[2+2] Cycloaddition of the Schrock titanium silylidene and acetylene

[2+2] Cycloadduct of the titanium silylidene Cp 2 Ti(thf)=Si[Si 3 (SiMeBu t 2 ) 4 ] and acetylene was readily prepared, isolated, and characterized by NMR spectroscopy and computational studies of the Me 3 Si-substituted model. Geometric features of the model, based on its optimized geometry, sugges...

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Veröffentlicht in:	Russian chemical bulletin 2016-04, Vol.65 (4), p.1139-1141
Hauptverfasser:	Lee, V. Ya, Gapurenko, O. A., Minkin, V. I., Horiguchi, S., Sekiguchi, A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Brief Communications Chemistry Chemistry and Materials Science Chemistry/Food Science Cycloaddition Inorganic Chemistry NMR spectroscopy Organic Chemistry Organometallic compounds Titanium
Online-Zugang:	Volltext
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