Reactions of benzazole-2-thiones with 3,5-di-tert-butyl-4-hydroxybenzyl acetate
The benzylation of benzothiazole(oxazole, imidazole)-2-thiones with 3,5-di- tert -butyl-4-hydroxybenzyl acetate involves either the sulfur or nitrogen atom depending on the reaction conditions. The S - and N -benzylation products of benzazole-2-thiones are kinetically and thermodynamically controlle...
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| Veröffentlicht in: | Russian journal of general chemistry 2017, Vol.87 (1), p.22-28 |
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| container_title | Russian journal of general chemistry |
| container_volume | 87 |
| creator | Tagasheva, R. G. Gataullina, D. R. Zaripova, I. F. Bukharov, S. V. Nugumanova, G. N. Deberdeev, T. R. Voronina, Yu. K. |
| description | The benzylation of benzothiazole(oxazole, imidazole)-2-thiones with 3,5-di-
tert
-butyl-4-hydroxybenzyl acetate involves either the sulfur or nitrogen atom depending on the reaction conditions. The
S
- and
N
-benzylation products of benzazole-2-thiones are kinetically and thermodynamically controlled products, respectively. The use of 3,5-di-
tert
-butyl-4-hydroxy-benzyl acetate allows sterically hindered hydroxybenzyl derivatives of benzаzole-2-thiones to be generally synthesized under milder conditions than in known methods of their synthesis. |
| doi_str_mv | 10.1134/S1070363217010054 |
| format | Article |
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tert
-butyl-4-hydroxybenzyl acetate involves either the sulfur or nitrogen atom depending on the reaction conditions. The
S
- and
N
-benzylation products of benzazole-2-thiones are kinetically and thermodynamically controlled products, respectively. The use of 3,5-di-
tert
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tert
-butyl-4-hydroxybenzyl acetate involves either the sulfur or nitrogen atom depending on the reaction conditions. The
S
- and
N
-benzylation products of benzazole-2-thiones are kinetically and thermodynamically controlled products, respectively. The use of 3,5-di-
tert
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tert
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S
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N
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tert
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| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Imidazole Oxazole |
| title | Reactions of benzazole-2-thiones with 3,5-di-tert-butyl-4-hydroxybenzyl acetate |
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