Solvation state of iron(III) in aqueous solutions of dimethyl sulfoxide. Complex formation ability of iron(III) with respect to derivatives of sym-triazine and bis(hydrazinocarbonylmethyl) sulfoxide

Parameters of the solvation equilibria [ F e ( H 2 O ) 6 ] 3 + + n D M S O ⇄ [ F e ( H 2 O ) 6 − n ( D M S O ) n ] 3 + + n H 2 O have been determined in aqueous-dimethyl sulfoxide solutions (0–90 vol% DMSO) by means of spectrophotometry and mathematical modeling of equilibria. Iron(III) is not invol...

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Veröffentlicht in:	Russian journal of general chemistry 2016-10, Vol.86 (10), p.2367-2374
Hauptverfasser:	Neklyudov, V. V., Boos, G. A., Chmutova, G. A., Fattakhov, S. G., Shulaeva, M. M., Bagina, Yu. I., Salnikov, Yu. I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemistry Chemistry and Materials Science Chemistry/Food Science Complex formation Copper Density functional theory Dimethyl sulfoxide Iron Nickel Solvation Spectrophotometry Sulfoxides
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