemical composition</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Liquid phases</subject><subject>Liquid-liquid equilibrium</subject><subject>Phase equilibria</subject><issn>0040-5795</issn><issn>1608-3431</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1UEtLAzEQDqJgrf4AbwGPsjWzeR-l-MKCB_W8ZDfZNmW7u022SO_-cNNWRBBP38x8jxkGoUsgEwDKbl4JYYRLzUEQTqiUR2iUSpVRRuEYjXZ0tuNP0VmMS0KIFkKP0Od04Va-Mg12641vfBn8ZoVNa3Hj08Bm_cJEh2Pf-GHw7Rz7FpvKDb5K4C2-xm3Wh643bdf8NNtmrzGDS6OPBAHHbRxcCh5wrukE-H4F5fvy-Ryd1KaJ7uIbx-j9_u5t-pjNXh6eprezrMqFklkJlBtTWlHXWlsiwbq6rriyFWOgZCK1sKokSiqjZK5LZrgulVDgqGBg6BhdHXLTkeuNi0Ox7DahTSsLUIooJgF4UsFBVYUuxuDqog9-ZcK2AFLsnl38eXby5AdPTNp27sKv5H9NX6DMfjQ</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Samarov, A. A.</creator><creator>Toikka, M. A.</creator><creator>Naumkin, P. V.</creator><creator>Toikka, A. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2016</creationdate><title>Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K</title><author>Samarov, A. A. ; Toikka, M. A. ; Naumkin, P. V. ; Toikka, A. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2687-b135aabd6ff99d071deffc58dc4418735a96d8b0878a8729b4a59b8681e3641a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acetic acid</topic><topic>Chemical composition</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Liquid phases</topic><topic>Liquid-liquid equilibrium</topic><topic>Phase equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Samarov, A. A.</creatorcontrib><creatorcontrib>Toikka, M. A.</creatorcontrib><creatorcontrib>Naumkin, P. V.</creatorcontrib><creatorcontrib>Toikka, A. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Theoretical foundations of chemical engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Samarov, A. A.</au><au>Toikka, M. A.</au><au>Naumkin, P. V.</au><au>Toikka, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K</atitle><jtitle>Theoretical foundations of chemical engineering</jtitle><stitle>Theor Found Chem Eng</stitle><date>2016</date><risdate>2016</risdate><volume>50</volume><issue>5</issue><spage>739</spage><epage>745</epage><pages>739-745</pages><issn>0040-5795</issn><eissn>1608-3431</eissn><abstract>The paper presents new experimental data on the chemical equilibrium in the system
n
-propanol + acetic acid +
n
-propyl acetate + water at 293.15 and 353.15 K, and the data on liquid–liquid equilibrium at 353.15 K. Based on the experimental and literature data, the possibilities that chemical equilibrium exists in a homogeneous or heterogeneous region of compositions has been analyzed. The temperature shift of chemical and phase equilibria and the values of the thermodynamic constants of chemical equilibrium are discussed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0040579516050377</doi><tpages>7</tpages></addata></record> |
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| ispartof | Theoretical foundations of chemical engineering, 2016, Vol.50 (5), p.739-745 |
| issn | 0040-5795 1608-3431 |
| language | eng |
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| source | Springer Journals |
| subjects | Acetic acid Chemical composition Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Liquid phases Liquid-liquid equilibrium Phase equilibria |
| title | Chemical equilibrium and liquid-phase splitting in acetic acid + n-propanol + n-propyl acetate + water system at 293.15 and 353.15 K |
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