Formation of core-shell structures upon methane decomposition on metal-carbon composites with cobalt nanoparticles encapsulated into a porous carbon matrix

A method for the synthesis of core-shell structures during methane decomposition in a cobalt-carbon composite with metal particles uniformly dispersed in its bulk is proposed. These composites are obtained by the low-temperature formation of carbon structures based on reactive conjugated polymers ob...

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Veröffentlicht in:Nanotechnologies in Russia 2016-07, Vol.11 (7-8), p.414-420
Hauptverfasser: Kryazhev, Yu. G., Zapevalova, E. S., Semenova, O. N., Maslakov, K. I., Solodovnichenko, V. S., Trenikhin, M. V., Drozdov, V. A., Likholobov, V. A.
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Sprache:eng
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Zusammenfassung:A method for the synthesis of core-shell structures during methane decomposition in a cobalt-carbon composite with metal particles uniformly dispersed in its bulk is proposed. These composites are obtained by the low-temperature formation of carbon structures based on reactive conjugated polymers obtained by the dehydrochlorination of chlorine-containing carbon-chain polymers. Eelectron microscopy studies show the formation of structures containing 10–50 graphene layers closely packed around a metal core with an interlayer distance of 0.34–0.35 nm.
ISSN:1995-0780
1995-0799
DOI:10.1134/S1995078016040091