Phase formation in the BaCO3–PbO–Fe2O3–Nb2O5 system

Features of the formation of lead-ferroniobate compounds in the x BaCO 3 –(1 – x )PbO–Fe 2 O 3 –Nb 2 O 5 system by solid-phase synthesis are investigated. For perovskite-type lead-ferroniobate solid solution, a single-phase concentration region is revealed at 1233 K. The crystalline structures of th...

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Veröffentlicht in:Surface investigation, x-ray, synchrotron and neutron techniques x-ray, synchrotron and neutron techniques, 2017, Vol.11 (1), p.87-91
Hauptverfasser: Lupitskaya, Yu. A., Kalganov, D. A., Abdrakhmanova, K. V.
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Kalganov, D. A.
Abdrakhmanova, K. V.
description Features of the formation of lead-ferroniobate compounds in the x BaCO 3 –(1 – x )PbO–Fe 2 O 3 –Nb 2 O 5 system by solid-phase synthesis are investigated. For perovskite-type lead-ferroniobate solid solution, a single-phase concentration region is revealed at 1233 K. The crystalline structures of the synthesized compounds are refined using Rietveld analysis and the Pm 3̅ m and R 3 m space groups. Ceramic samples of lead ferroniobate are studied by scanning electron microscopy.
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subjects Chemistry and Materials Science
Materials Science
Niobium oxides
Perovskites
Solid phase synthesis
Solid solutions
Surfaces and Interfaces
Thin Films
title Phase formation in the BaCO3–PbO–Fe2O3–Nb2O5 system
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