Blue AIEgens bearing triphenylethylene peripheral: adjustable intramolecular conjugation and good device performance

The new approaches to construct deep blue aggregation-induced emission (ALE) materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of organic light-emitting diodes. In order to shorten the intramolecular conjugation le...

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Veröffentlicht in:Science bulletin (Beijing) 2016-11, Vol.61 (22), p.1746-1755
Hauptverfasser: Wang, Can, Li, Le, Zhan, Xuejun, Ruan, Zhijun, Xie, Yujun, Hu, Quanyuan, Ye, Shanghui, Li, Qianqian, Li, Zhen
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container_end_page 1755
container_issue 22
container_start_page 1746
container_title Science bulletin (Beijing)
container_volume 61
creator Wang, Can
Li, Le
Zhan, Xuejun
Ruan, Zhijun
Xie, Yujun
Hu, Quanyuan
Ye, Shanghui
Li, Qianqian
Li, Zhen
description The new approaches to construct deep blue aggregation-induced emission (ALE) materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of organic light-emitting diodes. In order to shorten the intramolecular conjugation length, triphenylethylene (tPE) was utilized to construct blue AIEgens as peripheral groups, instead of tetraphenylethylene (TPE), the famous AIE star molecule, to yield three blue AIEgens of 3,4-BtPE-PI, 4,4- BtPE-PI and 4,4-BtPE-PPI. Nondoped electroluminescence devices are fabricated by using these three AIEgens as the emitting material layer, the best performance of 3.8 cd/A as the maximum current efficiency achieved at the commission internationale de l'Eclairage coordinates of (0.17, 0.18).
doi_str_mv 10.1007/s11434-016-1180-1
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subjects Aggregation induced emission
Blue emission
Chemistry/Food Science
Commercialization
Conjugation
Current efficiency
Diodes
Earth Sciences
Engineering
Humanities and Social Sciences
Intramolecular conjugation
Life Sciences
multidisciplinary
OLEDs
Organic light emitting diodes
Physics
Science
Science (multidisciplinary)
Triphenylethylene
title Blue AIEgens bearing triphenylethylene peripheral: adjustable intramolecular conjugation and good device performance
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