Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties
The perovskite-type Ba- and Ti/Nb-doped (Ba 0.15 Sr 0.85 )(B 0.15 Co 0.85 )O 3 − δ (B = Ti, Nb) oxides were synthesized successfully by the solid-state reaction method. Crystal structure, elemental compositions, and oxygen nonstoichiometry of the as-synthesized (Ba 0.15 Sr 0.85 )(B 0.15 Co 0.85 )O 3...
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| Veröffentlicht in: | Ionics 2017-03, Vol.23 (3), p.717-724 |
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| creator | Lin, Hongquan Lu, Hui Cao, Shuyun Gui, Jianzhou Liu, Dan Park, Jung Hoon |
| description | The perovskite-type Ba- and Ti/Nb-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were synthesized successfully by the solid-state reaction method. Crystal structure, elemental compositions, and oxygen nonstoichiometry of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), inductively coupled plasma (ICP)-atomic emission spectrometry, thermogravimetry (TG), and iodometric titration. XRD results demonstrate that the as-obtained (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides possess purely cubic perovskite-type structures. The temperature-swing oxygen sorption/desorption properties of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) perovskite-type oxides were studied by the dynamic TG. Results show that the structural stability of the co-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is improved greatly, and the high oxygen sorption capacity for the perovskite-type (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is also obtained between 300 and 950 °C in air. |
| doi_str_mv | 10.1007/s11581-016-1835-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880758976</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880758976</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-8c8a869cc6e45ae1b63089962565bb1e5397387bb62f70a7d94bd4c5be62503e3</originalsourceid><addsrcrecordid>eNp1kU9uEzEUxi1EJULaA7AbiU0i1a09M_4zSCxIBKVSRCoR1pY9eQkOyXhqO4i5Qdc9QVacoCfIAThET4JDisSG1XtP3-_73uJD6BUlF5QQcRkoZZJiQjmmsmCYP0M9KnmOieDkOeqRqhRYkFK8QC9DWBHCOc1FD_28Ae--h282Ao5dC9lgpFMk--zJhWTDwehwjN2fY1rsd4939_vdr4eE7Xdv97uZPc8-mWHmftg5hDdZiH5bx63X67RqY9c2dudJ7ZbQZI1rQnS2_mrdBqJPgm7mf8XgfButay5TztOatd614KOFcIpOFnod4Oxp9tGXD-9n4494Mr26Hr-b4LqgPGJZSy15VdccSqaBGl4QWVU8Z5wZQ4EVlSikMIbnC0G0mFelmZc1M5AQUkDRR6-Puen17RZCVCu39U16qaiURDBZCZ4oeqRq70LwsFCttxvtO0WJOtShjnWoVIc61KEOnvzoCYltluD_Sf6v6Tegv5D9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880758976</pqid></control><display><type>article</type><title>Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties</title><source>SpringerLink Journals - AutoHoldings</source><creator>Lin, Hongquan ; Lu, Hui ; Cao, Shuyun ; Gui, Jianzhou ; Liu, Dan ; Park, Jung Hoon</creator><creatorcontrib>Lin, Hongquan ; Lu, Hui ; Cao, Shuyun ; Gui, Jianzhou ; Liu, Dan ; Park, Jung Hoon</creatorcontrib><description>The perovskite-type Ba- and Ti/Nb-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were synthesized successfully by the solid-state reaction method. Crystal structure, elemental compositions, and oxygen nonstoichiometry of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), inductively coupled plasma (ICP)-atomic emission spectrometry, thermogravimetry (TG), and iodometric titration. XRD results demonstrate that the as-obtained (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides possess purely cubic perovskite-type structures. The temperature-swing oxygen sorption/desorption properties of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) perovskite-type oxides were studied by the dynamic TG. Results show that the structural stability of the co-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is improved greatly, and the high oxygen sorption capacity for the perovskite-type (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is also obtained between 300 and 950 °C in air.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-016-1835-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystal structure ; Desorption ; Dynamic stability ; Electrochemistry ; Energy Storage ; Inductively coupled plasma ; Niobium ; Optical and Electronic Materials ; Original Paper ; Oxides ; Oxygen ; Perovskites ; Renewable and Green Energy ; Scientific imaging ; Sorption ; Spectrometry ; Spectroscopy ; Structural stability ; Thermogravimetry ; Titration ; X-ray diffraction</subject><ispartof>Ionics, 2017-03, Vol.23 (3), p.717-724</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-8c8a869cc6e45ae1b63089962565bb1e5397387bb62f70a7d94bd4c5be62503e3</citedby><cites>FETCH-LOGICAL-c316t-8c8a869cc6e45ae1b63089962565bb1e5397387bb62f70a7d94bd4c5be62503e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-016-1835-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-016-1835-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Lin, Hongquan</creatorcontrib><creatorcontrib>Lu, Hui</creatorcontrib><creatorcontrib>Cao, Shuyun</creatorcontrib><creatorcontrib>Gui, Jianzhou</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Park, Jung Hoon</creatorcontrib><title>Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties</title><title>Ionics</title><addtitle>Ionics</addtitle><description>The perovskite-type Ba- and Ti/Nb-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were synthesized successfully by the solid-state reaction method. Crystal structure, elemental compositions, and oxygen nonstoichiometry of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), inductively coupled plasma (ICP)-atomic emission spectrometry, thermogravimetry (TG), and iodometric titration. XRD results demonstrate that the as-obtained (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides possess purely cubic perovskite-type structures. The temperature-swing oxygen sorption/desorption properties of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) perovskite-type oxides were studied by the dynamic TG. Results show that the structural stability of the co-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is improved greatly, and the high oxygen sorption capacity for the perovskite-type (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is also obtained between 300 and 950 °C in air.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Desorption</subject><subject>Dynamic stability</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Inductively coupled plasma</subject><subject>Niobium</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Oxides</subject><subject>Oxygen</subject><subject>Perovskites</subject><subject>Renewable and Green Energy</subject><subject>Scientific imaging</subject><subject>Sorption</subject><subject>Spectrometry</subject><subject>Spectroscopy</subject><subject>Structural stability</subject><subject>Thermogravimetry</subject><subject>Titration</subject><subject>X-ray diffraction</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kU9uEzEUxi1EJULaA7AbiU0i1a09M_4zSCxIBKVSRCoR1pY9eQkOyXhqO4i5Qdc9QVacoCfIAThET4JDisSG1XtP3-_73uJD6BUlF5QQcRkoZZJiQjmmsmCYP0M9KnmOieDkOeqRqhRYkFK8QC9DWBHCOc1FD_28Ae--h282Ao5dC9lgpFMk--zJhWTDwehwjN2fY1rsd4939_vdr4eE7Xdv97uZPc8-mWHmftg5hDdZiH5bx63X67RqY9c2dudJ7ZbQZI1rQnS2_mrdBqJPgm7mf8XgfButay5TztOatd614KOFcIpOFnod4Oxp9tGXD-9n4494Mr26Hr-b4LqgPGJZSy15VdccSqaBGl4QWVU8Z5wZQ4EVlSikMIbnC0G0mFelmZc1M5AQUkDRR6-Puen17RZCVCu39U16qaiURDBZCZ4oeqRq70LwsFCttxvtO0WJOtShjnWoVIc61KEOnvzoCYltluD_Sf6v6Tegv5D9</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Lin, Hongquan</creator><creator>Lu, Hui</creator><creator>Cao, Shuyun</creator><creator>Gui, Jianzhou</creator><creator>Liu, Dan</creator><creator>Park, Jung Hoon</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170301</creationdate><title>Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties</title><author>Lin, Hongquan ; Lu, Hui ; Cao, Shuyun ; Gui, Jianzhou ; Liu, Dan ; Park, Jung Hoon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-8c8a869cc6e45ae1b63089962565bb1e5397387bb62f70a7d94bd4c5be62503e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Desorption</topic><topic>Dynamic stability</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Inductively coupled plasma</topic><topic>Niobium</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Oxides</topic><topic>Oxygen</topic><topic>Perovskites</topic><topic>Renewable and Green Energy</topic><topic>Scientific imaging</topic><topic>Sorption</topic><topic>Spectrometry</topic><topic>Spectroscopy</topic><topic>Structural stability</topic><topic>Thermogravimetry</topic><topic>Titration</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Hongquan</creatorcontrib><creatorcontrib>Lu, Hui</creatorcontrib><creatorcontrib>Cao, Shuyun</creatorcontrib><creatorcontrib>Gui, Jianzhou</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Park, Jung Hoon</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Hongquan</au><au>Lu, Hui</au><au>Cao, Shuyun</au><au>Gui, Jianzhou</au><au>Liu, Dan</au><au>Park, Jung Hoon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>23</volume><issue>3</issue><spage>717</spage><epage>724</epage><pages>717-724</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>The perovskite-type Ba- and Ti/Nb-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were synthesized successfully by the solid-state reaction method. Crystal structure, elemental compositions, and oxygen nonstoichiometry of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), inductively coupled plasma (ICP)-atomic emission spectrometry, thermogravimetry (TG), and iodometric titration. XRD results demonstrate that the as-obtained (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides possess purely cubic perovskite-type structures. The temperature-swing oxygen sorption/desorption properties of the as-synthesized (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) perovskite-type oxides were studied by the dynamic TG. Results show that the structural stability of the co-doped (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is improved greatly, and the high oxygen sorption capacity for the perovskite-type (Ba
0.15
Sr
0.85
)(B
0.15
Co
0.85
)O
3 − δ
(B = Ti, Nb) oxides is also obtained between 300 and 950 °C in air.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-016-1835-6</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-7047 |
| ispartof | Ionics, 2017-03, Vol.23 (3), p.717-724 |
| issn | 0947-7047 1862-0760 |
| language | eng |
| recordid | cdi_proquest_journals_1880758976 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Crystal structure Desorption Dynamic stability Electrochemistry Energy Storage Inductively coupled plasma Niobium Optical and Electronic Materials Original Paper Oxides Oxygen Perovskites Renewable and Green Energy Scientific imaging Sorption Spectrometry Spectroscopy Structural stability Thermogravimetry Titration X-ray diffraction |
| title | Perovskite-type (Ba0.15Sr0.85)(B0.15Co0.85)O3 − δ (B = Ti, Nb) oxides: structural stability, oxygen nonstoichiometry, and oxygen sorption/desorption properties |
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