A mild and highly chemoselective iodination of alcohol using polymer supported DMAP
The synthesis of organic compounds using polymer supported catalysts and reagents, where the required product is always in solution, has been of great interest in recent years, both in industries and academia especially in pharmaceutical research. Here, a simple and efficient method for conversion o...
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| Veröffentlicht in: | Journal of chemical sciences (Bangalore, India) India), 2016-11, Vol.128 (11), p.1695-1701 |
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| container_end_page | 1701 |
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| container_issue | 11 |
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| container_title | Journal of chemical sciences (Bangalore, India) |
| container_volume | 128 |
| creator | DAS, DIPARJUN H ANAL, JASHA MOMO ROKHUM, SAMUEL LALTHAZUALA |
| description | The synthesis of organic compounds using polymer supported catalysts and reagents, where the required product is always in solution, has been of great interest in recent years, both in industries and academia especially in pharmaceutical research. Here, a simple and efficient method for conversion of alcohols into their iodides in high yield using polymer supported 4-(Dimethylamino)pyridine (DMAP) is described. Polymer supported DMAP is used in catalytic amount and is recovered and reused several times. Additionally, this method is highly chemoselective.
Graphical Abstract
A mild and highly selective iodination of alcohols using polymer supported 4-(Dimethylamino)pyridine (DMAP) in catalytic amount is reported. The base catalyst can be easily recovered by simple filtration and reused several times without appreciable loss in activity. |
| doi_str_mv | 10.1007/s12039-016-1158-1 |
| format | Article |
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Graphical Abstract
A mild and highly selective iodination of alcohols using polymer supported 4-(Dimethylamino)pyridine (DMAP) in catalytic amount is reported. The base catalyst can be easily recovered by simple filtration and reused several times without appreciable loss in activity.</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-016-1158-1</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Addition polymerization ; Alcohols ; Catalytic converters ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Iodination ; Organic compounds ; Polymers ; Reagents</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2016-11, Vol.128 (11), p.1695-1701</ispartof><rights>Indian Academy of Sciences 2016</rights><rights>Indian Academy of Sciences 2016.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-97db4f1ef48498d6a5261bab77f06e14901510be6240f02ea10f127a3b5bfe993</citedby><cites>FETCH-LOGICAL-c359t-97db4f1ef48498d6a5261bab77f06e14901510be6240f02ea10f127a3b5bfe993</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12039-016-1158-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12039-016-1158-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>DAS, DIPARJUN</creatorcontrib><creatorcontrib>H ANAL, JASHA MOMO</creatorcontrib><creatorcontrib>ROKHUM, SAMUEL LALTHAZUALA</creatorcontrib><title>A mild and highly chemoselective iodination of alcohol using polymer supported DMAP</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>The synthesis of organic compounds using polymer supported catalysts and reagents, where the required product is always in solution, has been of great interest in recent years, both in industries and academia especially in pharmaceutical research. Here, a simple and efficient method for conversion of alcohols into their iodides in high yield using polymer supported 4-(Dimethylamino)pyridine (DMAP) is described. Polymer supported DMAP is used in catalytic amount and is recovered and reused several times. Additionally, this method is highly chemoselective.
Graphical Abstract
A mild and highly selective iodination of alcohols using polymer supported 4-(Dimethylamino)pyridine (DMAP) in catalytic amount is reported. The base catalyst can be easily recovered by simple filtration and reused several times without appreciable loss in activity.</description><subject>Addition polymerization</subject><subject>Alcohols</subject><subject>Catalytic converters</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Iodination</subject><subject>Organic compounds</subject><subject>Polymers</subject><subject>Reagents</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxDAUhYMoOI7-AHcB19F7m_S1HMYnjCio65C2yTRD29SkFebf27Eu3Li6Z3G-c-Ej5BLhGgHSm4AR8JwBJgwxzhgekQXkKWcpAj_-yYLxJEpOyVkIOwCeiZQvyNuKtrapqOoqWttt3expWevWBd3ocrBfmlpX2U4N1nXUGaqa0tWuoWOw3Zb2rtm32tMw9r3zg67o7fPq9ZycGNUEffF7l-Tj_u59_cg2Lw9P69WGlTzOB5anVSEMaiMykWdVouIowUIVaWog0ShywBih0EkkwECkFYLBKFW8iAuj85wvydW823v3OeowyJ0bfTe9lJhlkAmBHKcWzq3SuxC8NrL3tlV-LxHkwZ2c3cnJnTy4kwcmmpkwdbut9n-W_4W-AR84cQQ</recordid><startdate>20161101</startdate><enddate>20161101</enddate><creator>DAS, DIPARJUN</creator><creator>H ANAL, JASHA MOMO</creator><creator>ROKHUM, SAMUEL LALTHAZUALA</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20161101</creationdate><title>A mild and highly chemoselective iodination of alcohol using polymer supported DMAP</title><author>DAS, DIPARJUN ; H ANAL, JASHA MOMO ; ROKHUM, SAMUEL LALTHAZUALA</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-97db4f1ef48498d6a5261bab77f06e14901510be6240f02ea10f127a3b5bfe993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Addition polymerization</topic><topic>Alcohols</topic><topic>Catalytic converters</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Iodination</topic><topic>Organic compounds</topic><topic>Polymers</topic><topic>Reagents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>DAS, DIPARJUN</creatorcontrib><creatorcontrib>H ANAL, JASHA MOMO</creatorcontrib><creatorcontrib>ROKHUM, SAMUEL LALTHAZUALA</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>DAS, DIPARJUN</au><au>H ANAL, JASHA MOMO</au><au>ROKHUM, SAMUEL LALTHAZUALA</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A mild and highly chemoselective iodination of alcohol using polymer supported DMAP</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2016-11-01</date><risdate>2016</risdate><volume>128</volume><issue>11</issue><spage>1695</spage><epage>1701</epage><pages>1695-1701</pages><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>The synthesis of organic compounds using polymer supported catalysts and reagents, where the required product is always in solution, has been of great interest in recent years, both in industries and academia especially in pharmaceutical research. Here, a simple and efficient method for conversion of alcohols into their iodides in high yield using polymer supported 4-(Dimethylamino)pyridine (DMAP) is described. Polymer supported DMAP is used in catalytic amount and is recovered and reused several times. Additionally, this method is highly chemoselective.
Graphical Abstract
A mild and highly selective iodination of alcohols using polymer supported 4-(Dimethylamino)pyridine (DMAP) in catalytic amount is reported. The base catalyst can be easily recovered by simple filtration and reused several times without appreciable loss in activity.</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-016-1158-1</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Journal of chemical sciences (Bangalore, India), 2016-11, Vol.128 (11), p.1695-1701 |
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| language | eng |
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| source | SpringerLink Journals; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Addition polymerization Alcohols Catalytic converters Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Iodination Organic compounds Polymers Reagents |
| title | A mild and highly chemoselective iodination of alcohol using polymer supported DMAP |
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