Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler
In the present study, industrial toilet seat wastes which contain 70 wt% urea formaldehyde and 30 wt% cellulose were used as a particulate reinforcement in epoxy matrix and their mechanical and physical properties were investigated. The usage of urea formaldehyde and cellulose mixture as filler of p...
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Veröffentlicht in: | Waste and biomass valorization 2017-04, Vol.8 (3), p.669-678 |
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description | In the present study, industrial toilet seat wastes which contain 70 wt% urea formaldehyde and 30 wt% cellulose were used as a particulate reinforcement in epoxy matrix and their mechanical and physical properties were investigated. The usage of urea formaldehyde and cellulose mixture as filler of polymer composite materials is a novel study. Initially toilet seat wastes were ground and particles in the required size range were obtained. The characterization of waste particulate filler was carried out by scanning electron microscopy, X-ray diffraction techniques and He gas pycnometer. Optimum concentration of the filler was determined as a maximum of 40 wt% because of the increase in viscosity at higher waste concentration. The effect of particle size on mechanical properties such as hardness, bending strength and bending modulus was evaluated. These are the key properties most likely to be affected by incorporation of reinforcement phase. Experimental results showed that bending modulus and hardness increased and bending strength decreased with filler addition into epoxy resin. With the increase in filler content both porosity and bending strength decreased and bending modulus increased. On the other hand increase in particle size led to the enhancement of bending strength and bending modulus while accompanied with a decrease in porosity. As a result, incorporation of urea formaldehyde wastes basically resulted in the reinforcement of the epoxy matrix. This allows for the recycling of hardly recoverable thermosetting residues as well as improving some mechanical properties of the composites. |
doi_str_mv | 10.1007/s12649-016-9651-9 |
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The usage of urea formaldehyde and cellulose mixture as filler of polymer composite materials is a novel study. Initially toilet seat wastes were ground and particles in the required size range were obtained. The characterization of waste particulate filler was carried out by scanning electron microscopy, X-ray diffraction techniques and He gas pycnometer. Optimum concentration of the filler was determined as a maximum of 40 wt% because of the increase in viscosity at higher waste concentration. The effect of particle size on mechanical properties such as hardness, bending strength and bending modulus was evaluated. These are the key properties most likely to be affected by incorporation of reinforcement phase. Experimental results showed that bending modulus and hardness increased and bending strength decreased with filler addition into epoxy resin. With the increase in filler content both porosity and bending strength decreased and bending modulus increased. On the other hand increase in particle size led to the enhancement of bending strength and bending modulus while accompanied with a decrease in porosity. As a result, incorporation of urea formaldehyde wastes basically resulted in the reinforcement of the epoxy matrix. This allows for the recycling of hardly recoverable thermosetting residues as well as improving some mechanical properties of the composites.</description><identifier>ISSN: 1877-2641</identifier><identifier>EISSN: 1877-265X</identifier><identifier>DOI: 10.1007/s12649-016-9651-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bend strength ; Bending modulus ; Biomass ; Cellulose ; Engineering ; Environment ; Environmental Engineering/Biotechnology ; Epoxy matrix composites ; Epoxy resins ; Formaldehyde ; Hardness ; Industrial Pollution Prevention ; Mechanical properties ; Original Paper ; Particle size ; Particulate composites ; Physical properties ; Polymer matrix composites ; Porosity ; Reinforcement ; Renewable and Green Energy ; Urea formaldehyde resins ; Waste Management/Waste Technology ; Wastes</subject><ispartof>Waste and biomass valorization, 2017-04, Vol.8 (3), p.669-678</ispartof><rights>Springer Science+Business Media Dordrecht 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-2454192e7ca9bd9ea5c8af254ca143ebe4177c63ebe2cf0062aae64c1ad57ef13</citedby><cites>FETCH-LOGICAL-c353t-2454192e7ca9bd9ea5c8af254ca143ebe4177c63ebe2cf0062aae64c1ad57ef13</cites><orcidid>0000-0001-6193-8252</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12649-016-9651-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12649-016-9651-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Acikbas, Nurcan Calis</creatorcontrib><creatorcontrib>Acikbas, Gokhan</creatorcontrib><title>Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler</title><title>Waste and biomass valorization</title><addtitle>Waste Biomass Valor</addtitle><description>In the present study, industrial toilet seat wastes which contain 70 wt% urea formaldehyde and 30 wt% cellulose were used as a particulate reinforcement in epoxy matrix and their mechanical and physical properties were investigated. The usage of urea formaldehyde and cellulose mixture as filler of polymer composite materials is a novel study. Initially toilet seat wastes were ground and particles in the required size range were obtained. The characterization of waste particulate filler was carried out by scanning electron microscopy, X-ray diffraction techniques and He gas pycnometer. Optimum concentration of the filler was determined as a maximum of 40 wt% because of the increase in viscosity at higher waste concentration. The effect of particle size on mechanical properties such as hardness, bending strength and bending modulus was evaluated. These are the key properties most likely to be affected by incorporation of reinforcement phase. Experimental results showed that bending modulus and hardness increased and bending strength decreased with filler addition into epoxy resin. With the increase in filler content both porosity and bending strength decreased and bending modulus increased. On the other hand increase in particle size led to the enhancement of bending strength and bending modulus while accompanied with a decrease in porosity. As a result, incorporation of urea formaldehyde wastes basically resulted in the reinforcement of the epoxy matrix. This allows for the recycling of hardly recoverable thermosetting residues as well as improving some mechanical properties of the composites.</description><subject>Bend strength</subject><subject>Bending modulus</subject><subject>Biomass</subject><subject>Cellulose</subject><subject>Engineering</subject><subject>Environment</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Epoxy matrix composites</subject><subject>Epoxy resins</subject><subject>Formaldehyde</subject><subject>Hardness</subject><subject>Industrial Pollution Prevention</subject><subject>Mechanical properties</subject><subject>Original Paper</subject><subject>Particle size</subject><subject>Particulate composites</subject><subject>Physical properties</subject><subject>Polymer matrix composites</subject><subject>Porosity</subject><subject>Reinforcement</subject><subject>Renewable and Green Energy</subject><subject>Urea formaldehyde resins</subject><subject>Waste Management/Waste Technology</subject><subject>Wastes</subject><issn>1877-2641</issn><issn>1877-265X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLw0AQhRdRsNT-AG8Bz9GdzWY3e5TSqtCiB4velulmUlPSJO6m0P77pkTEi6f5Du-9gY-xW-D3wLl-CCCUNDEHFRuVQmwu2AgyrWOh0s_LX5ZwzSYhbDnnAiATiR6x5axtDsdoiZ0vD9G02bVNKDsKPdYdlnVZb6KVJ4zmjd9hldPXMafoA0NH0Rv6rnT7Cnuel1VF_oZdFVgFmvzcMVvNZ-_T53jx-vQyfVzELkmTLhYylWAEaYdmnRvC1GVYiFQ6BJnQmiRo7dSZhCs4VwKRlHSAeaqpgGTM7obd1jffewqd3TZ7X_cvLWQZ19IkivcpGFLONyF4Kmzryx36owVuz-LsIM724uxZnDV9Rwyd0GfrDfk_y_-WTkV5cSc</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Acikbas, Nurcan Calis</creator><creator>Acikbas, Gokhan</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6193-8252</orcidid></search><sort><creationdate>20170401</creationdate><title>Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler</title><author>Acikbas, Nurcan Calis ; Acikbas, Gokhan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-2454192e7ca9bd9ea5c8af254ca143ebe4177c63ebe2cf0062aae64c1ad57ef13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Bend strength</topic><topic>Bending modulus</topic><topic>Biomass</topic><topic>Cellulose</topic><topic>Engineering</topic><topic>Environment</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Epoxy matrix composites</topic><topic>Epoxy resins</topic><topic>Formaldehyde</topic><topic>Hardness</topic><topic>Industrial Pollution Prevention</topic><topic>Mechanical properties</topic><topic>Original Paper</topic><topic>Particle size</topic><topic>Particulate composites</topic><topic>Physical properties</topic><topic>Polymer matrix composites</topic><topic>Porosity</topic><topic>Reinforcement</topic><topic>Renewable and Green Energy</topic><topic>Urea formaldehyde resins</topic><topic>Waste Management/Waste Technology</topic><topic>Wastes</topic><toplevel>online_resources</toplevel><creatorcontrib>Acikbas, Nurcan Calis</creatorcontrib><creatorcontrib>Acikbas, Gokhan</creatorcontrib><collection>CrossRef</collection><jtitle>Waste and biomass valorization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Acikbas, Nurcan Calis</au><au>Acikbas, Gokhan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler</atitle><jtitle>Waste and biomass valorization</jtitle><stitle>Waste Biomass Valor</stitle><date>2017-04-01</date><risdate>2017</risdate><volume>8</volume><issue>3</issue><spage>669</spage><epage>678</epage><pages>669-678</pages><issn>1877-2641</issn><eissn>1877-265X</eissn><abstract>In the present study, industrial toilet seat wastes which contain 70 wt% urea formaldehyde and 30 wt% cellulose were used as a particulate reinforcement in epoxy matrix and their mechanical and physical properties were investigated. The usage of urea formaldehyde and cellulose mixture as filler of polymer composite materials is a novel study. Initially toilet seat wastes were ground and particles in the required size range were obtained. The characterization of waste particulate filler was carried out by scanning electron microscopy, X-ray diffraction techniques and He gas pycnometer. Optimum concentration of the filler was determined as a maximum of 40 wt% because of the increase in viscosity at higher waste concentration. The effect of particle size on mechanical properties such as hardness, bending strength and bending modulus was evaluated. These are the key properties most likely to be affected by incorporation of reinforcement phase. Experimental results showed that bending modulus and hardness increased and bending strength decreased with filler addition into epoxy resin. With the increase in filler content both porosity and bending strength decreased and bending modulus increased. On the other hand increase in particle size led to the enhancement of bending strength and bending modulus while accompanied with a decrease in porosity. As a result, incorporation of urea formaldehyde wastes basically resulted in the reinforcement of the epoxy matrix. This allows for the recycling of hardly recoverable thermosetting residues as well as improving some mechanical properties of the composites.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s12649-016-9651-9</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-6193-8252</orcidid></addata></record> |
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subjects | Bend strength Bending modulus Biomass Cellulose Engineering Environment Environmental Engineering/Biotechnology Epoxy matrix composites Epoxy resins Formaldehyde Hardness Industrial Pollution Prevention Mechanical properties Original Paper Particle size Particulate composites Physical properties Polymer matrix composites Porosity Reinforcement Renewable and Green Energy Urea formaldehyde resins Waste Management/Waste Technology Wastes |
title | Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler |
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