Statistical design analysis of isophorone electrocatalytic hydrogenation: the use of cyclodextrins as inverse phase transfer catalysts
Fundamentals and applications of a 2 3 factorial design were performed for assessing the influence of the cyclodextrin (CyD) type, concentration and encapsulation time on the electrocatalytic hydrogenation (ECH) of isophorone. Electrolysis were carried out using nickel as electrocatalyst and sacrifi...
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| Veröffentlicht in: | Journal of inclusion phenomena and macrocyclic chemistry 2017-02, Vol.87 (1-2), p.13-20 |
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| container_title | Journal of inclusion phenomena and macrocyclic chemistry |
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| creator | de Medeiros, Anderson Oliveira da Paz, Josinete Angela Sales, Ayrlane Navarro, Marcelo de Menezes, Frederico Duarte Vilar, Márcio |
| description | Fundamentals and applications of a 2
3
factorial design were performed for assessing the influence of the cyclodextrin (CyD) type, concentration and encapsulation time on the electrocatalytic hydrogenation (ECH) of isophorone. Electrolysis were carried out using nickel as electrocatalyst and sacrificial anode. A discussion of model validation is presented. The analysis of the results showed that the most significant factors to the conversion rate were the CyD type and concentration, with 3 mmol dm
−3
of βCyD giving the best results. The isophorone C=C hydrogenation yield, in the presence of βCyD, was 28 % higher than in its absence, and it is comparable to those obtained by other well-established ECH procedures in terms of hydrogenation yield, selectivity and current efficiency. |
| doi_str_mv | 10.1007/s10847-016-0672-6 |
| format | Article |
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3
factorial design were performed for assessing the influence of the cyclodextrin (CyD) type, concentration and encapsulation time on the electrocatalytic hydrogenation (ECH) of isophorone. Electrolysis were carried out using nickel as electrocatalyst and sacrificial anode. A discussion of model validation is presented. The analysis of the results showed that the most significant factors to the conversion rate were the CyD type and concentration, with 3 mmol dm
−3
of βCyD giving the best results. The isophorone C=C hydrogenation yield, in the presence of βCyD, was 28 % higher than in its absence, and it is comparable to those obtained by other well-established ECH procedures in terms of hydrogenation yield, selectivity and current efficiency.</description><identifier>ISSN: 1388-3127</identifier><identifier>EISSN: 1573-1111</identifier><identifier>DOI: 10.1007/s10847-016-0672-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Chemistry ; Chemistry and Materials Science ; Crystallography and Scattering Methods ; Current efficiency ; Cyclodextrins ; Design analysis ; Electrocatalysts ; Electrolysis ; Factorial design ; Food Science ; Hydrogenation ; Organic Chemistry ; Original Article ; Phase transfer catalysts ; Sacrificial anodes</subject><ispartof>Journal of inclusion phenomena and macrocyclic chemistry, 2017-02, Vol.87 (1-2), p.13-20</ispartof><rights>Springer Science+Business Media Dordrecht 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-219a6281b7f82c8328bdb4208eb31af05a6e7e1fe5bceb93e536e043ca085e463</citedby><cites>FETCH-LOGICAL-c353t-219a6281b7f82c8328bdb4208eb31af05a6e7e1fe5bceb93e536e043ca085e463</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10847-016-0672-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10847-016-0672-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>de Medeiros, Anderson Oliveira</creatorcontrib><creatorcontrib>da Paz, Josinete Angela</creatorcontrib><creatorcontrib>Sales, Ayrlane</creatorcontrib><creatorcontrib>Navarro, Marcelo</creatorcontrib><creatorcontrib>de Menezes, Frederico Duarte</creatorcontrib><creatorcontrib>Vilar, Márcio</creatorcontrib><title>Statistical design analysis of isophorone electrocatalytic hydrogenation: the use of cyclodextrins as inverse phase transfer catalysts</title><title>Journal of inclusion phenomena and macrocyclic chemistry</title><addtitle>J Incl Phenom Macrocycl Chem</addtitle><description>Fundamentals and applications of a 2
3
factorial design were performed for assessing the influence of the cyclodextrin (CyD) type, concentration and encapsulation time on the electrocatalytic hydrogenation (ECH) of isophorone. Electrolysis were carried out using nickel as electrocatalyst and sacrificial anode. A discussion of model validation is presented. The analysis of the results showed that the most significant factors to the conversion rate were the CyD type and concentration, with 3 mmol dm
−3
of βCyD giving the best results. The isophorone C=C hydrogenation yield, in the presence of βCyD, was 28 % higher than in its absence, and it is comparable to those obtained by other well-established ECH procedures in terms of hydrogenation yield, selectivity and current efficiency.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystallography and Scattering Methods</subject><subject>Current efficiency</subject><subject>Cyclodextrins</subject><subject>Design analysis</subject><subject>Electrocatalysts</subject><subject>Electrolysis</subject><subject>Factorial design</subject><subject>Food Science</subject><subject>Hydrogenation</subject><subject>Organic Chemistry</subject><subject>Original Article</subject><subject>Phase transfer catalysts</subject><subject>Sacrificial anodes</subject><issn>1388-3127</issn><issn>1573-1111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhosouK7-AG8Bz9V8tE3Wmyx-geBBPYc0nW671KRmsmL_gL_bLPXgxTnMDMz7PjBvlp0zeskolVfIqCpkTlmV00ryvDrIFqyUImepDtMulMoF4_I4O0HcUsorXohF9v0STewx9tYMpAHsN44YZ4YJeyS-JT36sfPBOyAwgI3BWxPTORlINzXBb8AlgHfXJHZAdgh7l53s4Bv4iqF3SAyS3n1CSLexM6nHYBy2EMjMwoin2VFrBoSz37nM3u5uX9cP-dPz_eP65im3ohQx52xlKq5YLVvFrRJc1U1dcKqgFsy0tDQVSGAtlLWFeiWgFBXQQlhDVQlFJZbZxcwdg__YAUa99buQ_kXNlKJSCi5EUrFZZYNHDNDqMfTvJkyaUb2PW89x6xS33set92Q-ezBp3QbCH_K_ph-9JYZ_</recordid><startdate>20170201</startdate><enddate>20170201</enddate><creator>de Medeiros, Anderson Oliveira</creator><creator>da Paz, Josinete Angela</creator><creator>Sales, Ayrlane</creator><creator>Navarro, Marcelo</creator><creator>de Menezes, Frederico Duarte</creator><creator>Vilar, Márcio</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170201</creationdate><title>Statistical design analysis of isophorone electrocatalytic hydrogenation: the use of cyclodextrins as inverse phase transfer catalysts</title><author>de Medeiros, Anderson Oliveira ; da Paz, Josinete Angela ; Sales, Ayrlane ; Navarro, Marcelo ; de Menezes, Frederico Duarte ; Vilar, Márcio</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-219a6281b7f82c8328bdb4208eb31af05a6e7e1fe5bceb93e536e043ca085e463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystallography and Scattering Methods</topic><topic>Current efficiency</topic><topic>Cyclodextrins</topic><topic>Design analysis</topic><topic>Electrocatalysts</topic><topic>Electrolysis</topic><topic>Factorial design</topic><topic>Food Science</topic><topic>Hydrogenation</topic><topic>Organic Chemistry</topic><topic>Original Article</topic><topic>Phase transfer catalysts</topic><topic>Sacrificial anodes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Medeiros, Anderson Oliveira</creatorcontrib><creatorcontrib>da Paz, Josinete Angela</creatorcontrib><creatorcontrib>Sales, Ayrlane</creatorcontrib><creatorcontrib>Navarro, Marcelo</creatorcontrib><creatorcontrib>de Menezes, Frederico Duarte</creatorcontrib><creatorcontrib>Vilar, Márcio</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inclusion phenomena and macrocyclic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Medeiros, Anderson Oliveira</au><au>da Paz, Josinete Angela</au><au>Sales, Ayrlane</au><au>Navarro, Marcelo</au><au>de Menezes, Frederico Duarte</au><au>Vilar, Márcio</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Statistical design analysis of isophorone electrocatalytic hydrogenation: the use of cyclodextrins as inverse phase transfer catalysts</atitle><jtitle>Journal of inclusion phenomena and macrocyclic chemistry</jtitle><stitle>J Incl Phenom Macrocycl Chem</stitle><date>2017-02-01</date><risdate>2017</risdate><volume>87</volume><issue>1-2</issue><spage>13</spage><epage>20</epage><pages>13-20</pages><issn>1388-3127</issn><eissn>1573-1111</eissn><abstract>Fundamentals and applications of a 2
3
factorial design were performed for assessing the influence of the cyclodextrin (CyD) type, concentration and encapsulation time on the electrocatalytic hydrogenation (ECH) of isophorone. Electrolysis were carried out using nickel as electrocatalyst and sacrificial anode. A discussion of model validation is presented. The analysis of the results showed that the most significant factors to the conversion rate were the CyD type and concentration, with 3 mmol dm
−3
of βCyD giving the best results. The isophorone C=C hydrogenation yield, in the presence of βCyD, was 28 % higher than in its absence, and it is comparable to those obtained by other well-established ECH procedures in terms of hydrogenation yield, selectivity and current efficiency.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10847-016-0672-6</doi><tpages>8</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Crystallography and Scattering Methods Current efficiency Cyclodextrins Design analysis Electrocatalysts Electrolysis Factorial design Food Science Hydrogenation Organic Chemistry Original Article Phase transfer catalysts Sacrificial anodes |
| title | Statistical design analysis of isophorone electrocatalytic hydrogenation: the use of cyclodextrins as inverse phase transfer catalysts |
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