Thermochemical study of the reactions of acid–base interaction in an aqueous solution of α-aminobutyric acid
The heat effects of the interaction between a solution of α-aminobutyric acid and solutions of HNO 3 and KОН are measured by means of calorimetry in different ranges of рН at 298.15 K and values of ionic strength of 0.25, 0.5, and 0.75 (KNO 3 ). The heat effects of the stepwise dissociation of the a...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2017, Vol.91 (1), p.1-5 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 91 |
| creator | Lytkin, A. I. Chernikov, V. V. Krutova, O. N. Skvortsov, I. A. Korchagina, A. S. |
| description | The heat effects of the interaction between a solution of α-aminobutyric acid and solutions of HNO
3
and KОН are measured by means of calorimetry in different ranges of рН at 298.15 K and values of ionic strength of 0.25, 0.5, and 0.75 (KNO
3
). The heat effects of the stepwise dissociation of the amino acid are determined. Standard thermodynamic characteristics (Δ
r
H
0
, Δ
r
G
0
, and Δ
r
S
0
) of the reactions of acid–base interaction in aqueous solutions of α-aminobutyric acid are calculated. The connection between the thermodynamic characteristics of the dissociation of the amino acid and the structure of this compound is considered. |
| doi_str_mv | 10.1134/S0036024417010174 |
| format | Article |
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3
and KОН are measured by means of calorimetry in different ranges of рН at 298.15 K and values of ionic strength of 0.25, 0.5, and 0.75 (KNO
3
). The heat effects of the stepwise dissociation of the amino acid are determined. Standard thermodynamic characteristics (Δ
r
H
0
, Δ
r
G
0
, and Δ
r
S
0
) of the reactions of acid–base interaction in aqueous solutions of α-aminobutyric acid are calculated. The connection between the thermodynamic characteristics of the dissociation of the amino acid and the structure of this compound is considered.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024417010174</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amino acids ; Aqueous solutions ; Chemical Thermodynamics and Thermochemistry ; Chemistry ; Chemistry and Materials Science ; High temperature effects ; Physical Chemistry ; Thermodynamics</subject><ispartof>Russian Journal of Physical Chemistry A, 2017, Vol.91 (1), p.1-5</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-36b0b1e3b25334932bd6d8c6e51c4ef460a0fb75adac5a4564d4df0549ba760d3</citedby><cites>FETCH-LOGICAL-c316t-36b0b1e3b25334932bd6d8c6e51c4ef460a0fb75adac5a4564d4df0549ba760d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024417010174$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024417010174$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernikov, V. V.</creatorcontrib><creatorcontrib>Krutova, O. N.</creatorcontrib><creatorcontrib>Skvortsov, I. A.</creatorcontrib><creatorcontrib>Korchagina, A. S.</creatorcontrib><title>Thermochemical study of the reactions of acid–base interaction in an aqueous solution of α-aminobutyric acid</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The heat effects of the interaction between a solution of α-aminobutyric acid and solutions of HNO
3
and KОН are measured by means of calorimetry in different ranges of рН at 298.15 K and values of ionic strength of 0.25, 0.5, and 0.75 (KNO
3
). The heat effects of the stepwise dissociation of the amino acid are determined. Standard thermodynamic characteristics (Δ
r
H
0
, Δ
r
G
0
, and Δ
r
S
0
) of the reactions of acid–base interaction in aqueous solutions of α-aminobutyric acid are calculated. The connection between the thermodynamic characteristics of the dissociation of the amino acid and the structure of this compound is considered.</description><subject>Amino acids</subject><subject>Aqueous solutions</subject><subject>Chemical Thermodynamics and Thermochemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>High temperature effects</subject><subject>Physical Chemistry</subject><subject>Thermodynamics</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UM1Kw0AQXkTBWn0AbwHP0ZnsZpMepfgHBQ8qeAv7F7ulydbd5NCb7-CT-CI-hE_ipvEgiDAww_c3wxByinCOSNnFAwDlkDGGBSBgwfbIBHOKacnp8z6ZDHQ68IfkKIQVAItSNiHucWl849TSNFaJdRK6Xm8TVyfd0iTeCNVZ14YBEMrqr7d3KYJJbNsZP3JxTkSs1964PiTBrfsdHB2fH6lobOtk3229VbuEY3JQi3UwJz99Sp6urx7nt-ni_uZufrlIFUXepZRLkGiozHJK2YxmUnNdKm5yVMzUjIOAWha50ELlguWcaaZryNlMioKDplNyNuZuvIunha5aud63cWWFZQlFwVmJUYWjSnkXgjd1tfG2EX5bIVTDX6s_f42ebPSEqG1fjP-V_K_pGxDQfME</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Lytkin, A. I.</creator><creator>Chernikov, V. V.</creator><creator>Krutova, O. N.</creator><creator>Skvortsov, I. A.</creator><creator>Korchagina, A. S.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Thermochemical study of the reactions of acid–base interaction in an aqueous solution of α-aminobutyric acid</title><author>Lytkin, A. I. ; Chernikov, V. V. ; Krutova, O. N. ; Skvortsov, I. A. ; Korchagina, A. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-36b0b1e3b25334932bd6d8c6e51c4ef460a0fb75adac5a4564d4df0549ba760d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Amino acids</topic><topic>Aqueous solutions</topic><topic>Chemical Thermodynamics and Thermochemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>High temperature effects</topic><topic>Physical Chemistry</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lytkin, A. I.</creatorcontrib><creatorcontrib>Chernikov, V. V.</creatorcontrib><creatorcontrib>Krutova, O. N.</creatorcontrib><creatorcontrib>Skvortsov, I. A.</creatorcontrib><creatorcontrib>Korchagina, A. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lytkin, A. I.</au><au>Chernikov, V. V.</au><au>Krutova, O. N.</au><au>Skvortsov, I. A.</au><au>Korchagina, A. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermochemical study of the reactions of acid–base interaction in an aqueous solution of α-aminobutyric acid</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2017</date><risdate>2017</risdate><volume>91</volume><issue>1</issue><spage>1</spage><epage>5</epage><pages>1-5</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The heat effects of the interaction between a solution of α-aminobutyric acid and solutions of HNO
3
and KОН are measured by means of calorimetry in different ranges of рН at 298.15 K and values of ionic strength of 0.25, 0.5, and 0.75 (KNO
3
). The heat effects of the stepwise dissociation of the amino acid are determined. Standard thermodynamic characteristics (Δ
r
H
0
, Δ
r
G
0
, and Δ
r
S
0
) of the reactions of acid–base interaction in aqueous solutions of α-aminobutyric acid are calculated. The connection between the thermodynamic characteristics of the dissociation of the amino acid and the structure of this compound is considered.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024417010174</doi><tpages>5</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Amino acids Aqueous solutions Chemical Thermodynamics and Thermochemistry Chemistry Chemistry and Materials Science High temperature effects Physical Chemistry Thermodynamics |
| title | Thermochemical study of the reactions of acid–base interaction in an aqueous solution of α-aminobutyric acid |
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