Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries
A porous, hollow, microspherical composite of Li 2 MnO 3 and LiMn 1/3 Co 1/3 Ni 1/3 O 2 (composition: Li 1.2 Mn 0.53 Ni 0.13 Co 0.13 O 2 ) was prepared using hollow MnO 2 as the sacrificial template. The resulting composite was found to be mesoporous; its pores were about 20 nm in diameter. It also...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2017-02, Vol.21 (2), p.437-445 |
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| container_title | Journal of solid state electrochemistry |
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| creator | Duraisamy, Shanmughasundaram Penki, Tirupathi Rao Kishore, Brij Barpanda, Prabeer Nayak, Prasant Kumar Aurbach, Doron Munichandraiah, Nookala |
| description | A porous, hollow, microspherical composite of Li
2
MnO
3
and LiMn
1/3
Co
1/3
Ni
1/3
O
2
(composition: Li
1.2
Mn
0.53
Ni
0.13
Co
0.13
O
2
) was prepared using hollow MnO
2
as the sacrificial template. The resulting composite was found to be mesoporous; its pores were about 20 nm in diameter. It also delivered a reversible discharge capacity value of 220 mAh g
−1
at a specific current of 25 mA g
−1
with excellent cycling stability and a high rate capability. A discharge capacity of 100 mAh g
−1
was obtained for this composite at a specific current of 1000 mA g
−1
. The high rate capability of this hollow microspherical composite can be attributed to its porous nature.
Graphical Abstract
ᅟ |
| doi_str_mv | 10.1007/s10008-016-3380-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880785198</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880785198</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-c8c7ea2f8356794febf9ffa17f505d2f3087b941e027ce9da272e678c87f7a5d3</originalsourceid><addsrcrecordid>eNp1UMtOwzAQjBBIQOEDuFniisvaTmLniCpeUqEc4Gy5yZq6pHWwUxB_j0M4cEFaza5WM7PaybIzBlMGIC9jQlAUWEmFUEDlXnbEciEoyFLt_8ycqlypw-w4xjUAkyWDo-ztyQe_ixdk5dvWf5K5Y1P-sIVpIR5d8hYzP-CCk42rg4_dCgNGYlKRzkfXuw8k2GLdB98g2ZgegzMtsT4kL-r8lixNPywxnmQH1rQRT3_7JHu5uX6e3dH54vZ-djWntShET2tVSzTcKlGUssotLm1lrWHSFlA03ApQclnlDIHLGqvGcMmxlKpW0kpTNGKSnY--XfDvO4y9Xvtd2KaTmikFUhWsUonFRtbwVgxodRfcxoQvzUAPmeoxU50y1UOmWiYNHzUxcbevGP44_yv6Bv2Ud8g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880785198</pqid></control><display><type>article</type><title>Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries</title><source>SpringerLink Journals - AutoHoldings</source><creator>Duraisamy, Shanmughasundaram ; Penki, Tirupathi Rao ; Kishore, Brij ; Barpanda, Prabeer ; Nayak, Prasant Kumar ; Aurbach, Doron ; Munichandraiah, Nookala</creator><creatorcontrib>Duraisamy, Shanmughasundaram ; Penki, Tirupathi Rao ; Kishore, Brij ; Barpanda, Prabeer ; Nayak, Prasant Kumar ; Aurbach, Doron ; Munichandraiah, Nookala</creatorcontrib><description>A porous, hollow, microspherical composite of Li
2
MnO
3
and LiMn
1/3
Co
1/3
Ni
1/3
O
2
(composition: Li
1.2
Mn
0.53
Ni
0.13
Co
0.13
O
2
) was prepared using hollow MnO
2
as the sacrificial template. The resulting composite was found to be mesoporous; its pores were about 20 nm in diameter. It also delivered a reversible discharge capacity value of 220 mAh g
−1
at a specific current of 25 mA g
−1
with excellent cycling stability and a high rate capability. A discharge capacity of 100 mAh g
−1
was obtained for this composite at a specific current of 1000 mA g
−1
. The high rate capability of this hollow microspherical composite can be attributed to its porous nature.
Graphical Abstract
ᅟ</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-016-3380-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Discharge ; Electrochemistry ; Electrode materials ; Energy Storage ; Lithium-ion batteries ; Manganese dioxide ; Microspheres ; Original Paper ; Physical Chemistry ; Porous materials</subject><ispartof>Journal of solid state electrochemistry, 2017-02, Vol.21 (2), p.437-445</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-c8c7ea2f8356794febf9ffa17f505d2f3087b941e027ce9da272e678c87f7a5d3</citedby><cites>FETCH-LOGICAL-c353t-c8c7ea2f8356794febf9ffa17f505d2f3087b941e027ce9da272e678c87f7a5d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10008-016-3380-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10008-016-3380-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Duraisamy, Shanmughasundaram</creatorcontrib><creatorcontrib>Penki, Tirupathi Rao</creatorcontrib><creatorcontrib>Kishore, Brij</creatorcontrib><creatorcontrib>Barpanda, Prabeer</creatorcontrib><creatorcontrib>Nayak, Prasant Kumar</creatorcontrib><creatorcontrib>Aurbach, Doron</creatorcontrib><creatorcontrib>Munichandraiah, Nookala</creatorcontrib><title>Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>A porous, hollow, microspherical composite of Li
2
MnO
3
and LiMn
1/3
Co
1/3
Ni
1/3
O
2
(composition: Li
1.2
Mn
0.53
Ni
0.13
Co
0.13
O
2
) was prepared using hollow MnO
2
as the sacrificial template. The resulting composite was found to be mesoporous; its pores were about 20 nm in diameter. It also delivered a reversible discharge capacity value of 220 mAh g
−1
at a specific current of 25 mA g
−1
with excellent cycling stability and a high rate capability. A discharge capacity of 100 mAh g
−1
was obtained for this composite at a specific current of 1000 mA g
−1
. The high rate capability of this hollow microspherical composite can be attributed to its porous nature.
Graphical Abstract
ᅟ</description><subject>Analytical Chemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Discharge</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Energy Storage</subject><subject>Lithium-ion batteries</subject><subject>Manganese dioxide</subject><subject>Microspheres</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Porous materials</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UMtOwzAQjBBIQOEDuFniisvaTmLniCpeUqEc4Gy5yZq6pHWwUxB_j0M4cEFaza5WM7PaybIzBlMGIC9jQlAUWEmFUEDlXnbEciEoyFLt_8ycqlypw-w4xjUAkyWDo-ztyQe_ixdk5dvWf5K5Y1P-sIVpIR5d8hYzP-CCk42rg4_dCgNGYlKRzkfXuw8k2GLdB98g2ZgegzMtsT4kL-r8lixNPywxnmQH1rQRT3_7JHu5uX6e3dH54vZ-djWntShET2tVSzTcKlGUssotLm1lrWHSFlA03ApQclnlDIHLGqvGcMmxlKpW0kpTNGKSnY--XfDvO4y9Xvtd2KaTmikFUhWsUonFRtbwVgxodRfcxoQvzUAPmeoxU50y1UOmWiYNHzUxcbevGP44_yv6Bv2Ud8g</recordid><startdate>20170201</startdate><enddate>20170201</enddate><creator>Duraisamy, Shanmughasundaram</creator><creator>Penki, Tirupathi Rao</creator><creator>Kishore, Brij</creator><creator>Barpanda, Prabeer</creator><creator>Nayak, Prasant Kumar</creator><creator>Aurbach, Doron</creator><creator>Munichandraiah, Nookala</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170201</creationdate><title>Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries</title><author>Duraisamy, Shanmughasundaram ; Penki, Tirupathi Rao ; Kishore, Brij ; Barpanda, Prabeer ; Nayak, Prasant Kumar ; Aurbach, Doron ; Munichandraiah, Nookala</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-c8c7ea2f8356794febf9ffa17f505d2f3087b941e027ce9da272e678c87f7a5d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analytical Chemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Discharge</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Energy Storage</topic><topic>Lithium-ion batteries</topic><topic>Manganese dioxide</topic><topic>Microspheres</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Porous materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Duraisamy, Shanmughasundaram</creatorcontrib><creatorcontrib>Penki, Tirupathi Rao</creatorcontrib><creatorcontrib>Kishore, Brij</creatorcontrib><creatorcontrib>Barpanda, Prabeer</creatorcontrib><creatorcontrib>Nayak, Prasant Kumar</creatorcontrib><creatorcontrib>Aurbach, Doron</creatorcontrib><creatorcontrib>Munichandraiah, Nookala</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Duraisamy, Shanmughasundaram</au><au>Penki, Tirupathi Rao</au><au>Kishore, Brij</au><au>Barpanda, Prabeer</au><au>Nayak, Prasant Kumar</au><au>Aurbach, Doron</au><au>Munichandraiah, Nookala</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2017-02-01</date><risdate>2017</risdate><volume>21</volume><issue>2</issue><spage>437</spage><epage>445</epage><pages>437-445</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>A porous, hollow, microspherical composite of Li
2
MnO
3
and LiMn
1/3
Co
1/3
Ni
1/3
O
2
(composition: Li
1.2
Mn
0.53
Ni
0.13
Co
0.13
O
2
) was prepared using hollow MnO
2
as the sacrificial template. The resulting composite was found to be mesoporous; its pores were about 20 nm in diameter. It also delivered a reversible discharge capacity value of 220 mAh g
−1
at a specific current of 25 mA g
−1
with excellent cycling stability and a high rate capability. A discharge capacity of 100 mAh g
−1
was obtained for this composite at a specific current of 1000 mA g
−1
. The high rate capability of this hollow microspherical composite can be attributed to its porous nature.
Graphical Abstract
ᅟ</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-016-3380-7</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of solid state electrochemistry, 2017-02, Vol.21 (2), p.437-445 |
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| language | eng |
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| subjects | Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Discharge Electrochemistry Electrode materials Energy Storage Lithium-ion batteries Manganese dioxide Microspheres Original Paper Physical Chemistry Porous materials |
| title | Porous, hollow Li1.2Mn0.53Ni0.13Co0.13O2 microspheres as a positive electrode material for Li-ion batteries |
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