Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates
Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L 1 )(1,3-BDC)(H 2 O) 3 ] ⋅ H 2 O ( 1 ), [Ni(L 1 )(1,3,5-HBTC)(H 2 O) 3 ] ( 2 ), [Ni 3 (L 2 ) 3 (1,3,5-BTC) 2 (H 2 O) 8 ] ⋅12H 2 O ( 3 ) [L 1 = N,N ′ -bis(pyridin-3-yl...
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| Veröffentlicht in: | Journal of chemical sciences (Bangalore, India) India), 2017, Vol.129 (1), p.9-20 |
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| creator | LIN, HONGYAN SUN, JUNJUN LIU∗, GUOCHENG WANG, XIANG CHEN, PANWEN |
| description | Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] ⋅
H
2
O (
1
), [Ni(L
1
)(1,3,5-HBTC)(H
2
O)
3
] (
2
), [Ni
3
(L
2
)
3
(1,3,5-BTC)
2
(H
2
O)
8
] ⋅12H
2
O (
3
) [L
1
= N,N
′
-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L
2
= N,N
′
-bis(3-pyridyl)octandiamide, 1,3-H
2
BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H
3
BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer
1
is a 2D interlaced layer based on the 1D [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] meso-helical chains. Polymer
2
is a 1D wave-shaped chain derived from the 1D [Ni(L
1
)]
n
chain and monodentate coordinated 1,3,5-HBTC anions. Polymer
3
possesses an interesting 2D layer containing the trinuclear [Ni
3
(1,3,5-BTC)
2
] substructural unit and 1D zigzag [Ni(L
2
)]
n
chain, representing a 3,4-connected {6 ⋅8
2
}
2
{6
2
⋅8
2
⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of
1–3
have been investigated.
Graphical Abstract
Three new Ni(II) coordination polymers have been hydrothermally synthesized by self-assembly of two bis-pyridyl-bis-amide ligands (L
1
, L
2
) and two aromatic polycarboxylates (1,3-H
2
BDC, 1,3,5-H
3
BTC). The thermal stability, fluorescent properties and the photocatalytic activities of polymers
1
–
3
have been studied. |
| doi_str_mv | 10.1007/s12039-016-1213-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880795339</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880795339</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-7d592e6fa49e0a4fb9e01cfcbc17df171c82334c4f590eeda6fb2d0ef2802f013</originalsourceid><addsrcrecordid>eNp1UctO3TAUjFCRoMAHsLPEppVq8CM3j2WFKFwJwQJYW459DEZJnB77Avko_hFf0gWbrmaONA8dTVEcc3bKGavPIhdMtpTxinLBJZ13in3W1pLWnMlvn7ykshLVXvE9xmfGZFPWcr94v4PeUR0jDF0__yIx4cakDUIkerRkwjABJp_P4Eh6QgAywiu58T_W65_EhIDWjzr5MJIp9PMAGIkF9C9gicMwkPQaiPXOAcKYSOcjnWb0du7pluvBWyC9f8xlS-NWr7MxZ5rPSKOxC29zrxPEw2LX6T7C0T88KB7-XNyfX9Hr28v1-e9rauSqTbS2q1ZA5XTZAtOl6zJw40xneG0dr7lphJSlKd2qZQBWV64TloETDROOcXlQnCy5-f-_G4hJPYcNjrlS8aZhdbuSss0qvqgMhhgRnJrQDxpnxZnarqKWVVReRW1XUXP2iMUTs3Z8BPyS_F_TBzGSlYo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880795339</pqid></control><display><type>article</type><title>Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates</title><source>SpringerLink Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Alma/SFX Local Collection</source><source>Free Full-Text Journals in Chemistry</source><creator>LIN, HONGYAN ; SUN, JUNJUN ; LIU∗, GUOCHENG ; WANG, XIANG ; CHEN, PANWEN</creator><creatorcontrib>LIN, HONGYAN ; SUN, JUNJUN ; LIU∗, GUOCHENG ; WANG, XIANG ; CHEN, PANWEN</creatorcontrib><description>Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] ⋅
H
2
O (
1
), [Ni(L
1
)(1,3,5-HBTC)(H
2
O)
3
] (
2
), [Ni
3
(L
2
)
3
(1,3,5-BTC)
2
(H
2
O)
8
] ⋅12H
2
O (
3
) [L
1
= N,N
′
-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L
2
= N,N
′
-bis(3-pyridyl)octandiamide, 1,3-H
2
BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H
3
BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer
1
is a 2D interlaced layer based on the 1D [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] meso-helical chains. Polymer
2
is a 1D wave-shaped chain derived from the 1D [Ni(L
1
)]
n
chain and monodentate coordinated 1,3,5-HBTC anions. Polymer
3
possesses an interesting 2D layer containing the trinuclear [Ni
3
(1,3,5-BTC)
2
] substructural unit and 1D zigzag [Ni(L
2
)]
n
chain, representing a 3,4-connected {6 ⋅8
2
}
2
{6
2
⋅8
2
⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of
1–3
have been investigated.
Graphical Abstract
Three new Ni(II) coordination polymers have been hydrothermally synthesized by self-assembly of two bis-pyridyl-bis-amide ligands (L
1
, L
2
) and two aromatic polycarboxylates (1,3-H
2
BDC, 1,3,5-H
3
BTC). The thermal stability, fluorescent properties and the photocatalytic activities of polymers
1
–
3
have been studied.</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-016-1213-y</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination polymers ; Cyclohexane ; Fluorescence ; Hydrogen bonding ; Photocatalysis ; Polymers ; Regular Article ; Self-assembly ; Single crystals ; Thermal stability ; Topology</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2017, Vol.129 (1), p.9-20</ispartof><rights>Indian Academy of Sciences 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-7d592e6fa49e0a4fb9e01cfcbc17df171c82334c4f590eeda6fb2d0ef2802f013</citedby><cites>FETCH-LOGICAL-c359t-7d592e6fa49e0a4fb9e01cfcbc17df171c82334c4f590eeda6fb2d0ef2802f013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12039-016-1213-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12039-016-1213-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>LIN, HONGYAN</creatorcontrib><creatorcontrib>SUN, JUNJUN</creatorcontrib><creatorcontrib>LIU∗, GUOCHENG</creatorcontrib><creatorcontrib>WANG, XIANG</creatorcontrib><creatorcontrib>CHEN, PANWEN</creatorcontrib><title>Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] ⋅
H
2
O (
1
), [Ni(L
1
)(1,3,5-HBTC)(H
2
O)
3
] (
2
), [Ni
3
(L
2
)
3
(1,3,5-BTC)
2
(H
2
O)
8
] ⋅12H
2
O (
3
) [L
1
= N,N
′
-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L
2
= N,N
′
-bis(3-pyridyl)octandiamide, 1,3-H
2
BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H
3
BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer
1
is a 2D interlaced layer based on the 1D [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] meso-helical chains. Polymer
2
is a 1D wave-shaped chain derived from the 1D [Ni(L
1
)]
n
chain and monodentate coordinated 1,3,5-HBTC anions. Polymer
3
possesses an interesting 2D layer containing the trinuclear [Ni
3
(1,3,5-BTC)
2
] substructural unit and 1D zigzag [Ni(L
2
)]
n
chain, representing a 3,4-connected {6 ⋅8
2
}
2
{6
2
⋅8
2
⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of
1–3
have been investigated.
Graphical Abstract
Three new Ni(II) coordination polymers have been hydrothermally synthesized by self-assembly of two bis-pyridyl-bis-amide ligands (L
1
, L
2
) and two aromatic polycarboxylates (1,3-H
2
BDC, 1,3,5-H
3
BTC). The thermal stability, fluorescent properties and the photocatalytic activities of polymers
1
–
3
have been studied.</description><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination polymers</subject><subject>Cyclohexane</subject><subject>Fluorescence</subject><subject>Hydrogen bonding</subject><subject>Photocatalysis</subject><subject>Polymers</subject><subject>Regular Article</subject><subject>Self-assembly</subject><subject>Single crystals</subject><subject>Thermal stability</subject><subject>Topology</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UctO3TAUjFCRoMAHsLPEppVq8CM3j2WFKFwJwQJYW459DEZJnB77Avko_hFf0gWbrmaONA8dTVEcc3bKGavPIhdMtpTxinLBJZ13in3W1pLWnMlvn7ykshLVXvE9xmfGZFPWcr94v4PeUR0jDF0__yIx4cakDUIkerRkwjABJp_P4Eh6QgAywiu58T_W65_EhIDWjzr5MJIp9PMAGIkF9C9gicMwkPQaiPXOAcKYSOcjnWb0du7pluvBWyC9f8xlS-NWr7MxZ5rPSKOxC29zrxPEw2LX6T7C0T88KB7-XNyfX9Hr28v1-e9rauSqTbS2q1ZA5XTZAtOl6zJw40xneG0dr7lphJSlKd2qZQBWV64TloETDROOcXlQnCy5-f-_G4hJPYcNjrlS8aZhdbuSss0qvqgMhhgRnJrQDxpnxZnarqKWVVReRW1XUXP2iMUTs3Z8BPyS_F_TBzGSlYo</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>LIN, HONGYAN</creator><creator>SUN, JUNJUN</creator><creator>LIU∗, GUOCHENG</creator><creator>WANG, XIANG</creator><creator>CHEN, PANWEN</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates</title><author>LIN, HONGYAN ; SUN, JUNJUN ; LIU∗, GUOCHENG ; WANG, XIANG ; CHEN, PANWEN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-7d592e6fa49e0a4fb9e01cfcbc17df171c82334c4f590eeda6fb2d0ef2802f013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination polymers</topic><topic>Cyclohexane</topic><topic>Fluorescence</topic><topic>Hydrogen bonding</topic><topic>Photocatalysis</topic><topic>Polymers</topic><topic>Regular Article</topic><topic>Self-assembly</topic><topic>Single crystals</topic><topic>Thermal stability</topic><topic>Topology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>LIN, HONGYAN</creatorcontrib><creatorcontrib>SUN, JUNJUN</creatorcontrib><creatorcontrib>LIU∗, GUOCHENG</creatorcontrib><creatorcontrib>WANG, XIANG</creatorcontrib><creatorcontrib>CHEN, PANWEN</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>LIN, HONGYAN</au><au>SUN, JUNJUN</au><au>LIU∗, GUOCHENG</au><au>WANG, XIANG</au><au>CHEN, PANWEN</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2017</date><risdate>2017</risdate><volume>129</volume><issue>1</issue><spage>9</spage><epage>20</epage><pages>9-20</pages><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] ⋅
H
2
O (
1
), [Ni(L
1
)(1,3,5-HBTC)(H
2
O)
3
] (
2
), [Ni
3
(L
2
)
3
(1,3,5-BTC)
2
(H
2
O)
8
] ⋅12H
2
O (
3
) [L
1
= N,N
′
-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L
2
= N,N
′
-bis(3-pyridyl)octandiamide, 1,3-H
2
BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H
3
BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer
1
is a 2D interlaced layer based on the 1D [Ni(L
1
)(1,3-BDC)(H
2
O)
3
] meso-helical chains. Polymer
2
is a 1D wave-shaped chain derived from the 1D [Ni(L
1
)]
n
chain and monodentate coordinated 1,3,5-HBTC anions. Polymer
3
possesses an interesting 2D layer containing the trinuclear [Ni
3
(1,3,5-BTC)
2
] substructural unit and 1D zigzag [Ni(L
2
)]
n
chain, representing a 3,4-connected {6 ⋅8
2
}
2
{6
2
⋅8
2
⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of
1–3
have been investigated.
Graphical Abstract
Three new Ni(II) coordination polymers have been hydrothermally synthesized by self-assembly of two bis-pyridyl-bis-amide ligands (L
1
, L
2
) and two aromatic polycarboxylates (1,3-H
2
BDC, 1,3,5-H
3
BTC). The thermal stability, fluorescent properties and the photocatalytic activities of polymers
1
–
3
have been studied.</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-016-1213-y</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0974-3626 |
| ispartof | Journal of chemical sciences (Bangalore, India), 2017, Vol.129 (1), p.9-20 |
| issn | 0974-3626 0973-7103 |
| language | eng |
| recordid | cdi_proquest_journals_1880795339 |
| source | SpringerLink Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Catalytic activity Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination polymers Cyclohexane Fluorescence Hydrogen bonding Photocatalysis Polymers Regular Article Self-assembly Single crystals Thermal stability Topology |
| title | Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates |
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