Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates
A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths （OF,） to the different positions of the spherical [60]fullerene （C60） through a rigid linkage. The conjugates were characterized by IH-NMR, 13C-NMR, FTIR, EA and MA...
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| Veröffentlicht in: | Chinese journal of polymer science 2017-04, Vol.35 (4), p.503-514 |
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| container_title | Chinese journal of polymer science |
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| creator | Teng, Fu-ai Liu, Feng-li Han, Lu Zhu, Zheng-ju Zhang, Yi-fang Wu, Zhi-jin Han, Zhe-wen Zhang, Wen-bin Li, Hui |
| description | A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths （OF,） to the different positions of the spherical [60]fullerene （C60） through a rigid linkage. The conjugates were characterized by IH-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores （C60 and OFn） in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self- assembly, structure-property relationship, and potential technical applications of the conjugates. |
| doi_str_mv | 10.1007/s10118-017-1899-4 |
| format | Article |
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The conjugates were characterized by IH-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores （C60 and OFn） in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self- assembly, structure-property relationship, and potential technical applications of the conjugates.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-017-1899-4</identifier><language>eng</language><publisher>Beijing: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Absorption spectroscopy ; Buckminsterfullerene ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chromophores ; Condensed Matter Physics ; Conjugates ; Connecting rods ; Energy transfer ; Fluorescence ; Fullerenes ; Industrial Chemistry/Chemical Engineering ; Mass spectrometry ; NMR ; Nuclear magnetic resonance ; Optical properties ; Polymer Sciences ; Scientific imaging ; Self-assembly ; Toluene ; Voltammetry</subject><ispartof>Chinese journal of polymer science, 2017-04, Vol.35 (4), p.503-514</ispartof><rights>Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2584-4580c0c0390ac05bf8e1fd021eb71a508ef95bd404c6315f7d9d6fd7b1eab7d73</citedby><cites>FETCH-LOGICAL-c2584-4580c0c0390ac05bf8e1fd021eb71a508ef95bd404c6315f7d9d6fd7b1eab7d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-017-1899-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-017-1899-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Teng, Fu-ai</creatorcontrib><creatorcontrib>Liu, Feng-li</creatorcontrib><creatorcontrib>Han, Lu</creatorcontrib><creatorcontrib>Zhu, Zheng-ju</creatorcontrib><creatorcontrib>Zhang, Yi-fang</creatorcontrib><creatorcontrib>Wu, Zhi-jin</creatorcontrib><creatorcontrib>Han, Zhe-wen</creatorcontrib><creatorcontrib>Zhang, Wen-bin</creatorcontrib><creatorcontrib>Li, Hui</creatorcontrib><title>Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><addtitle>Chinese Journal of Polymer Science</addtitle><description>A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths （OF,） to the different positions of the spherical [60]fullerene （C60） through a rigid linkage. 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It presents a systematic study on the self- assembly, structure-property relationship, and potential technical applications of the conjugates.</description><subject>Absorption spectroscopy</subject><subject>Buckminsterfullerene</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromophores</subject><subject>Condensed Matter Physics</subject><subject>Conjugates</subject><subject>Connecting rods</subject><subject>Energy transfer</subject><subject>Fluorescence</subject><subject>Fullerenes</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mass spectrometry</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical properties</subject><subject>Polymer Sciences</subject><subject>Scientific imaging</subject><subject>Self-assembly</subject><subject>Toluene</subject><subject>Voltammetry</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9UM1u1DAQthCVWFoegJsF15p6Esd2jmVpC1KlIhbOlhOPk6xSO7Wzh74CT42rXSFOaEaa0cz3I32EvAf-CThXVxk4gGYcFAPdtky8IhsQdctkxevXZMOrRjIlVfuGvM15z7kUqlEb8vsL5mkIl3T3HNax7PmS2uDow7JOvZ2vbmbs1xTD1NPvKS6Y1gkzjZ5ausN02nfLiAnZj-jobrQL0uvHZZxKz-X_2WZ0NAZa5OlWchbnaYh-PsSEoVxi2B8Gu2K-IGfezhnfneY5-XV783P7ld0_3H3bXt-zvmq0YKLRvC9Vt9z2vOm8RvCOV4CdAttwjb5tOie46GUNjVeuddI71QHaTjlVn5OPR90lxacD5tXs4yGFYmlAa66LlJAFBUdUn2LOCb1Z0vRo07MBbl4iN8fITYncvERuROFUR04u2DBg-kf5P6QPJ6MxhuGp8P46SQWVrmoJ9R8X95AU</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Teng, Fu-ai</creator><creator>Liu, Feng-li</creator><creator>Han, Lu</creator><creator>Zhu, Zheng-ju</creator><creator>Zhang, Yi-fang</creator><creator>Wu, Zhi-jin</creator><creator>Han, Zhe-wen</creator><creator>Zhang, Wen-bin</creator><creator>Li, Hui</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170401</creationdate><title>Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates</title><author>Teng, Fu-ai ; 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The conjugates were characterized by IH-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores （C60 and OFn） in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. 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| subjects | Absorption spectroscopy Buckminsterfullerene Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chromophores Condensed Matter Physics Conjugates Connecting rods Energy transfer Fluorescence Fullerenes Industrial Chemistry/Chemical Engineering Mass spectrometry NMR Nuclear magnetic resonance Optical properties Polymer Sciences Scientific imaging Self-assembly Toluene Voltammetry |
| title | Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates |
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