Synthesis, crystal structure, thermal and dielectric properties of tetrapropylammonium tetrabromozincate [N(C3H7)4]2[ZnBr4] compound
The new organic–inorganic compound tetrapropylammonium tetrabromozincate [N(C 3 H 7 ) 4 ] 2 ZnBr 4 has been synthesized and characterized by single-crystal X-ray diffraction, differential scanning calorimetry, IR, Raman and impedance measurements. The crystal structure refinement shows that the [N(C...
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| Veröffentlicht in: | Applied physics. A, Materials science & processing Materials science & processing, 2016-12, Vol.122 (12), p.1-8, Article 1066 |
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| creator | Chkoundali, Souad Hlel, Faouzi Khemekhem, Hamadi |
| description | The new organic–inorganic compound tetrapropylammonium tetrabromozincate [N(C
3
H
7
)
4
]
2
ZnBr
4
has been synthesized and characterized by single-crystal X-ray diffraction, differential scanning calorimetry, IR, Raman and impedance measurements. The crystal structure refinement shows that the [N(C
3
H
7
)
4
]
2
ZnBr
4
compound is crystallized in the monoclinic system (space group C
2/c
) with the following unit cell parameters:
a
= 33.145(5) Å,
b
= 14.234(3) Å,
c
= 15.081(2) Å,
β
= 110.207(5)° and
Z
= 8. The structural arrangement of the title compound can be described as an alternation of organic and inorganic layers along the [100] direction. Differential scanning calorimetry disclosed two order–disorder transition phases located at 340 and 393 K. Besides, an analysis of the dielectric constants
ε
′ and
ε
″, at several frequencies, shows a distribution of relaxation times. This relaxation is probably due to the reorientational dynamics of alkyl chains. |
| doi_str_mv | 10.1007/s00339-016-0596-4 |
| format | Article |
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3
H
7
)
4
]
2
ZnBr
4
has been synthesized and characterized by single-crystal X-ray diffraction, differential scanning calorimetry, IR, Raman and impedance measurements. The crystal structure refinement shows that the [N(C
3
H
7
)
4
]
2
ZnBr
4
compound is crystallized in the monoclinic system (space group C
2/c
) with the following unit cell parameters:
a
= 33.145(5) Å,
b
= 14.234(3) Å,
c
= 15.081(2) Å,
β
= 110.207(5)° and
Z
= 8. The structural arrangement of the title compound can be described as an alternation of organic and inorganic layers along the [100] direction. Differential scanning calorimetry disclosed two order–disorder transition phases located at 340 and 393 K. Besides, an analysis of the dielectric constants
ε
′ and
ε
″, at several frequencies, shows a distribution of relaxation times. This relaxation is probably due to the reorientational dynamics of alkyl chains.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-016-0596-4</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied physics ; Characterization and Evaluation of Materials ; Condensed Matter Physics ; Crystal structure ; Crystallization ; Dielectric properties ; Differential scanning calorimetry ; Heat measurement ; Inorganic compounds ; Machines ; Manufacturing ; Materials science ; Nanotechnology ; Optical and Electronic Materials ; Physics ; Physics and Astronomy ; Processes ; Single crystals ; Surfaces and Interfaces ; Thin Films ; Unit cell</subject><ispartof>Applied physics. A, Materials science & processing, 2016-12, Vol.122 (12), p.1-8, Article 1066</ispartof><rights>The Author(s) 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2744-53f5e2307407c1e288daf0b12b90e7de0b147655266305c380697c2e387770c33</citedby><cites>FETCH-LOGICAL-c2744-53f5e2307407c1e288daf0b12b90e7de0b147655266305c380697c2e387770c33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-016-0596-4$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-016-0596-4$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Chkoundali, Souad</creatorcontrib><creatorcontrib>Hlel, Faouzi</creatorcontrib><creatorcontrib>Khemekhem, Hamadi</creatorcontrib><title>Synthesis, crystal structure, thermal and dielectric properties of tetrapropylammonium tetrabromozincate [N(C3H7)4]2[ZnBr4] compound</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>The new organic–inorganic compound tetrapropylammonium tetrabromozincate [N(C
3
H
7
)
4
]
2
ZnBr
4
has been synthesized and characterized by single-crystal X-ray diffraction, differential scanning calorimetry, IR, Raman and impedance measurements. The crystal structure refinement shows that the [N(C
3
H
7
)
4
]
2
ZnBr
4
compound is crystallized in the monoclinic system (space group C
2/c
) with the following unit cell parameters:
a
= 33.145(5) Å,
b
= 14.234(3) Å,
c
= 15.081(2) Å,
β
= 110.207(5)° and
Z
= 8. The structural arrangement of the title compound can be described as an alternation of organic and inorganic layers along the [100] direction. Differential scanning calorimetry disclosed two order–disorder transition phases located at 340 and 393 K. Besides, an analysis of the dielectric constants
ε
′ and
ε
″, at several frequencies, shows a distribution of relaxation times. This relaxation is probably due to the reorientational dynamics of alkyl chains.</description><subject>Applied physics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Dielectric properties</subject><subject>Differential scanning calorimetry</subject><subject>Heat measurement</subject><subject>Inorganic compounds</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Single crystals</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Unit cell</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp1UD1PwzAQtRBIlMIPYLPEAlID54_EyQgVUCQEA7CAkJU6Fwhq4mI7Q5j54bgKAwu33Onde_fxCDlkcMoA1JkHEKJIgGUJpEWWyC0yYVLwBDIB22QChVRJLopsl-x5_wExJOcT8v0wdOEdfeNn1LjBh3JFfXC9Cb3DGY0t10ao7CpaNbhCE1xj6NrZNbrQoKe2pgGDKzfQsCrb1nZN347Y0tnWfjWdKQPSl7vjuVioE_nKX567CydfqbHt2vZdtU926nLl8eA3T8nT1eXjfJHc3l_fzM9vE8OVlEkq6hS5ACVBGYY8z6uyhiXjywJQVRhLqbI05Vn8OTUih6xQhqPIlVJghJiSo3FuPPazRx_0h-1dF1dqlueQs1TILLLYyDLOeu-w1mvXtKUbNAO9MVuPZutott6YrWXU8FHjI7d7Q_dn8r-iH-stgp0</recordid><startdate>20161201</startdate><enddate>20161201</enddate><creator>Chkoundali, Souad</creator><creator>Hlel, Faouzi</creator><creator>Khemekhem, Hamadi</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20161201</creationdate><title>Synthesis, crystal structure, thermal and dielectric properties of tetrapropylammonium tetrabromozincate [N(C3H7)4]2[ZnBr4] compound</title><author>Chkoundali, Souad ; Hlel, Faouzi ; Khemekhem, Hamadi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2744-53f5e2307407c1e288daf0b12b90e7de0b147655266305c380697c2e387770c33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Applied physics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Dielectric properties</topic><topic>Differential scanning calorimetry</topic><topic>Heat measurement</topic><topic>Inorganic compounds</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Single crystals</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chkoundali, Souad</creatorcontrib><creatorcontrib>Hlel, Faouzi</creatorcontrib><creatorcontrib>Khemekhem, Hamadi</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chkoundali, Souad</au><au>Hlel, Faouzi</au><au>Khemekhem, Hamadi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal structure, thermal and dielectric properties of tetrapropylammonium tetrabromozincate [N(C3H7)4]2[ZnBr4] compound</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2016-12-01</date><risdate>2016</risdate><volume>122</volume><issue>12</issue><spage>1</spage><epage>8</epage><pages>1-8</pages><artnum>1066</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>The new organic–inorganic compound tetrapropylammonium tetrabromozincate [N(C
3
H
7
)
4
]
2
ZnBr
4
has been synthesized and characterized by single-crystal X-ray diffraction, differential scanning calorimetry, IR, Raman and impedance measurements. The crystal structure refinement shows that the [N(C
3
H
7
)
4
]
2
ZnBr
4
compound is crystallized in the monoclinic system (space group C
2/c
) with the following unit cell parameters:
a
= 33.145(5) Å,
b
= 14.234(3) Å,
c
= 15.081(2) Å,
β
= 110.207(5)° and
Z
= 8. The structural arrangement of the title compound can be described as an alternation of organic and inorganic layers along the [100] direction. Differential scanning calorimetry disclosed two order–disorder transition phases located at 340 and 393 K. Besides, an analysis of the dielectric constants
ε
′ and
ε
″, at several frequencies, shows a distribution of relaxation times. This relaxation is probably due to the reorientational dynamics of alkyl chains.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-016-0596-4</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Applied physics. A, Materials science & processing, 2016-12, Vol.122 (12), p.1-8, Article 1066 |
| issn | 0947-8396 1432-0630 |
| language | eng |
| recordid | cdi_proquest_journals_1880815346 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Applied physics Characterization and Evaluation of Materials Condensed Matter Physics Crystal structure Crystallization Dielectric properties Differential scanning calorimetry Heat measurement Inorganic compounds Machines Manufacturing Materials science Nanotechnology Optical and Electronic Materials Physics Physics and Astronomy Processes Single crystals Surfaces and Interfaces Thin Films Unit cell |
| title | Synthesis, crystal structure, thermal and dielectric properties of tetrapropylammonium tetrabromozincate [N(C3H7)4]2[ZnBr4] compound |
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