Structural and thermoanalytical features of novel morpholinium-based high-voltage ionic liquid
Ionic liquid N-methyl-N-(2-(2-methoxyethoxy)-ethyl)-morpholinium bis-(trifluoromethylsulfonyl) imide was synthesized for the first time by nucleophilic substitution of bromide ion by N-methyl-morpholine. The composition was confirmed by 1 H and 13 C nuclear magnetic resonance (NMR) spectroscopy. Usi...
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| Veröffentlicht in: | Structural chemistry 2017-04, Vol.28 (2), p.279-287 |
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| container_title | Structural chemistry |
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| creator | Lunin, Valery V. Artemova, Anastasiia O. Savilov, Serguei V. Ivanov, Anthon S. Desyatov, Andrey V. Shen, ZeXiang |
| description | Ionic liquid N-methyl-N-(2-(2-methoxyethoxy)-ethyl)-morpholinium bis-(trifluoromethylsulfonyl) imide was synthesized for the first time by nucleophilic substitution of bromide ion by N-methyl-morpholine. The composition was confirmed by
1
H and
13
C nuclear magnetic resonance (NMR) spectroscopy. Using thermal analysis and mass spectroscopy, thermal stability of this ionic liquid as well as possible directions of its destruction was analyzed. Melting point for this liquid using differential scanning calorimetry (DSC) was estimated in the range (−80 to −74) °C. The dependence of electroconductivity of acetonitrile solution on concentration and temperature was studied for dissociation constant and conductivity activation energy calculations, respectively. The electrochemical stability window for this ionic liquid was defined by cyclic voltammetry and estimated as 4.84 V. |
| doi_str_mv | 10.1007/s11224-016-0768-z |
| format | Article |
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1
H and
13
C nuclear magnetic resonance (NMR) spectroscopy. Using thermal analysis and mass spectroscopy, thermal stability of this ionic liquid as well as possible directions of its destruction was analyzed. Melting point for this liquid using differential scanning calorimetry (DSC) was estimated in the range (−80 to −74) °C. The dependence of electroconductivity of acetonitrile solution on concentration and temperature was studied for dissociation constant and conductivity activation energy calculations, respectively. The electrochemical stability window for this ionic liquid was defined by cyclic voltammetry and estimated as 4.84 V.</description><identifier>ISSN: 1040-0400</identifier><identifier>EISSN: 1572-9001</identifier><identifier>DOI: 10.1007/s11224-016-0768-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acetonitrile ; Chemistry ; Chemistry and Materials Science ; Computer Applications in Chemistry ; Ionic liquids ; Ions ; Melting points ; Morpholine ; NMR ; NMR spectroscopy ; Nuclear magnetic resonance ; Original Research ; Physical Chemistry ; Spectrum analysis ; Stability analysis ; Theoretical and Computational Chemistry ; Thermal analysis ; Thermal stability</subject><ispartof>Structural chemistry, 2017-04, Vol.28 (2), p.279-287</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d9a44206d1346ceacf1695f0388591ec15764f461c4b6e8b6f7ae3f37e492e783</citedby><cites>FETCH-LOGICAL-c316t-d9a44206d1346ceacf1695f0388591ec15764f461c4b6e8b6f7ae3f37e492e783</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11224-016-0768-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11224-016-0768-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lunin, Valery V.</creatorcontrib><creatorcontrib>Artemova, Anastasiia O.</creatorcontrib><creatorcontrib>Savilov, Serguei V.</creatorcontrib><creatorcontrib>Ivanov, Anthon S.</creatorcontrib><creatorcontrib>Desyatov, Andrey V.</creatorcontrib><creatorcontrib>Shen, ZeXiang</creatorcontrib><title>Structural and thermoanalytical features of novel morpholinium-based high-voltage ionic liquid</title><title>Structural chemistry</title><addtitle>Struct Chem</addtitle><description>Ionic liquid N-methyl-N-(2-(2-methoxyethoxy)-ethyl)-morpholinium bis-(trifluoromethylsulfonyl) imide was synthesized for the first time by nucleophilic substitution of bromide ion by N-methyl-morpholine. The composition was confirmed by
1
H and
13
C nuclear magnetic resonance (NMR) spectroscopy. Using thermal analysis and mass spectroscopy, thermal stability of this ionic liquid as well as possible directions of its destruction was analyzed. Melting point for this liquid using differential scanning calorimetry (DSC) was estimated in the range (−80 to −74) °C. The dependence of electroconductivity of acetonitrile solution on concentration and temperature was studied for dissociation constant and conductivity activation energy calculations, respectively. The electrochemical stability window for this ionic liquid was defined by cyclic voltammetry and estimated as 4.84 V.</description><subject>Acetonitrile</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Computer Applications in Chemistry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Melting points</subject><subject>Morpholine</subject><subject>NMR</subject><subject>NMR spectroscopy</subject><subject>Nuclear magnetic resonance</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Spectrum analysis</subject><subject>Stability analysis</subject><subject>Theoretical and Computational Chemistry</subject><subject>Thermal analysis</subject><subject>Thermal stability</subject><issn>1040-0400</issn><issn>1572-9001</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UMtOwzAQtBBIlMIHcIvE2eCNHTs5ooqXVIkDcMVyHbtxlcStnVRqvx5X4cCFw2pXszMjzSB0C-QeCBEPESDPGSbAMRG8xMczNINC5LgiBM7TTRjBacgluopxk0DgtJih748hjHoYg2oz1dfZ0JjQedWr9jA4nUBrVPqamHmb9X5v2qzzYdv41vVu7PBKRVNnjVs3eO_bQa1N5nzvdNa63ejqa3RhVRvNze-eo6_np8_FK16-v7wtHpdYU-ADrivFWE54DZRxbZS2wKvCElqWRQVGpyScWcZBsxU35YpboQy1VBhW5UaUdI7uJt9t8LvRxEFu_BhSiiihLIkQlOQssWBi6eBjDMbKbXCdCgcJRJ5qlFONMtUoTzXKY9LkkyYmbr824Y_zv6Ifw3B3Bw</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Lunin, Valery V.</creator><creator>Artemova, Anastasiia O.</creator><creator>Savilov, Serguei V.</creator><creator>Ivanov, Anthon S.</creator><creator>Desyatov, Andrey V.</creator><creator>Shen, ZeXiang</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170401</creationdate><title>Structural and thermoanalytical features of novel morpholinium-based high-voltage ionic liquid</title><author>Lunin, Valery V. ; Artemova, Anastasiia O. ; Savilov, Serguei V. ; Ivanov, Anthon S. ; Desyatov, Andrey V. ; Shen, ZeXiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d9a44206d1346ceacf1695f0388591ec15764f461c4b6e8b6f7ae3f37e492e783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acetonitrile</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Computer Applications in Chemistry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Melting points</topic><topic>Morpholine</topic><topic>NMR</topic><topic>NMR spectroscopy</topic><topic>Nuclear magnetic resonance</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Spectrum analysis</topic><topic>Stability analysis</topic><topic>Theoretical and Computational Chemistry</topic><topic>Thermal analysis</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lunin, Valery V.</creatorcontrib><creatorcontrib>Artemova, Anastasiia O.</creatorcontrib><creatorcontrib>Savilov, Serguei V.</creatorcontrib><creatorcontrib>Ivanov, Anthon S.</creatorcontrib><creatorcontrib>Desyatov, Andrey V.</creatorcontrib><creatorcontrib>Shen, ZeXiang</creatorcontrib><collection>CrossRef</collection><jtitle>Structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lunin, Valery V.</au><au>Artemova, Anastasiia O.</au><au>Savilov, Serguei V.</au><au>Ivanov, Anthon S.</au><au>Desyatov, Andrey V.</au><au>Shen, ZeXiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural and thermoanalytical features of novel morpholinium-based high-voltage ionic liquid</atitle><jtitle>Structural chemistry</jtitle><stitle>Struct Chem</stitle><date>2017-04-01</date><risdate>2017</risdate><volume>28</volume><issue>2</issue><spage>279</spage><epage>287</epage><pages>279-287</pages><issn>1040-0400</issn><eissn>1572-9001</eissn><abstract>Ionic liquid N-methyl-N-(2-(2-methoxyethoxy)-ethyl)-morpholinium bis-(trifluoromethylsulfonyl) imide was synthesized for the first time by nucleophilic substitution of bromide ion by N-methyl-morpholine. The composition was confirmed by
1
H and
13
C nuclear magnetic resonance (NMR) spectroscopy. Using thermal analysis and mass spectroscopy, thermal stability of this ionic liquid as well as possible directions of its destruction was analyzed. Melting point for this liquid using differential scanning calorimetry (DSC) was estimated in the range (−80 to −74) °C. The dependence of electroconductivity of acetonitrile solution on concentration and temperature was studied for dissociation constant and conductivity activation energy calculations, respectively. The electrochemical stability window for this ionic liquid was defined by cyclic voltammetry and estimated as 4.84 V.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11224-016-0768-z</doi><tpages>9</tpages></addata></record> |
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| subjects | Acetonitrile Chemistry Chemistry and Materials Science Computer Applications in Chemistry Ionic liquids Ions Melting points Morpholine NMR NMR spectroscopy Nuclear magnetic resonance Original Research Physical Chemistry Spectrum analysis Stability analysis Theoretical and Computational Chemistry Thermal analysis Thermal stability |
| title | Structural and thermoanalytical features of novel morpholinium-based high-voltage ionic liquid |
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