Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes
A novel approach of double hydroxide-mediated synthesis of nickel cobaltite (NiCo 2 O 4 ) electro-active material by the hydrothermal method is reported. The obtained NiCo 2 O 4 electro-active material displays the spinel cubic phase and hexagonal-like morphology. Thermogravimetry analysis confirms...
Gespeichert in:
| Veröffentlicht in: | Ionics 2017-04, Vol.23 (4), p.977-984 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 984 |
|---|---|
| container_issue | 4 |
| container_start_page | 977 |
| container_title | Ionics |
| container_volume | 23 |
| creator | Venkatachalam, V. Alsalme, A. Alghamdi, A. Jayavel, R. |
| description | A novel approach of double hydroxide-mediated synthesis of nickel cobaltite (NiCo
2
O
4
) electro-active material by the hydrothermal method is reported. The obtained NiCo
2
O
4
electro-active material displays the spinel cubic phase and hexagonal-like morphology. Thermogravimetry analysis confirms the thermal stability of the electrode material. The functional groups and phase formation of NiCo
2
O
4
have been confirmed by FT-IR and Raman spectral analysis. The modified NiCo
2
O
4
electrode exhibits the highest specific capacitance of 767.5 F g
−1
at a current density of 0.5 A g
−1
in 3 M KOH electrolyte and excellent cyclic stability (94 % capacitance retention after 1000 cycles at a high current density of 5 A g
−1
). The excellent electrochemical performance of the electrode is attributed to the hexagonal-like morphology, which contributes to the rich surface electro-active sites and easy transport pathway for the ions during the electrochemical reaction. The attractive Faradic behavior of NiCo
2
O
4
electrode has been ascribed to the redox contribution of Ni
2+
/Ni
3+
and Co
2+
/Co
3+
metal species in the alkaline medium. The symmetrical two-electrode cell has been fabricated using the NiCo
2
O
4
electro-active material with excellent electrochemical properties for supercapacitor applications. |
| doi_str_mv | 10.1007/s11581-016-1868-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880746034</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880746034</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-5f6fe59aa54175105c287857b923f3e0c4edbf24e0c9007062c140ab0cc0e7ae3</originalsourceid><addsrcrecordid>eNp1kDFPwzAUhC0EEqXwA9giMRueHcdORlQBRUJ0obPluM9tShoHO5HKv8dVGFiY3j3p7qT7CLllcM8A1ENkrCgZBSYpK2VJj2dklgSnoCSckxlUQlEFQl2Sqxj3AFIyrmZkvcSj2frOtLRtPjF7bxaer0TWmc7HIYx2GANmtYm4yXbNdkd7DM6Hg-ksZnFMnzW9sc3gQ4Yt2iH4DcZrcuFMG_Hm987J-vnpY7Gkb6uX18XjG7U5kwMtnHRYVMYUgqmCQWF5qcpC1RXPXY5gBW5qx0VSVRoJklsmwNRgLaAymM_J3dTbB_81Yhz03o8hjYmalSUoISEXycUmlw0-xoBO96E5mPCtGegTPT3R04mePtHTx5ThUyYmb7fF8Kf539APYllzew</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880746034</pqid></control><display><type>article</type><title>Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes</title><source>SpringerLink Journals - AutoHoldings</source><creator>Venkatachalam, V. ; Alsalme, A. ; Alghamdi, A. ; Jayavel, R.</creator><creatorcontrib>Venkatachalam, V. ; Alsalme, A. ; Alghamdi, A. ; Jayavel, R.</creatorcontrib><description>A novel approach of double hydroxide-mediated synthesis of nickel cobaltite (NiCo
2
O
4
) electro-active material by the hydrothermal method is reported. The obtained NiCo
2
O
4
electro-active material displays the spinel cubic phase and hexagonal-like morphology. Thermogravimetry analysis confirms the thermal stability of the electrode material. The functional groups and phase formation of NiCo
2
O
4
have been confirmed by FT-IR and Raman spectral analysis. The modified NiCo
2
O
4
electrode exhibits the highest specific capacitance of 767.5 F g
−1
at a current density of 0.5 A g
−1
in 3 M KOH electrolyte and excellent cyclic stability (94 % capacitance retention after 1000 cycles at a high current density of 5 A g
−1
). The excellent electrochemical performance of the electrode is attributed to the hexagonal-like morphology, which contributes to the rich surface electro-active sites and easy transport pathway for the ions during the electrochemical reaction. The attractive Faradic behavior of NiCo
2
O
4
electrode has been ascribed to the redox contribution of Ni
2+
/Ni
3+
and Co
2+
/Co
3+
metal species in the alkaline medium. The symmetrical two-electrode cell has been fabricated using the NiCo
2
O
4
electro-active material with excellent electrochemical properties for supercapacitor applications.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-016-1868-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemistry ; Energy Storage ; Functional groups ; Optical and Electronic Materials ; Original Paper ; Renewable and Green Energy ; Supercapacitors ; Thermal stability</subject><ispartof>Ionics, 2017-04, Vol.23 (4), p.977-984</ispartof><rights>Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5f6fe59aa54175105c287857b923f3e0c4edbf24e0c9007062c140ab0cc0e7ae3</citedby><cites>FETCH-LOGICAL-c316t-5f6fe59aa54175105c287857b923f3e0c4edbf24e0c9007062c140ab0cc0e7ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-016-1868-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-016-1868-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Venkatachalam, V.</creatorcontrib><creatorcontrib>Alsalme, A.</creatorcontrib><creatorcontrib>Alghamdi, A.</creatorcontrib><creatorcontrib>Jayavel, R.</creatorcontrib><title>Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes</title><title>Ionics</title><addtitle>Ionics</addtitle><description>A novel approach of double hydroxide-mediated synthesis of nickel cobaltite (NiCo
2
O
4
) electro-active material by the hydrothermal method is reported. The obtained NiCo
2
O
4
electro-active material displays the spinel cubic phase and hexagonal-like morphology. Thermogravimetry analysis confirms the thermal stability of the electrode material. The functional groups and phase formation of NiCo
2
O
4
have been confirmed by FT-IR and Raman spectral analysis. The modified NiCo
2
O
4
electrode exhibits the highest specific capacitance of 767.5 F g
−1
at a current density of 0.5 A g
−1
in 3 M KOH electrolyte and excellent cyclic stability (94 % capacitance retention after 1000 cycles at a high current density of 5 A g
−1
). The excellent electrochemical performance of the electrode is attributed to the hexagonal-like morphology, which contributes to the rich surface electro-active sites and easy transport pathway for the ions during the electrochemical reaction. The attractive Faradic behavior of NiCo
2
O
4
electrode has been ascribed to the redox contribution of Ni
2+
/Ni
3+
and Co
2+
/Co
3+
metal species in the alkaline medium. The symmetrical two-electrode cell has been fabricated using the NiCo
2
O
4
electro-active material with excellent electrochemical properties for supercapacitor applications.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Functional groups</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Renewable and Green Energy</subject><subject>Supercapacitors</subject><subject>Thermal stability</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAUhC0EEqXwA9giMRueHcdORlQBRUJ0obPluM9tShoHO5HKv8dVGFiY3j3p7qT7CLllcM8A1ENkrCgZBSYpK2VJj2dklgSnoCSckxlUQlEFQl2Sqxj3AFIyrmZkvcSj2frOtLRtPjF7bxaer0TWmc7HIYx2GANmtYm4yXbNdkd7DM6Hg-ksZnFMnzW9sc3gQ4Yt2iH4DcZrcuFMG_Hm987J-vnpY7Gkb6uX18XjG7U5kwMtnHRYVMYUgqmCQWF5qcpC1RXPXY5gBW5qx0VSVRoJklsmwNRgLaAymM_J3dTbB_81Yhz03o8hjYmalSUoISEXycUmlw0-xoBO96E5mPCtGegTPT3R04mePtHTx5ThUyYmb7fF8Kf539APYllzew</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Venkatachalam, V.</creator><creator>Alsalme, A.</creator><creator>Alghamdi, A.</creator><creator>Jayavel, R.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170401</creationdate><title>Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes</title><author>Venkatachalam, V. ; Alsalme, A. ; Alghamdi, A. ; Jayavel, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5f6fe59aa54175105c287857b923f3e0c4edbf24e0c9007062c140ab0cc0e7ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Functional groups</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Renewable and Green Energy</topic><topic>Supercapacitors</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Venkatachalam, V.</creatorcontrib><creatorcontrib>Alsalme, A.</creatorcontrib><creatorcontrib>Alghamdi, A.</creatorcontrib><creatorcontrib>Jayavel, R.</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Venkatachalam, V.</au><au>Alsalme, A.</au><au>Alghamdi, A.</au><au>Jayavel, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2017-04-01</date><risdate>2017</risdate><volume>23</volume><issue>4</issue><spage>977</spage><epage>984</epage><pages>977-984</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>A novel approach of double hydroxide-mediated synthesis of nickel cobaltite (NiCo
2
O
4
) electro-active material by the hydrothermal method is reported. The obtained NiCo
2
O
4
electro-active material displays the spinel cubic phase and hexagonal-like morphology. Thermogravimetry analysis confirms the thermal stability of the electrode material. The functional groups and phase formation of NiCo
2
O
4
have been confirmed by FT-IR and Raman spectral analysis. The modified NiCo
2
O
4
electrode exhibits the highest specific capacitance of 767.5 F g
−1
at a current density of 0.5 A g
−1
in 3 M KOH electrolyte and excellent cyclic stability (94 % capacitance retention after 1000 cycles at a high current density of 5 A g
−1
). The excellent electrochemical performance of the electrode is attributed to the hexagonal-like morphology, which contributes to the rich surface electro-active sites and easy transport pathway for the ions during the electrochemical reaction. The attractive Faradic behavior of NiCo
2
O
4
electrode has been ascribed to the redox contribution of Ni
2+
/Ni
3+
and Co
2+
/Co
3+
metal species in the alkaline medium. The symmetrical two-electrode cell has been fabricated using the NiCo
2
O
4
electro-active material with excellent electrochemical properties for supercapacitor applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-016-1868-x</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-7047 |
| ispartof | Ionics, 2017-04, Vol.23 (4), p.977-984 |
| issn | 0947-7047 1862-0760 |
| language | eng |
| recordid | cdi_proquest_journals_1880746034 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Energy Storage Functional groups Optical and Electronic Materials Original Paper Renewable and Green Energy Supercapacitors Thermal stability |
| title | Hexagonal-like NiCo2O4 nanostructure based high-performance supercapacitor electrodes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T15%3A55%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hexagonal-like%20NiCo2O4%20nanostructure%20based%20high-performance%20supercapacitor%20electrodes&rft.jtitle=Ionics&rft.au=Venkatachalam,%20V.&rft.date=2017-04-01&rft.volume=23&rft.issue=4&rft.spage=977&rft.epage=984&rft.pages=977-984&rft.issn=0947-7047&rft.eissn=1862-0760&rft_id=info:doi/10.1007/s11581-016-1868-x&rft_dat=%3Cproquest_cross%3E1880746034%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1880746034&rft_id=info:pmid/&rfr_iscdi=true |