Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid
A stable three-dimensional coordination complex, {[Cd 1.5 (tta)(H 2 O) 4.5 ]·H 2 O} n ( 1) (tta = terphenyl—3,4″,5—tricarboxylic acid), was prepared by the solvothermal reaction of Cd(CH 3 COO) 2 ·2H 2 O and tta in water, which was characterized by infrared spectroscopy, single-crystal X-ray diffrac...
Gespeichert in:
| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2017, Vol.27 (1), p.80-86 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 86 |
|---|---|
| container_issue | 1 |
| container_start_page | 80 |
| container_title | Journal of inorganic and organometallic polymers and materials |
| container_volume | 27 |
| creator | Dai, Haiyu Wang, Cuijuan Tang, Yuyuan Tong, Yan Mao, Kaili Zhang, Zhibin Zhou, Xianli |
| description | A stable three-dimensional coordination complex, {[Cd
1.5
(tta)(H
2
O)
4.5
]·H
2
O}
n
(
1)
(tta = terphenyl—3,4″,5—tricarboxylic acid), was prepared by the solvothermal reaction of Cd(CH
3
COO)
2
·2H
2
O and tta in water, which was characterized by infrared spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, fluorescence, and thermogravimetric analyses. In the solid state of this compound, the Cd (II) center displayed a distorted trigonal bipyramid coordination sphere consisting of two oxygen atoms from two different carboxyl which were offered by two separate tta ligands and three oxygen atoms from three water molecules. The one-dimensional linear (1D) structure and two-dimensional plane were formed by Cd-O coordination bond while the 3D supramolecular reticular structure was formed by hydrogen-bond interactions. And there are large rectangular holes whose size are 13.30 × 13.31 Å along crystallographic axis
a
. The drug loading content (DLC) of
1
was 0.203 g (Ibu)/g (compound) and the release was desirable. |
| doi_str_mv | 10.1007/s10904-016-0446-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880796794</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880796794</sourcerecordid><originalsourceid>FETCH-LOGICAL-c231z-e6c57ba319daee5693281b7f625602e2ca38e76dcdaa4eac034487c2acbef6893</originalsourceid><addsrcrecordid>eNp1kcFu1DAQhiNEJUrLA3AbiQtIG2rHjpMcyxbKSitY0XK2vM5k11ViL7aDyJ76Dn0S1Dfqk-CyCHHhNDO__u-fw59lLyl5SwmpzgIlDeE5oSInnIt8_yQ7pmXFc8pL-vTvztmz7HkIN4SwmpT0OPt5Ndm4xWDCDK6iH3UcPc5gtXXR9eNgLAaNNoKyLVz4cQNLp1pjN7-FL9ijCggr73boo8EArgMFn9x37GGu2sGMA7xeLN7A3DmfOBWNs7By_TSgD_Au0S0k5Rr9bot26h9u79gM-MPt_QzKdERvtPJr92PqjYZzbdrT7KhTfcAXf-ZJ9vXD--v5x3z5-XIxP1_mumB0n6PQZbVWjDatQixFw4qarqtOFKUgBRZasRor0epWKY5KE8Z5XelC6TV2om7YSfbqkLvz7tuIIcobN3qbXkpa16RqRNXw5KIHl_YuBI-d3HkzKD9JSuRjM_LQjEzNyMdm5D4xxYEJyWs36P9J_i_0CzGBlqs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880796794</pqid></control><display><type>article</type><title>Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid</title><source>Springer Nature - Complete Springer Journals</source><creator>Dai, Haiyu ; Wang, Cuijuan ; Tang, Yuyuan ; Tong, Yan ; Mao, Kaili ; Zhang, Zhibin ; Zhou, Xianli</creator><creatorcontrib>Dai, Haiyu ; Wang, Cuijuan ; Tang, Yuyuan ; Tong, Yan ; Mao, Kaili ; Zhang, Zhibin ; Zhou, Xianli</creatorcontrib><description>A stable three-dimensional coordination complex, {[Cd
1.5
(tta)(H
2
O)
4.5
]·H
2
O}
n
(
1)
(tta = terphenyl—3,4″,5—tricarboxylic acid), was prepared by the solvothermal reaction of Cd(CH
3
COO)
2
·2H
2
O and tta in water, which was characterized by infrared spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, fluorescence, and thermogravimetric analyses. In the solid state of this compound, the Cd (II) center displayed a distorted trigonal bipyramid coordination sphere consisting of two oxygen atoms from two different carboxyl which were offered by two separate tta ligands and three oxygen atoms from three water molecules. The one-dimensional linear (1D) structure and two-dimensional plane were formed by Cd-O coordination bond while the 3D supramolecular reticular structure was formed by hydrogen-bond interactions. And there are large rectangular holes whose size are 13.30 × 13.31 Å along crystallographic axis
a
. The drug loading content (DLC) of
1
was 0.203 g (Ibu)/g (compound) and the release was desirable.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-016-0446-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Coordination polymers ; Hydrogen bonds ; Infrared spectroscopy ; Inorganic Chemistry ; Ligands ; Organic Chemistry ; Photoluminescence ; Polymer Sciences ; Single crystals</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2017, Vol.27 (1), p.80-86</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c231z-e6c57ba319daee5693281b7f625602e2ca38e76dcdaa4eac034487c2acbef6893</citedby><cites>FETCH-LOGICAL-c231z-e6c57ba319daee5693281b7f625602e2ca38e76dcdaa4eac034487c2acbef6893</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-016-0446-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-016-0446-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Dai, Haiyu</creatorcontrib><creatorcontrib>Wang, Cuijuan</creatorcontrib><creatorcontrib>Tang, Yuyuan</creatorcontrib><creatorcontrib>Tong, Yan</creatorcontrib><creatorcontrib>Mao, Kaili</creatorcontrib><creatorcontrib>Zhang, Zhibin</creatorcontrib><creatorcontrib>Zhou, Xianli</creatorcontrib><title>Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A stable three-dimensional coordination complex, {[Cd
1.5
(tta)(H
2
O)
4.5
]·H
2
O}
n
(
1)
(tta = terphenyl—3,4″,5—tricarboxylic acid), was prepared by the solvothermal reaction of Cd(CH
3
COO)
2
·2H
2
O and tta in water, which was characterized by infrared spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, fluorescence, and thermogravimetric analyses. In the solid state of this compound, the Cd (II) center displayed a distorted trigonal bipyramid coordination sphere consisting of two oxygen atoms from two different carboxyl which were offered by two separate tta ligands and three oxygen atoms from three water molecules. The one-dimensional linear (1D) structure and two-dimensional plane were formed by Cd-O coordination bond while the 3D supramolecular reticular structure was formed by hydrogen-bond interactions. And there are large rectangular holes whose size are 13.30 × 13.31 Å along crystallographic axis
a
. The drug loading content (DLC) of
1
was 0.203 g (Ibu)/g (compound) and the release was desirable.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Coordination polymers</subject><subject>Hydrogen bonds</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Organic Chemistry</subject><subject>Photoluminescence</subject><subject>Polymer Sciences</subject><subject>Single crystals</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kcFu1DAQhiNEJUrLA3AbiQtIG2rHjpMcyxbKSitY0XK2vM5k11ViL7aDyJ76Dn0S1Dfqk-CyCHHhNDO__u-fw59lLyl5SwmpzgIlDeE5oSInnIt8_yQ7pmXFc8pL-vTvztmz7HkIN4SwmpT0OPt5Ndm4xWDCDK6iH3UcPc5gtXXR9eNgLAaNNoKyLVz4cQNLp1pjN7-FL9ijCggr73boo8EArgMFn9x37GGu2sGMA7xeLN7A3DmfOBWNs7By_TSgD_Au0S0k5Rr9bot26h9u79gM-MPt_QzKdERvtPJr92PqjYZzbdrT7KhTfcAXf-ZJ9vXD--v5x3z5-XIxP1_mumB0n6PQZbVWjDatQixFw4qarqtOFKUgBRZasRor0epWKY5KE8Z5XelC6TV2om7YSfbqkLvz7tuIIcobN3qbXkpa16RqRNXw5KIHl_YuBI-d3HkzKD9JSuRjM_LQjEzNyMdm5D4xxYEJyWs36P9J_i_0CzGBlqs</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Dai, Haiyu</creator><creator>Wang, Cuijuan</creator><creator>Tang, Yuyuan</creator><creator>Tong, Yan</creator><creator>Mao, Kaili</creator><creator>Zhang, Zhibin</creator><creator>Zhou, Xianli</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid</title><author>Dai, Haiyu ; Wang, Cuijuan ; Tang, Yuyuan ; Tong, Yan ; Mao, Kaili ; Zhang, Zhibin ; Zhou, Xianli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c231z-e6c57ba319daee5693281b7f625602e2ca38e76dcdaa4eac034487c2acbef6893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Coordination polymers</topic><topic>Hydrogen bonds</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Organic Chemistry</topic><topic>Photoluminescence</topic><topic>Polymer Sciences</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Haiyu</creatorcontrib><creatorcontrib>Wang, Cuijuan</creatorcontrib><creatorcontrib>Tang, Yuyuan</creatorcontrib><creatorcontrib>Tong, Yan</creatorcontrib><creatorcontrib>Mao, Kaili</creatorcontrib><creatorcontrib>Zhang, Zhibin</creatorcontrib><creatorcontrib>Zhou, Xianli</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Haiyu</au><au>Wang, Cuijuan</au><au>Tang, Yuyuan</au><au>Tong, Yan</au><au>Mao, Kaili</au><au>Zhang, Zhibin</au><au>Zhou, Xianli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2017</date><risdate>2017</risdate><volume>27</volume><issue>1</issue><spage>80</spage><epage>86</epage><pages>80-86</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A stable three-dimensional coordination complex, {[Cd
1.5
(tta)(H
2
O)
4.5
]·H
2
O}
n
(
1)
(tta = terphenyl—3,4″,5—tricarboxylic acid), was prepared by the solvothermal reaction of Cd(CH
3
COO)
2
·2H
2
O and tta in water, which was characterized by infrared spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction, fluorescence, and thermogravimetric analyses. In the solid state of this compound, the Cd (II) center displayed a distorted trigonal bipyramid coordination sphere consisting of two oxygen atoms from two different carboxyl which were offered by two separate tta ligands and three oxygen atoms from three water molecules. The one-dimensional linear (1D) structure and two-dimensional plane were formed by Cd-O coordination bond while the 3D supramolecular reticular structure was formed by hydrogen-bond interactions. And there are large rectangular holes whose size are 13.30 × 13.31 Å along crystallographic axis
a
. The drug loading content (DLC) of
1
was 0.203 g (Ibu)/g (compound) and the release was desirable.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-016-0446-z</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2017, Vol.27 (1), p.80-86 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_journals_1880796794 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Coordination compounds Coordination polymers Hydrogen bonds Infrared spectroscopy Inorganic Chemistry Ligands Organic Chemistry Photoluminescence Polymer Sciences Single crystals |
| title | Synthesis, Structure, Photoluminescent and Drug Loading and Release Properties of a Novel Cadmium (II) Coordination Polymers Based on Terphenyl–3, 4″, 5–tricarboxylic Acid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T19%3A51%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20Structure,%20Photoluminescent%20and%20Drug%20Loading%20and%20Release%20Properties%20of%20a%20Novel%20Cadmium%20(II)%20Coordination%20Polymers%20Based%20on%20Terphenyl%E2%80%933,%204%E2%80%B3,%205%E2%80%93tricarboxylic%20Acid&rft.jtitle=Journal%20of%20inorganic%20and%20organometallic%20polymers%20and%20materials&rft.au=Dai,%20Haiyu&rft.date=2017&rft.volume=27&rft.issue=1&rft.spage=80&rft.epage=86&rft.pages=80-86&rft.issn=1574-1443&rft.eissn=1574-1451&rft_id=info:doi/10.1007/s10904-016-0446-z&rft_dat=%3Cproquest_cross%3E1880796794%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1880796794&rft_id=info:pmid/&rfr_iscdi=true |