Oxidative conversion of ethane involving lattice oxygen of molybdenum systems modified with aluminum, gallium, or yttrium oxide
Oxidative conversion of ethane on the molybdenum oxide MoO 3 mixed with 0–95% Al 2 O 3 , Ga 2 O 3 , or Y 2 O 3 has been studied in the pulse mode at 600°C. It has been revealed that the components of these systems undergo strong interaction, which leads to enhanced ethane conversion and an increased...
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| Veröffentlicht in: | Petroleum chemistry 2016-09, Vol.56 (9), p.841-845 |
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| container_title | Petroleum chemistry |
| container_volume | 56 |
| creator | Usachev, N. Ya Gerzeliev, I. M. Kharlamov, V. V. Kalinin, V. P. Belanova, E. P. Kanaev, S. A. Kazakov, A. V. Starostina, T. S. |
| description | Oxidative conversion of ethane on the molybdenum oxide MoO
3
mixed with 0–95% Al
2
O
3
, Ga
2
O
3
, or Y
2
O
3
has been studied in the pulse mode at 600°C. It has been revealed that the components of these systems undergo strong interaction, which leads to enhanced ethane conversion and an increased selectivity for ethylene with a decrease in the MoO
3
content. The 5%MoO
3
–95%Al
2
O
3
system has proved the most effective in the oxidative dehydrogenation of ethane, with the selectivity for ethylene reaching 90% at an ethane conversion of 30 wt %. |
| doi_str_mv | 10.1134/S0965544116090218 |
| format | Article |
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3
mixed with 0–95% Al
2
O
3
, Ga
2
O
3
, or Y
2
O
3
has been studied in the pulse mode at 600°C. It has been revealed that the components of these systems undergo strong interaction, which leads to enhanced ethane conversion and an increased selectivity for ethylene with a decrease in the MoO
3
content. The 5%MoO
3
–95%Al
2
O
3
system has proved the most effective in the oxidative dehydrogenation of ethane, with the selectivity for ethylene reaching 90% at an ethane conversion of 30 wt %.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544116090218</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum oxide ; Chemistry ; Chemistry and Materials Science ; Dehydrogenation ; Ethane ; Ethylene ; Gallium oxides ; Industrial Chemistry/Chemical Engineering ; Molybdenum ; Molybdenum oxides ; Rare earth metals ; Yttrium compounds ; Yttrium oxide</subject><ispartof>Petroleum chemistry, 2016-09, Vol.56 (9), p.841-845</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-86fab81c4be3127bc98de828e46f708c003b1dd2c75df12aa5474b673367fa9e3</citedby><cites>FETCH-LOGICAL-c392t-86fab81c4be3127bc98de828e46f708c003b1dd2c75df12aa5474b673367fa9e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0965544116090218$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0965544116090218$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Usachev, N. Ya</creatorcontrib><creatorcontrib>Gerzeliev, I. M.</creatorcontrib><creatorcontrib>Kharlamov, V. V.</creatorcontrib><creatorcontrib>Kalinin, V. P.</creatorcontrib><creatorcontrib>Belanova, E. P.</creatorcontrib><creatorcontrib>Kanaev, S. A.</creatorcontrib><creatorcontrib>Kazakov, A. V.</creatorcontrib><creatorcontrib>Starostina, T. S.</creatorcontrib><title>Oxidative conversion of ethane involving lattice oxygen of molybdenum systems modified with aluminum, gallium, or yttrium oxide</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>Oxidative conversion of ethane on the molybdenum oxide MoO
3
mixed with 0–95% Al
2
O
3
, Ga
2
O
3
, or Y
2
O
3
has been studied in the pulse mode at 600°C. It has been revealed that the components of these systems undergo strong interaction, which leads to enhanced ethane conversion and an increased selectivity for ethylene with a decrease in the MoO
3
content. The 5%MoO
3
–95%Al
2
O
3
system has proved the most effective in the oxidative dehydrogenation of ethane, with the selectivity for ethylene reaching 90% at an ethane conversion of 30 wt %.</description><subject>Aluminum oxide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dehydrogenation</subject><subject>Ethane</subject><subject>Ethylene</subject><subject>Gallium oxides</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Molybdenum</subject><subject>Molybdenum oxides</subject><subject>Rare earth metals</subject><subject>Yttrium compounds</subject><subject>Yttrium oxide</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kU1r3DAQhkVpods0PyA3Qa91qrEkWz6G0C8I5NDkbGRptFGwpVTSbuNT_3rlbg-FUuYww7zvMxo0hFwAuwTg4sM3NnRSCgHQsYG1oF6QHUgpm67lw0uy2-Rm01-TNzk_MgY9CL4jP2-fvdXFH5GaGI6Yso-BRkexPOiA1IdjnI8-7OmsS_EGaXxe9_jbssR5nSyGw0Lzmgsuubasdx4t_eHLA9XzYfFVfk_3ep79VsRE11JSresgb_EteeX0nPH8Tz4j958-3l1_aW5uP3-9vrppDB_a0qjO6UmBERNyaPvJDMqiahWKzvVMGcb4BNa2ppfWQau1FL2Yup7zrnd6QH5G3p3mPqX4_YC5jI_xkEJ9cgSlWD8I4LK6Lk-uui-OPrhYkjY1LC6-_g86X_tXkvFBSNVtAJwAk2LOCd34lPyi0zoCG7fDjP8cpjLticnVG_aY_lrlv9Av-giR5g</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Usachev, N. Ya</creator><creator>Gerzeliev, I. M.</creator><creator>Kharlamov, V. V.</creator><creator>Kalinin, V. P.</creator><creator>Belanova, E. P.</creator><creator>Kanaev, S. A.</creator><creator>Kazakov, A. V.</creator><creator>Starostina, T. S.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160901</creationdate><title>Oxidative conversion of ethane involving lattice oxygen of molybdenum systems modified with aluminum, gallium, or yttrium oxide</title><author>Usachev, N. Ya ; Gerzeliev, I. M. ; Kharlamov, V. V. ; Kalinin, V. P. ; Belanova, E. P. ; Kanaev, S. A. ; Kazakov, A. V. ; Starostina, T. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-86fab81c4be3127bc98de828e46f708c003b1dd2c75df12aa5474b673367fa9e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aluminum oxide</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dehydrogenation</topic><topic>Ethane</topic><topic>Ethylene</topic><topic>Gallium oxides</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Molybdenum</topic><topic>Molybdenum oxides</topic><topic>Rare earth metals</topic><topic>Yttrium compounds</topic><topic>Yttrium oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Usachev, N. Ya</creatorcontrib><creatorcontrib>Gerzeliev, I. M.</creatorcontrib><creatorcontrib>Kharlamov, V. V.</creatorcontrib><creatorcontrib>Kalinin, V. P.</creatorcontrib><creatorcontrib>Belanova, E. P.</creatorcontrib><creatorcontrib>Kanaev, S. A.</creatorcontrib><creatorcontrib>Kazakov, A. V.</creatorcontrib><creatorcontrib>Starostina, T. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Usachev, N. Ya</au><au>Gerzeliev, I. M.</au><au>Kharlamov, V. V.</au><au>Kalinin, V. P.</au><au>Belanova, E. P.</au><au>Kanaev, S. A.</au><au>Kazakov, A. V.</au><au>Starostina, T. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidative conversion of ethane involving lattice oxygen of molybdenum systems modified with aluminum, gallium, or yttrium oxide</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2016-09-01</date><risdate>2016</risdate><volume>56</volume><issue>9</issue><spage>841</spage><epage>845</epage><pages>841-845</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>Oxidative conversion of ethane on the molybdenum oxide MoO
3
mixed with 0–95% Al
2
O
3
, Ga
2
O
3
, or Y
2
O
3
has been studied in the pulse mode at 600°C. It has been revealed that the components of these systems undergo strong interaction, which leads to enhanced ethane conversion and an increased selectivity for ethylene with a decrease in the MoO
3
content. The 5%MoO
3
–95%Al
2
O
3
system has proved the most effective in the oxidative dehydrogenation of ethane, with the selectivity for ethylene reaching 90% at an ethane conversion of 30 wt %.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0965544116090218</doi><tpages>5</tpages></addata></record> |
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| ispartof | Petroleum chemistry, 2016-09, Vol.56 (9), p.841-845 |
| issn | 0965-5441 1555-6239 |
| language | eng |
| recordid | cdi_proquest_journals_1880794135 |
| source | Business Source Complete; Springer Nature - Complete Springer Journals |
| subjects | Aluminum oxide Chemistry Chemistry and Materials Science Dehydrogenation Ethane Ethylene Gallium oxides Industrial Chemistry/Chemical Engineering Molybdenum Molybdenum oxides Rare earth metals Yttrium compounds Yttrium oxide |
| title | Oxidative conversion of ethane involving lattice oxygen of molybdenum systems modified with aluminum, gallium, or yttrium oxide |
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